Platinum Catalyst
Mostrando 1-12 de 32 artigos, teses e dissertações.
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1. The Influence of the Platinum Weight Percentage in the Catalyst Formulation on the Performance of a High Temperature Ethanol Electroreformer Based on H3PO4 Doped Polybenzimidazole for Green Hydrogen Production
A vapor-fed high temperature proton exchange ethanol electroreformer has been developed based on the use of a H3PO4-doped polybenzimidazole membrane to produce green hydrogen. As a key parameter, this article describes the influence of platinum weight percent (wt.%) in the catalyst formulation from different commercial catalysts (20, 40, 60, 80 wt.% Pt/C and
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Synthesis of Triazoles by Electro-Assisted Click Reaction Using a Copper Foil Electrode
This paper presents an innovative pathway for the synthesis of triazoles using the well-known “click chemistry” assisted by the electrochemical oxidation of metallic Cu0. The click reaction is used to couple a wide range of biological interest compounds. In this case, faster and less polluting methods for a biological environment was achived by in situ C
J. Braz. Chem. Soc.. Publicado em: 2021-07
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3. INFLUÊNCIA DA COMPOSIÇÃO DOS NANOFIOS PT-IR/C NA ATIVIDADE CATALÍTICA FRENTE A OXIDAÇÃO ELETROQUÍMICA DE ETANOL EM MEIO ÁCIDO
Carbon-supported platinum-iridium nanowire-shape electrocatalysts containing 20% of metallic loading were synthesized by chemical reduction method using formic acid as a reducing agent and tested towards the oxidation of ethanol in acidic medium. The developed electrocatalysts were synthesized with the following compositions: Pt0.9Ir0.1/C, Pt0.8Ir0.2/C, Pt0.
Quím. Nova. Publicado em: 2020-02
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4. CATALYTIC OXIDATION OF ISOPROPYL ALCOHOL OVER PLATINUM BASED CATALYST: A STUDY OF THE EFFECT OF METHYL CELLULOSE ON Pt PARTICLES DISPERSION OVER MULLITE
Abstract Isopropyl alcohol (IPA) catalytic oxidation remains one of the most popular techniques to remove volatile organic compounds from indoor places. In our study, catalytic oxidation of IPA was investigated on catalysts based on platinum deposited on mullite (Al6Si2O13), known for its excellent thermal stability. Pt/Al6Si2O13 catalysts were prepared by i
Braz. J. Chem. Eng.. Publicado em: 09/12/2019
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5. Adsorción y oxidación de monóxido de carbono en una lamina de ß-grafino: Estudio teórico
ABSTRACT This work presents a study, based on the Density functional theory (DFT), of the adsorption and oxidation of CO on a free platinum catalyst constituted from a sheet of Graphyne. Graphyne is a new allotrope of carbon, its structure is two-dimensional and is constituted by a monolayer of carbon atoms with sp-sp2 hybridization. Depending on the differe
Matéria (Rio J.). Publicado em: 19/07/2018
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6. Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactions
Rhodium and platinum nanoparticles were supported in polymeric membranes with 10, 20 and 40 µm thickness. The polymeric membranes were prepared combining cellulose acetate and the ionic liquid (IL) 1-n-butyl-3-methylimidazolium bis(trifluoromethane sulfonyl)imide (BMI.(NTf)2. The presence of metal nanoparticles induced an increase in the polymeric membrane
Polímeros. Publicado em: 18/04/2014
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7. Desenvolvimento de método para a determinação de irídio, paládio, platina e ródio por ICP OES em sílica mesoporosa para uso catalítico / Development of method for the determination of iridium, palladium, platinum and rhodium in mesoporosa silica for catalyst use by ICP OES
O objetivo deste estudo foi avaliar parâmetros tais como, moagem, tamanho de partículas, homogeneidade, segregação, dissolução de amostras e amostragem de suspensão, visando o desenvolvimento de método para a determinação de Ir, Pd, Pt e Rh por espectrometria de emissão óptica com plasma indutivamente acoplado (ICP OES) em sílica mesoporosa para
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 10/07/2012
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8. Platinum and nioubium based catalysts for the anode of polymer electrolyte membrane fuel cells fed with low molecular weight alcohols / Catalisadores a base de platina e nióbio para o ânodo da célula a combustível de membrana trocadora de prótons alimentada com alcoóis de baixa massa molecular
In this work, the methanol and ethanol electrochemical oxidation reactions are studied on platinum (Pt) and niobium (Nb) catalysts supported on high surface area carbon. The selected materials were PtNb/C, Pt-Nb2O5(amorphous) /C e Pt-Nb2O5(crystalline) /C, using as reference for comparison purposes the commercial catalyst 20% Pt-C E-TEK. The catalysts were p
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 25/01/2012
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9. Catalisadores à base de platina frente a correntes de H2 contendo acetaldeído geradas via reforma do etanol / Platinum-based catalystic in the face of current H2 containing acthaldehyde generated via reforming of ethanol
Due to the greenhouse effect, hydrogen production from bioethanol reforming is a very important subject in heterogeneous catalysis research. Pt based catalysts are employed in H2 purification processes and also as electrocatalysts of PEM (Proton Exchange Membrane) fuel cells. Hydrogen obtained from ethanol reforming may contain acetaldehyde and small amounts
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 23/05/2011
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10. Low metal loading catalysts used for the selective hydrogenation of styrene
A series of Group VIII metal catalysts was obtained for the semi-hydrogenation of styrene. Catalysts were characterized by Hydrogen Chemisorption, TPR and XPS. Palladium, rhodium and platinum low metal loading prepared catalysts presented high activity and selectivity (ca. 98%) during the semi-hydrogenation of styrene, being palladium the most active catalys
Química Nova. Publicado em: 2010
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11. Catalytic materials based on Pt, Pb and carbon powder to the oxidation of formic acid in acid medium / Materiais catalíticos baseados em PT, PB e pó de Carbono para a oxidação de ácido fórmico em meio ácido
Proton Exchange Membrane Fuel Cell (PEMFC) that operates with formic acid as fuel (Direct Formic Acid Fuel Cell, DFAFC) constitutes a promising power source to be used in portable devices. In this context, this work aims to find efficient anodes to be used in this kind of system. All materials, based in Pt, Pb and carbon black were synthesized by the Sol-Gel
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 19/02/2009
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12. A hidrogenação do adipato de dimetila utilizando catalisadores suportados em argilas pilarizadas / Hydrogenation of dimethyl adipate at presence of pillared clay based catalysts
Vários métodos de síntese das argilas pilarizadas foram testados. Obtivemos os materiais pilarizados com alumínio em condições distintas: suspensões diluídas (Al-PILC 02), suspensões concentradas (Al-PILC 03), soluções pilarizantes concentradas (Al-PILC 04) e o uso de microondas no processo de envelhecimento (Al-PILC 05). Este último demonstrou s
Publicado em: 2009