Acrolein
Mostrando 1-12 de 53 artigos, teses e dissertações.
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1. Metal-Supported Niobium Catalysts Investigation for Conversion of Bio-Renewable Glycerol to Organic Compounds
The glycerol oxidative dehydration to organic compounds, especially acrolein and acrylic acid, was studied over vanadium, molybdenum, and cobalt oxides supported on niobium oxide and niobium phosphate catalysts. At 300 °C, the glycerol conversion was 100% over all catalysts tested, and acrolein was the main product observed, without significant deactivation
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Catalytic Dehydration of Glycerol to Acrolein over Aluminum Phosphate Catalysts
Gas phase conversion of glycerol to acrolein over a variety of aluminum phosphate (AlP) catalysts synthesized by a simple replacement reaction method with a variation in calcination temperature (300-700 ºC, AlP-300, AlP-400, AlP-500, AlP-600, and AlP-700, respectively) has been investigated. The textural properties, acidities and coke contents of the sample
J. Braz. Chem. Soc.. Publicado em: 2020-08
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3. DNA Damage by Endogenous and Exogenous Aldehydes
The present overview describes the formation of deoxyribonucleic acid (DNA) adducts from endogenous and exogenous aldehydes, such as acetaldehyde, acrolein, crotonaldehyde, malonaldehyde, 4-hydroxy-2-nonenal and 2,4-decadienal. Malonaldehyde reacts with 2’-deoxyguanosine, 2’-deoxyadenosine, and 2’-deoxycytidine, yielding cyclic pyrimidopurinone and acy
J. Braz. Chem. Soc.. Publicado em: 21/10/2019
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4. Carbonyl compounds in wine: factors related to presence and toxic effects
RESUMO: O objetivo deste estudo foi revisar os fatores tecnológicos e toxicológicos relacionados à presença de compostos carbonílicos encontrados em vinhos, incluindo acetaldeído, formaldeído, acroleína, carbamato de etila (CE) e furfural. O acetaldeído e o formaldeído podem ser formados através da oxidação do etanol e do metanol, respectivament
Cienc. Rural. Publicado em: 29/07/2019
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5. Oxidative Dehydration of Glycerol over Molybdenum- and Vanadium-Based Catalysts
Surplus of glycerol production from the biodiesel industry has led to the search for glycerol conversion routes, the most common of which are dehydration and oxidative dehydration. Vanadium and molybdenum oxides were supported on γ-Al2O3 and their properties were analyzed through several characterization techniques, showing that the acidity increases after
J. Braz. Chem. Soc.. Publicado em: 08/04/2019
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6. Exposure risk to carbonyl compounds and furfuryl alcohol through the consumption of sparkling wines
RESUMO: Os objetivos deste estudo foram verificar a ocorrência de álcool furfurílico (FA) e compostos carbonílicos (acetaldeído, acroleína, carbamato de etila (CE), formaldeído e furfural) em espumantes e avaliar, pela primeira vez, se o consumo das amostras em estudo poderia representar risco para a saúde do consumidor. Esses compostos são eletrof
Cienc. Rural. Publicado em: 21/03/2019
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7. CRAQUEAMENTO TÉRMICO DA GLICERINA: UMA PROPOSTA DE EXPERIMENTO PARA QUÍMICA ORGÂNICA
In this work, an undergraduate organic chemistry experiment based on thermal cracking of glycerin is proposed. The reagent is obtained as a by-product from the practice of biodiesel synthesis, and allows reduction of waste produced in the lab. The main product obtained from thermal cracking was characterized by GC analysis as acrolein. This substance was
Quím. Nova. Publicado em: 2015-06
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8. The Mutagenic Potential Caused by the Emissions from Combustion of Crude Glycerin and Diesel Fuel
This study evaluated the use of crude glycerin as an alternative of energy generation to replace the traditional fuels. The Tradescantia stamen hair mutation assay (Trad-SH) was applied to study the mutagenic effects caused by the emissions generated in the direct combustion of diesel oil and glycerin in a flame tube furnace. Tradescantia inflorescences were
Braz. arch. biol. technol.. Publicado em: 11/11/2014
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9. ESTUDO EXPERIMENTAL DA COMBUSTÃO DO GLP E GLICEROL RESIDUAL DERIVADO DA PRODUÇÃO DE BIODIESEL EM MEIOS POROSOS RADIANTE / EXPERIMENTAL STUDY OF LPG COMBUSTION OF GLYCEROL AND RESIDUAL DERIVED FROM BIODIESEL PRODUCTION IN RADIANT POROUS MEDIA
The increasing production of biodiesel has caused increased production of residue glycerol. The large amount of glycerin (our glycerol) in the market causes a surplus unusable commercially and industrially, which should give a correct destination. At this point, the porous combustion is characterized by burning within an inert medium, to the pollutants reduc
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 04/05/2012
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10. Estudo da combustão direta da glicerina bruta e loira como alternativa de aproveitamento energético sustentável / Study of the direct combustion of crude and technical glycerin as an alternative sustainable energy use
Nesta tese investiga-se e avalia-se a combustão direta da glicerina bruta e loira, co-produto e derivado, respectivamente, do processo de fabricação do biodiesel como alternativa de aproveitamento energético sustentável. Focaliza-se especialmente nos aspectos ambiental, técnico e econômico considerando as emissões, a transferência de calor associada
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 10/11/2011
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11. Avaliação de catalisadores na reação de desidratação do glicerol
Problemas ambientais gerados devido ao uso generalizado de combustíveis fósseis têm levado a busca por novas alternativas energéticas. Nesse contexto, o biodiesel, surge como um combustível de grande interesse. Entretanto, o aumento na produção deste biocombustível acarreta a produção de grandes quantidades de glicerol, que por sua vez, desponta co
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 29/07/2011
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12. Caracterização e quantificação de contaminantes em aguardentes de cana
The objective of the present study was the evaluation of the presence of organic and inorganic contaminants in samples of aged cachaça from the South of the state of Minas Gerais. Furfural, methanol and copper were determined by colorimetric reactions, while the analyses of ethyl carbamate and acrolein were performed by GC/MS and HPLC, respectively. High le
Química Nova. Publicado em: 2011