Voltammetry
Mostrando 1-12 de 483 artigos, teses e dissertações.
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1. Enhanced Catalytic Performance of Strontium-Doped Lanthanum Manganites by the Presence of Molybdenum Oxides for Electro-Reduction of Hydrogen Peroxide
In this work, two catalysts, lanthanum manganite strontium-doped perovskite without (LSM) and with (LSMMO) mixed molybdenum oxides, were synthesized by the sol-gel route and deposited by immersion in carbon cloth substrates. Their performance as cathodes in the hydrogen peroxide reduction reaction (HPRR) and oxygen reduction reaction (ORR) was investigated t
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Chemometric Evaluation of Poly(3-hexylthiophene) Electrochemical Aging Path as a Function of Electrochemical Synthesis Variables
Conductive polymers are versatile materials that can be applied in many different technology fields, especially green energy. They have several advantages, such as easy synthesis, low density, and cost. However, its electric conduction property is also related to material aging with great loss of their characteristics, limiting their applicability. The in-de
Journal of the Brazilian Chemical Society. Publicado em: 2022
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3. Additive Manufacturing towards the Fabrication of Greener Electrochemical Sensors for Antioxidants
Additive manufacturing is an emerging tool that has contributed to the sustainable fabrication of devices in several areas based on the concept of “zero waste”. Considering extrusion-based manufacturing (or 3D printing), polylactic acid (PLA) has been highlighted due to its biodegradability, obtention from renewable sources, and compatibility for 3D prin
Journal of the Brazilian Chemical Society. Publicado em: 2022
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4. Graphite-Polyurethane Composite Electrode Modified with Molecularly Imprinted Polymer for Determination of Diclofenac
A molecularly imprinted polymer (MIP) was prepared using the anti-inflammatory diclofenac (DCF) as a template. A non-imprinted polymer (NIP) was also prepared as a control. These MIP and NIP were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET), revealing a higher porosity in the fir
Journal of the Brazilian Chemical Society. Publicado em: 2022
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5. Electrochemical Determination of Trifluralin Herbicide Using Silver Solid Amalgam Electrode: Application in Fresh Food Samples
This paper reports the use of polished silver solid amalgam electrode (p-AgSAE) allied to square wave voltammetry (SWV) in the development of a simple, sensitive, fast and green electroanalytical methodology for the trifluralin herbicide determination in fresh food samples. The experimental (supporting electrolyte and potential and time accumulation) and vol
J. Braz. Chem. Soc.. Publicado em: 2021-07
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6. Synthesis of Triazoles by Electro-Assisted Click Reaction Using a Copper Foil Electrode
This paper presents an innovative pathway for the synthesis of triazoles using the well-known “click chemistry” assisted by the electrochemical oxidation of metallic Cu0. The click reaction is used to couple a wide range of biological interest compounds. In this case, faster and less polluting methods for a biological environment was achived by in situ C
J. Braz. Chem. Soc.. Publicado em: 2021-07
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7. Thallium Associated with Manganese Ore Tailings in a Deactivated Mine in the Western Region of Bahia, Brazil
Thallium (Tl) is a rare metal with toxic effects notably harmful to human health and the environment. In this article, the natural occurrence of Tl was evaluated in a deactivated manganese mine located in the western region of Bahia, Brazil. The extraction procedure with aqua regia was used to dissolve the soil, sediment, and tailings samples. The Tl content
J. Braz. Chem. Soc.. Publicado em: 2021-05
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8. Voltammetric Generation and Kinetic Stability of Nitro Anion Radical from Nitrofurazone in Ionic Liquids
The nitrofurazone (NF) electrochemical reduction has been studied by cyclic voltammetry (CV) and square wave voltammetry (SWV) in non-aqueous medium using three different ionic liquids (IL): BMImTf2N, BMImBF4 and BMMImTf2N, having a carbon fiber microelectrode as working electrode. In all of them, two reversible cathodic peaks were recorded for NF. Under hig
J. Braz. Chem. Soc.. Publicado em: 2021-04
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9. Magnetic and Mesoporous Silica-Niobia Material as Modifier of Carbon Paste Electrode for p-Nitrophenol Electrochemical Determination
In the present work, the sol-gel synthesis method was employed as strategy to obtain a magnetic and mesoporous silica-niobia material. The planned synthesis was based on the hetero-condensation of niobium and silicon alkoxide precursors, in the presence of spherical magnetite particles. The resulting material presented interesting characteristics such as mag
J. Braz. Chem. Soc.. Publicado em: 2021-03
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10. INFLUÊNCIA DA FORÇA IÔNICA NA ESTIMATIVA DE pKa POR MÉTODO VOLTAMÉTRICO
The voltammetry is an important analytical technique and also useful for pKa determination. It is a usual procedure of this technique to employ inert electrolyte concentration 100 times higher than redox compound concentration further a pH buffer. However, the ionic strength changes with the solution pH. In this work, we study the consequences of this proced
Quím. Nova. Publicado em: 2020-12
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11. Tópicos Emergentes em Insuficiência Cardíaca: Terapias Intervencionistas na Insuficiência Cardíaca
In this paper a novel supramolecular strategy to improve the efficiency of a voltammetric sensor to determine two biologically relevant molecules (epinephrine (EP) and uric acid (UA)) is presented. The strategy is based on the use of a glassy carbon electrode modified with a copper(II) complex ([Cu(H2dimpy)Cl]PF6) adsorbed on multi-walled carbon nanotubes (M
Arq. Bras. Cardiol.. Publicado em: 2020-11
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12. Synergistic Supramolecular Effect on the Electro-Oxidation of Biological Relevant Molecules: A Novel Sensor for Simultaneous Determination of Epinephrine and Uric Acid in Human Urine Using MWCNT and a Copper(II) Complex
In this paper a novel supramolecular strategy to improve the efficiency of a voltammetric sensor to determine two biologically relevant molecules (epinephrine (EP) and uric acid (UA)) is presented. The strategy is based on the use of a glassy carbon electrode modified with a copper(II) complex ([Cu(H2dimpy)Cl]PF6) adsorbed on multi-walled carbon nanotubes (M
J. Braz. Chem. Soc.. Publicado em: 2020-11