Tin Iv
Mostrando 1-12 de 33 artigos, teses e dissertações.
-
1. PHNSNCL4-N SUPPORTED ON ACTIVATED CARBON AS NOVEL TIN-BASED CATALYSTS FOR ACETYLENE HYDROCHLORINATION
In this work, a series of PhnSnCl4-n (n = 1, 2, 3, and 4) based catalysts were prepared by incipient wetness impregnation using activated carbon (AC) as support and triphenyltin chloride (Ph3ClSn) and tin(IV) chloride (SnCl4) as Sn precursors. The obtained catalysts were systematically characterized by X-ray diffraction (XRD), N2 physisorption, Scanning elec
Quím. Nova. Publicado em: 26/08/2019
-
2. SÍNTESE E CARACTERIZAÇÃO DE NOVOS ORGANOMETÁLICOS DE ESTANHO (IV) COM LIGANTES DITIOCARBIMATOS E SUA AÇÃO ACCELERADORA NA VULCANIZAÇÃO DE BORRACHA NITRÍLICA
This paper describes the synthesis of four new organotin compounds of general formula: (Ph4P)[Sn(Cy)3(RSO2N=CS2)] [Ph4P = tetraphenylphosphonium cation, Cy = cyclohexyl, R = C6H5 (1), 4-ClC6H4 (2), 4-BrC6H4 (3) and 4-IC6H4 (4)]. They were obtained by the reaction between four different potassium N-R-sulfonyldithiocarbimate salts and tricyclohexyltin chloride
Quím. Nova. Publicado em: 2016-08
-
3. SAIS DE TETRAFENILFOSFÔNIO E TRIS(1,10-FENANTROLINA)FERRO(II) DE COMPLEXOS ANIÔNICOS DE DIBUTILESTANHO(IV) COM DITIOCARBIMATOS: SÍNTESE, CARACTERIZAÇÃO E ATIVIDADE ANTIFÚNGICA
Six new salts of organometallic complexes of tin(IV) with the general formulae: (Ph4P)2[Sn(Bu)2(RSO2N=CS2)2] and [Fe(phen)3][Sn(Bu)2(RSO2N=CS2)2] [Ph4P = tetraphenylphosphonium, R = CH3 (1), C2H5 (2) and C4H9 (3); Fe(phen)3 = tris(1,10-phenanthroline)iron(II), R = CH3 (4), C2H5 (5) and C4H9 (6)] were synthetized from potassium dithiocarbimates (RSO2N=CS2K2.H
Quím. Nova. Publicado em: 2016-06
-
4. Construção de sensores eletroquímicos utilizando como matriz materiais cerâmicos SI O IND. 2 / M IND. X O IND. Y , e materiais cerâmicos eletricamento condutores SI O IND. 2 / C/ M IND. X O IND. Y , preparados pelo processo sol-gel / Construction of electrochemical sensors using ceramic materials SI O IND. 2 / M IND. X O IND. Y and electrically conducting ceramic materials SI O IND. 2 /C/ M IND. X O IND. Y as matrix, prepared for the sol-gel process
This work describes the synthesis and characterization of three different materials: SiO2/SnO2, SiO2/SnO2/Sb2O5 and the film of Nb2O5 formed on the surface of the ceramic material SiO2/C obtained by sol-gel process and to use them as matrix in the development of electrochemical sensors. The mixed oxides, SiO2/SnO2, were synthesized using as source of SnO2, S
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 26/04/2012
-
5. Complexos metálicos de hidrazonas, tiossemicarbazonas e lapachol: atividade farmacológica e avaliação de relações estrutura-atividade
The present work comprises the synthesis and characterization of metal compounds with bioactive ligands and the study of their pharmacological profile. Anti-inflammatory, antimicrobial, antiparasitic and antitumor drug candidates were designed. Complex [Zn(LASSBio-466)H2O]2 was synthesized with salicylaldehyde-2-chlorobenzoyl hydrazone (H2LASSBio-466), while
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 10/02/2012
-
6. Construção de células solares sensibilizadas por corante a partir de nanoestruturas de ZnO obtidas por método hidrotermal / Construction of dye-sensitized solar cells from Nanostructures ZnO obtained by Method Hidroterma
The Photovoltaic (PV) sector has been facing an accelerated development rate within the last decade, which is comparable to the other renewable energy sources, according to the data released by the International Energy Agency (IEA). Therefore, a myriad of R&D activities and technological innovations are under way in order to cut down the manufacturing cost o
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 01/08/2011
-
7. Desenvolvimento de processos de eletrodos de porta (TaN e TiN) para dispositivos MOS / Process development of gate electrodes (TiN and TaN) for MOS devices
Tantalum nitride (TaN) and titanium nitride (TiN) films have been obtained by DC sputtering, using different nitrogen flow (10 - 80 sccm) and power (500 - 1500 W), in a nitrogen (N2)/argon (Ar) ambient on Si (100) substrates. The N2/Ar ratio in gas mixture and power effects on structural and electrical properties of TaN and TiN films were investigated by sca
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 01/07/2011
-
8. Obtenção e caracterização elétrica de filmes finos de SnO2:Sb / Deposition and electrical properties of sno2:sb films abstract
The growing demand for advanced electronic devices based on nanomaterials has motivated efforts to produce nanoscale building blocks with designed functions. Transparent conducting oxide nanocrystals (TCONs) are particularly promising for the development of such devices. TCONs synthesized in an organic medium play an important role as building blocks because
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 03/03/2011
-
9. Structural and microstructural characterization of tin(II) oxide useful as anode material in lithium rechargeable batteries obtained from a different synthesis route at room temperature
Tin (II) oxide has been proposed as potential anode material in lithium rechargeable batteries. Different methods to obtain such compound have been developed with relative difficulty due to the fact that Sn(II) is easily oxidized to Sn(IV). We have applied a different methodology to synthesize SnO-romarchite by modifying the solvent nature of the controlled
Materials Research. Publicado em: 03/06/2011
-
10. Desenvolvimento de catalisadores a base de estanho(IV), para produção de ésteres metílicos de ácidos graxos, via transesterificação e esterificação / Development of tin-based catalysts to produce methyl esters of fatty acid via transesterification and esterification.
Neste trabalho foi investigada a atividade catalítica de quatro complexos metálicos exibindo caráter ácido de Lewis: dibutildiacetato de estanho, dibutildilaurato de estanho, óxido de dibutil estanho e ácido butilestanóico. Esses complexos catalíticos foram testados na alcoólise do óleo de soja e de mamona, visando a obtenção de uma mistura de é
Publicado em: 2010
-
11. Obtenção e caracterização de materiais catalisadores da oxidação de contaminantes em solução aquosa
"Sn" and "Al" materials, with different reasons in Sn/Al2O3 mass were obtained, characterized and tested as catalysts for the oxidation of indigo carmine dye. The characterization of the materials confirmed the presence of Sn (IV) in all samples. It was observed only one phase, the SnO2. The particle size obtained was 22 to 36 nm. The photocatalytic tests sh
Publicado em: 2010
-
12. Síntese e caracterização de complexos de estanho com ditiocarbimatos derivados de sulfonamidas, e estudo de sua atividade antifúngica para Colletotrichum gloeosporioides / Syntheses and characterization of tin complexes with dithiocarbimates derived from sulphonamides and study of the antifungal activity againstaColletotrichum gloeosporioides
Este trabalho envolve a síntese e caracterização por análise elementar; espectroscopias vibracional na região do infravermelho, de ressonância magnética nuclear de 1H e 13C e Mössbauer de 119Sn de complexos aniônicos de estanho(IV) com ditiocarbimatos derivados de sulfonamidas. Oito complexos de fórmula geral: [Sn(RSO2N=CS2)3]2- (R= CH3, CH2CH3, (C
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 19/02/2009