Stationary Phase Chromatography
Mostrando 1-12 de 179 artigos, teses e dissertações.
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1. Per-Aqueous Liquid Chromatography for the Separation of Polar Compounds Preparation and Characterization of Poly(ethylene oxide co dimethylsiloxane) Based Stationary Phase
Poly(ethylene oxide-co-dimethylsiloxane) was thermally immobilized on silica particles-Si(PEO)-to separate small polar compounds with water-rich mobile phases. Poly(ethylene oxide-co-dimethylsiloxane) content on Si(PEO) stationary phase was optimized using a central composite design. Infrared spectroscopy, scanning electron microscopy, and thermogravimetric
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Development and application of a test mixture for untargeted liquid chromatography-mass spectrometry analysis of urine samples
Metabolic profiling of complex biological matrices based on liquid chromatography-mass spectrometry (LC-MS) allows detecting a wide range of metabolites with distinct concentrations and physicochemical properties. Given the complexity of samples and the necessity of a comprehensive approach in untargeted metabolomics, quality control strategies are mandatory
Química Nova. Publicado em: 2022
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3. AVALIAÇÃO DE ADITIVOS DE FASE MÓVEL E TEMPERATURA NA VIDA ÚTIL DE COLUNAS PARA CROMATOGRAFIA LÍQUIDA DE ALTA EFICIÊNCIA
Buffered solutions, additives, and column temperature are widely used in high-performance liquid chromatography to promote adequate retention of compounds and to improve the chromatographic separation. However, these factors can dramatically reduce the column lifetime. In this work, the effect of column temperature, pH and the salt type and concentration in
Quím. Nova. Publicado em: 2020-03
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4. Simultaneous determination of anti-diabetic drugs
A novel reverse phase, isocratic HPLC method is described to separate five anti-diabetic drugs i.e., glimepiride, metformin, sitagliptin, rosiglitazone and pioglitazone. Nucleosil C18 analytical column was used as stationary phase, while mobile phase consisted of acetonitrile:phosphate buffer: methanol (40/40/20, v/v) pH 2.0. Effluent was monitored at a flow
Braz. J. Pharm. Sci.. Publicado em: 20/12/2019
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5. SBSE(EG-Silicone)-UFLC-MS/MS and HPLC-Flu Analysis of Norharman in Passiflora edulis Rinds
Previous studies on Passiflora edulis (sour passion fruit) rinds reported some biological activities and there is a growing interest on rinds flour as a possible functional food, but its alkaloid composition was not detailed investigated. This work reports on for the first time in the literature the identification of norharman in P. edulis rinds, by using st
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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6. Synthesis of Hybrid Monolithic Columns Using a Click Chemistry Reaction for Application in Capillary Liquid Chromatography
Hybrid monolithic columns present characteristics of both silica and organic monoliths, such as good mechanical properties, wide pH tolerance, high permeability and stability and little swelling or shrinkage. A common way to prepare this type of material is by using alkoxysilanes and organic monomers via the sol-gel process and click chemistry reactions. In
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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7. Chemical Composition and Anti-Inflammatory Activity of the Decoction from Leaves of a Cultivated Specimen of Myracrodruon urundeuva
Myracrodruon urundeuva (Anacardiaceae) is the scientific designation of “aroeira-do-sertão”, a tree well dispersed at the northeastern Brazil. The medicinal use of this plant is widespread throughout the rural population and the inner trunk bark decoction is used to treat cutaneous affections, urinary and respiratory diseases, and gynecological problems
J. Braz. Chem. Soc.. Publicado em: 12/08/2019
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8. ARTIFACTS IN THE ANALYSIS AND ASSESSMENT OF LOW-COST CONTAINERS FOR SAMPLING AND STORING GREENHOUSE GASES
The objectives of this study were twofold: to assess two chromatographic methods for the analysis of greenhouse gases (GHG) and carbon monoxide, and to propose and evaluate a low-cost and reusable alternative system for their sampling and storage, using 10 different container configurations (flasks and bags). To that end, standard samples containing the gase
Quím. Nova. Publicado em: 2019-01
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9. Arsenic Speciation in Fish and Rice by HPLC-ICP-MS Using Salt Gradient Elution
This paper presents arsenic speciation studies by high-performance liquid chromatography with inductively coupled plasma-mass spectrometer (HPLC-ICP-MS) using a chromatography column containing a strong anion exchange stationary phase (Agilent Bio SAX G3154A/101) for determination of arsenobetaine (AsB), dimethylarsinic acid (DMA), AsIII, monomethylarsonic a
J. Braz. Chem. Soc.. Publicado em: 2018-08
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10. Study on the Mixed-Mode HPLC Separation of Shuang-Huang-Lian and Xue-Bi-Jing Injections Based on an Ionic Liquid Column
Both Shuang-Huang-Lian and Xue-Bi-Jing injections are clinically proven efficient and low cost medicines. However, the studies of their chromatographic separation are limited. In this study, a column based on ionic liquid stationary phase was applied for the first time for the analysis of these two injections. For Shuang-Huang-Lian injection, U-shaped plots
J. Braz. Chem. Soc.. Publicado em: 2018-07
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11. Determination of Enantioselectivities by Means of Chiral Stationary Phase HPLC in Order to Identify Effective Proline-Derived Organocatalysts
The pyrrolidine fragment is a privileged scaffold within chiral ligands employed in coordination complexes exhibiting catalytic activity in asymmetric reactions and, more recently, as enantioselective organocatalysts per se. Likewise, the employment of (S)-proline as starting material constitutes the most direct form to synthesize those chiral derivatives. A
J. Braz. Chem. Soc.. Publicado em: 2018-05
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12. Targeted-Analysis of β-Carboline Alkaloids in Passionfruit (“Maracujá”) by SBSE(PDMS)-LC/Flu and UHPLC-MS
Samples of pulp and seeds of sour (P. edulis) and sweet (P. alata) passionfruit were subjected to targeted analysis to identify β-carboline alkaloids, using combined UHPLC-MS (ultrahigh performance liquid chromatography-mass spectrometry) and SBSE(PDMS) (stir bar sorption extraction using polydimethylsiloxane as stationary phase) for sample preconcentration
J. Braz. Chem. Soc.. Publicado em: 2018-04