Solid Phase Preconcentration
Mostrando 1-12 de 67 artigos, teses e dissertações.
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1. Dispersive Solid-Phase Extraction Using 3-Mercaptopropyltrimethoxysilane Functionalized Magnetic MWCNT-Based Nanocomposite for Selective and Efficient Preconcentration of Pb2+ with FAAS Determination
A novel nanocomposite based on magnetic multiwalled carbon nanotubes coated with SiO2 and functionalized with 3-mercaptopropyltrimethoxysilane (3-MPTMS) was prepared for the efficient extraction and quantification of lead ions from water samples. The adsorption capacity of this adsorbent could reach 1.995 mg g-1 Pb2+ in an equilibrium time of 30 min. Under o
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Reduced Graphene Oxide-Cadmium Sulfide Quantum Dots Nanocomposite Based Dispersive Solid Phase Microextraction for Ultra-Trace Determination of Carbamazepine and Phenobarbital
This research presents a fast, sensitive, and selective ultrasound-assisted dispersive solid phase microextraction technique for simultaneous preconcentration and determination of ultra-trace amount of carbamazepine and phenobarbital. Reduced graphene oxide sheets decorated with cadmium sulfide quantum dots was synthesized, characterized, and used as a high
J. Braz. Chem. Soc.. Publicado em: 2021-04
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3. Multiresidue Determination of Endocrine Disrupting Compounds in Sewage Treatment Plants (SPE-HPLC-DAD)
This work focuses on the validation and application of solid phase extraction followed by high-performance liquid chromatography (SPE-HPLC) analysis of important endocrine disruptors compounds (EDC) from different classes in highly complex wastewater matrix. The endocrine disruptors investigated included three different categories: pharmaceuticals (sulfameth
J. Braz. Chem. Soc.. Publicado em: 2020-12
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4. AVALIAÇÃO DE NANOTUBOS DE CARBONO FUNCIONALIZADOS VISANDO O DESENVOLVIMENTO DE MÉTODOS DE PRÉ-CONCENTRAÇÃO DE ÍONS METÁLICOS E DETERMINAÇÃO POR TÉCNICAS ESPECTROMÉTRICAS E ELETROANALÍTICAS
This review focuses on the use of functionalized carbon nanotubes (CNTs) on the development of preconcentration methods with substantial contributions on selectivity and sensitivity for metal ions determination. CNTs have been usually employed in the development of preconcentration/speciation coupled to spectroanalytical techniques for ions determination at
Quím. Nova. Publicado em: 2020-09
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5. A Choline Chloride-Ethylene Glycol Deep Eutectic Solvent Based on Magnetic Polydopamine with Preconcentration and Determination for Sulfonylurea Herbicides in Water Samples
In this study, a novel deep eutectic solvent (DES) containing choline chloride and ethylene glycol was synthesized, and the magnetic polydopamine (PDA) was modified with this deep eutectic solvent to form Fe3O4@PDA-DES. Fourier transformed infrared spectroscopy, scanning electron microscopy, and vibrating sample magnetometer were used to characterize the pro
J. Braz. Chem. Soc.. Publicado em: 2020-07
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6. Solid Phase Extraction Using SiO2/Al2O3/TiO2 Ternary Oxide for Cu2+ Preconcentration
The present work aims at studying the preconcentration of Cu2+ ions by solid phase extraction using SiO2/Al2O3/TiO2 ternary oxide as adsorbent material. This methodology consists of the affinity of the analyte for the adsorbent material and its subsequent elution with the least amount of solvent. Subsequently, the aqueous phase containing the extracted analy
J. Braz. Chem. Soc.. Publicado em: 04/07/2019
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7. Dispersive Solid Phase Extraction Headspace Sampling in Gas Chromatography-Mass Spectrometric Analysis of Volatiles: Application to Separation of Polycyclic Aromatic Hydrocarbons
For the first time, dispersive solid phase extraction combined with headspace sampling was introduced and applied to separation and pre-concentration of polycyclic aromatic hydrocarbons (PAHs) as representative of volatile and semi-volatile compounds, from aqueous solutions and sediments using multiwall carbon nanotubes (MWCNTs). After adsorption, PAHs were
J. Braz. Chem. Soc.. Publicado em: 2019-04
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8. Synthesis of Chelating Agent Free-Solid Phase Extractor (CAF-SPE) Based on New SiO2/Al2O3/SnO2 Ternary Oxide and Application for Online Preconcentration of Pb2+ Coupled with FAAS
A new online solid phase preconcentration method using the new SiO2/Al2O3/SnO2 ternary oxide (designated as SiAlSn) as chelating agent free-solid phase extractor (CAF-SPE) coupled to flame atomic absorption spectrometry (FAAS) for Pb2+ determination at trace levels in different kind of samples is proposed. The solid adsorbent has been characterized by Fourie
J. Braz. Chem. Soc.. Publicado em: 2018-06
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9. Magnetic Solid-Phase Extraction Combined with Dispersive Liquid-Liquid Microextraction Followed by HPLC for Determination of Four Aromatic Amines Released from Azo Dyes in Paper Samples
A novel extraction technique combining dispersive liquid-liquid microextraction (DLLME) with magnetic solid-phase extraction (MSPE) is presented for pre-concentration of four primary aromatic amines (PAAs) released from azo dyes in paper samples prior to high performance liquid chromatography (HPLC). n-Octanol was used as the extractant and hydrophobic oleic
J. Braz. Chem. Soc.. Publicado em: 2018-04
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10. Pre-Concentration and Separation of Perphenazine Using Picric Acid Loaded α-Fe2O3 Nanoparticles: HPLC Syringe Filter as the Particles Support
Suspension of picric acid (PA) loaded iron oxide nanoparticles (PA-IONPs) was injected on the top of a 0.2 µm HPLC (high-performance liquid chromatography) syringe filter. The immobilized nanoparticles were used as SPE (solid phase extraction) sorbent for perphenazine separation and pre-concentration. By passing perphenazine solution through the filter, a m
J. Braz. Chem. Soc.. Publicado em: 2017-11
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11. Sensitive Estrogens Determination in Wastewater Samples by HPLC and Fluorescence Detection
A sensitive high-performance liquid chromatography-fluorescence detection method (HPLC-FLD) was developed and validated for 17β-estradiol (E2) and 17α-ethinylestradiol (EE2) determination in wastewater samples. Sample preparation was performed by solid-phase extraction (SPE) on Hypersep C18 cartridges. Conditioning and elution solvents and sample volume we
J. Braz. Chem. Soc.. Publicado em: 2017-08
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12. Problemas en el análisis de metilsiloxanos volátiles (VMS): origen y soluciones
Volatile methylsiloxanes (VMS) are pollutants widely distributed in the environment due to its extensive uses and high volatility. The analysis of these compounds is commounly performed by gas chromatography - mass spectrometry (GC-MS), and it is dificult due to the presence of background contamination and volatile losses. Different preconcentration techniqu
Quím. Nova. Publicado em: 2017-02