Small Molecule Structure
Mostrando 1-12 de 300 artigos, teses e dissertações.
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1. Estudo dos componentes protéicos da peçonha da serpente Micrurus frontalis (serpentes: elapidae)
Coral snakes (Micrurus genus) venoms contain a wide spectrum of biologically active proteins and peptides. The major obstacle to study Micrurus venoms is the small amount of material that can be collected. Therefore, the biochemistry and pharmacology of components from coral snakes venoms are mostly unknown. In this study we describe the isolation, molecular
Publicado em: 2010
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2. Propriedades física de molécilas orgânicas e compostos do tipo perovskita CdSiO3 e CaPbO3
In the first part of this work our concern was to investigate the thermal effects in organic crystals using the theory of the polarons. To analyse such effect, we used the Fröhlichs Hamiltonian, that describes the dynamics of the polarons, using a treatment based on the quantum mechanics, to elucidate the electron-phonon interaction. Many are the forms to a
Publicado em: 2009
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3. Métodos simples de formação de monocristal de substância orgânica para estudo estrutural por difração de raios X
This work presents three operationally simple laboratory protocols for monocrystal growth of small-molecule organic compounds, which have been applied with success in the last ten years for the formation of single crystals for X-ray structural studies. In addition, five structure hints were formulated as general guidelines for selecting a small-molecule orga
Química Nova. Publicado em: 2008
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4. AnÃlise experimental de sistemas de refrigeraÃÃo operando com R-290 e R-600a como fluidos refrigerantes alternativos
Refrigerants CFC (chlorofluorocarbons), as R-12, deplete the ozone layer which protects the surface of the earth, due to the presence of chlorine in their structure. The HCFC (hydrochlorofluorocarbons), as R-22, also have chlorine in their molecule and must be replaced as a refrigerant fluid. In Europe, brand new equipments are not produced with HCFC-22, sin
Publicado em: 2008
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5. Synthesis and study of photoinduced properties of phenothiazine derivatives on biomimetic systems / Síntese e estudo das propriedades fotoinduzidas de derivados fenotiazínicos em sistemas biomiméticos
The effect of interfaces on photophysical and photochemical properties of methylene blue (MB) and its derivatives was studied in this work, aiming to emploit their potencial as photosensitizers (PS) in photodynamic therapy.The presence of MB in SDS solutions affect the micelle equilibrium decreasing the apparent critical micelle concentration of SDS from 7mm
Publicado em: 2008
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6. Estudos estruturais do domínio catalítico da proteína tirosina fosfatase eta de rato / Structural studies of the catalytic domain of the rat protein tyrosine phosphatase eta
The rat protein tyrosine phosphatase eta, rPTPeta, is a transmembrane RPTP, with an intracellular portion composed of a unique catalytic region. The rPTPeta and the human homolog DEP-1 are down-regulated in rat and human neoplastic cells, respectively. However, the malignant phenotype is reverted after exogenous reconstitution of rPTPeta, suggesting that its
Publicado em: 2008
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7. Estudo voltamétrico da interação dos íons Zn2+, Cu2+, Cd2+ e Pb2+ com a enzima catalase
Catalase (CAT), which is an important enzyme that catalyzes the decomposition of hydrogen peroxide (H O ) to water (H O) and oxygen (O ), contains 2 2 2 2 some metal binding sites (Cys, His). The binding of metal ions to CAT can change or stabilize its secondary structure, resulting in its inhibition or activation, respectively. The inhibition of CAT, which
Publicado em: 2007
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8. Interação de nanotubos de carbono com segmentos de DNA
Single- and double-stranded DNA (deoxyribonucleic acid) molecules can strongly bind to single-walled carbon nanotubes (SWNT) via non-covalent interactions. Under certain conditions, the DNA molecule spontaneously self-assembles into a helical wrapping around the tubular structure of the carbon nanotubes to form DNA/SWNT hybrids, which are both stable and sol
Publicado em: 2007
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9. Síntese e caracterização de substâncias semelhantes aos ácidos húmicos de carvão de eucalipto, e sua interação com diclorofenol, cálcio, manganês e alumínio / Synthesis and characterization of humic acid-like substances from eucalypt charcoal, and its interaction with diclorofenol, calcium, manganese and aluminium
A wide range of commercial products containing humic substances have been applied successfully in agricultural and environmental remediation systems. Regarding their beneficial remediation characteristics, there is a high potential to adsorb heavy metals and organic pollutants, thus reducing their bioavailability. Industrially, they are extracted from non-re
Publicado em: 2005
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10. N2 and CO2 Adsorption by TMA- and HDP-Montmorillonites
N2 and CO2 gases adsorption by tetramethylammonium(TMA)-montmorillonites and hexadecylpyridinium(HDP)-montmorillonites was carried out using volumetric equipment at 25 °C and 0.1 MPa. The addition of organic compounds to montmorillonites was 1 and 4 times the cation exchange capacity (CEC) of the montmorillonites and the contact times between the TMA (or HD
Materials Research. Publicado em: 2002-10
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11. Identificação e caracterização de glubulina, albumina e lectina, e analise destas durante a formação e germinação da semente de tres variedades de Phaseolus vulgaris
Seeds of Phaseolus vulgaris cv. Norh, Jalo and Ouro Negro were analyzed for several aspects: contents of total protein and protein fractions (albumins, globulins, lectins), electrophoretic banding patterns, carbohydrate content and haemagglutinating activity of the lectin fractions. In addition, the accumulation of these fractions during seed maturation and
Publicado em: 1994
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12. An introduction to the methodology of structure determination by single crystal x-ray diffraction: applications to some complexes of lanthanides and transition metals with organic ligands / Introdução aos métodos de determinação de estruturas por difração de raios-X em monocristais: aplicação a alguns complexos de lantanídeos e metais de transição com ligantes orgânicos
The crystal structure of the complexes Ln(ClO4)3.6[PONH2(C6H5)2] where Ln=Eu, La, Cu[NH2(CH3)2CCO2]2, NiBr2.4[AsO(C6H5)3].8H2O (green), NiBr2.4[AsO(C6H5)3.1,5(CH3C6H5).H2O (orange) and of the ligand PONH2(C6H5)2 have been determined by X-ray diffraction. The complexes involving lanthanide ions refined to final R factors of R(Eu)=0.125 and R(La)=0.133 and the
Publicado em: 1983