Rhenium
Mostrando 1-12 de 29 artigos, teses e dissertações.
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1. Lowered serum cesium levels in schizophrenia: association with immune-inflammatory biomarkers and cognitive impairments
Objectives: A previous study has shown that schizophrenia (SCZ) is accompanied by lowered levels of trace/metal elements, including cesium. However, it is not clear whether changes in cesium, rubidium, and rhenium are associated with activated immune-inflammatory pathways, cognitive impairments, and the symptomatology of SCZ. Methods: This study measured c
Braz. J. Psychiatry. Publicado em: 2021-04
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2. Supramolecular Approach in Energy Conversion Devices
This review summarizes investigations carried out at the Laboratory of Photochemistry and Energy Conversion (LFCE) in the University of São Paulo dealing with design and characterization of ruthenium(II), rhenium(I) and iridium(III) polypyridine complexes with desired photochemical and photophysical properties in light of the development of optoelectronics
J. Braz. Chem. Soc.. Publicado em: 2020-11
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3. Uso de procesos pirometalúrgicas para la obtención de renio
ABSTRACT Rhenium is a metal that has different obtainment methods. The most used comes from molybdenite roasting. Traditional pyrometallurgical methods like oxidizing roasting are applied, but there are also innovative pyrometallurgical methods as is roasting with carbothermic reduction. This paper presents the behavior of rhenium onto two different roasting
Matéria (Rio J.). Publicado em: 19/07/2018
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4. Influence of the Protonatable Site in the Photo-Induced Proton-Coupled Electron Transfer between Rhenium(I) Polypyridyl Complexes and Hydroquinone
In the present work the influence of the distance of the protonatable site of different ancillary ligands to the metal center on the luminescence quenching of ReI polypyridyl complexes by hydroquinone are evaluated by means of experimental and theoretical studies. In these systems, it is expected the occurrence of proton-coupled electron transfer (PCET) reac
J. Braz. Chem. Soc.. Publicado em: 2017-09
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5. A importância do estado excitado 3MLCT de compostos de Ru(II), Re(I) e Ir(III) no desenvolvimento de fotossensores, oleds e fotorredução de CO2
The photochemistry and photophysics of coordination compounds have been extensively investigated not only because their structure, stability, reactivity dependence on the metal center oxidation state and the coordinated ligand; but also for their electronic transitions in a wide range of visible radiation. The knowledge of light absorption, excited state dea
Quím. Nova. Publicado em: 2017-02
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6. Rhenium(I) Polypyridine Complexes as Luminescence-Based Sensors for the BSA Protein
The binding interaction of rhenium(I) complexes fac-[Re(CO)3(NN)(py)]+, py = pyridine and NN = 1,10-phenanthroline (phen), 4,7-diphenyl-1,10-phenanthroline (ph2phen) or 4,7-dichloro-1,10-phenanthroline (Cl2phen), and bovine serum albumin (BSA) was investigated at physiological pH using emission intensity variation and circular dichroism (CD) spectroscopy. Th
J. Braz. Chem. Soc.. Publicado em: 2016-01
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7. Quelato-complexos de rênio e tecnécio com potencial aplicação medicinal / Rhenium and technetium chelate-complexes of potential medicinal application
Neste trabalho foram estudadas as formas de coordenação de piridinonas, ditiocarbazatos e N-(N\ \ ,N\ \ -dialquilaminotiocarbonil)-N\ -(2-hidroxifenil)benzoamidinas aos centros metálicos Re (V) e Tc (V). Neste sentido, os complexos triclorobis(trifenilfosfina)oxorrênio(V), [ReOCl3(PPh3)2]57, tribromobis(trifenilfosfina)oxorrênio(V), [ReOBr3(PPh3)2]57, e
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 11/05/2012
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8. Estudo comparativo da marcação do anticorpo anti-CD20 com 188Re / Comparative studies of antibody anti-CD20 labeled with 188Re
A Medicina Nuclear é uma modalidade de particular importância em oncologia e a investigação de novos radiofármacos direcionados a tumores, seja para diagnóstico e/ou terapia, é uma área de interesse para os pesquisadores. Rituximab (RTX) é um anticorpo monoclonal (AcM) quimérico (IgG 1) que se liga especificamente ao antígeno CD20 com alta afinida
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 24/02/2010
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9. Desenvolvimento de catalisadores nanoparticulados do tipo Pt-M1-M2(M1 e M2 = Sn e Re) para aplicação em células a combustível direta de etanol / Development of catalysts nanoparticles of type Pt-M1-M2 (M1 and M2 and Re + Sn) for application in the direct ethanol fuel cell
Neste trabalho foi investigada a eletrooxidação de etanol sobre eletrodos nanoparticulados binários Pt-M1 (M1 = Sn ou Re) e ternários Pt-M1-M2 (M1 e M2 = Sn e Re) suportados em carbono. Estes materiais foram preparados pelo método da redução por álcool e foram caracterizados por difração de raios-X e microscopia eletrônica de varredura associada a
Publicado em: 2008
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10. Study of organic light-emitting devices using rare earth and transition metals complexes. / Estudo de dispositivos orgânicos emissores de luz empregando complexos de terras raras e de metais de transição.
This work presents the study of the Rare Earth (RE) and Transition Metals (TM) complexes, as emissive layers of Organic Light-Emitting Devices (OLEDs) designed, built and electro-optically characterized. The thin films were thermally evaporated or spin-coated. This research started with the study of Europium complex changing its central ligand (CL), which sh
Publicado em: 2008
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11. Caracterização espectroscopica de catalisador a base de renio suportado em silica-alumina, modificado com oxido de boro e agentes alquilantes / Spectroscopic characterization of a rhenium oxide catalyst supported on borated silica-alumina and modified whit alkylating agents
Os catalisadores heterogêneos à base de rênio constituem-se importantes sistemas na metátese de ésteres insaturados provenientes dos óleos vegetais. No entanto, os sistemas heterogêneos à base de rênio são ativos na metátese de olefinas funcionalizadas somente se forem combinados com um promotor do tipo SnR4 ou PbR4. Acredita-se que o promotor tem
Publicado em: 2007
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12. Sistemas químicos integrados via complexos de rênio(I) e rutênio(II) na conversão de energia / Chemical integrated systems via rhenium and ruthenium complexes on energy conversion
The focus of this work is on two chemical integrated systems: dye-sensitized solar cells, Dye-Cells®, and photosensors based on rhenium(I) compounds. Novel ruthenium(II) compounds were synthesized, characterized and investigated as dye-sensitizers. The results of solar cells sensitized by cis-[(H3BCN)2Ru(dcbH2)2], H3BCN- = cyanoborohydride, dcbH2 = acid-4,4
Publicado em: 2007