Polymer Electrolyte
Mostrando 1-12 de 46 artigos, teses e dissertações.
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1. Chemometric Evaluation of Poly(3-hexylthiophene) Electrochemical Aging Path as a Function of Electrochemical Synthesis Variables
Conductive polymers are versatile materials that can be applied in many different technology fields, especially green energy. They have several advantages, such as easy synthesis, low density, and cost. However, its electric conduction property is also related to material aging with great loss of their characteristics, limiting their applicability. The in-de
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. New Insights into the Partitioning of Phenothiazine Dyes in Aqueous Two-Phase Systems
Aqueous two-phase systems (ATPSs) have proven to be efficient and environmentally safe methods for extracting chemical species. However, the driving forces behind the partition of solutes in these systems are still little understood. A complete thermodynamic partitioning of phenothiazine dyes was investigated in poly(ethylene oxide) (PEO) + salt + water ATPS
J. Braz. Chem. Soc.. Publicado em: 2020-08
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3. A Sustainable Methodology to Extract Bismuth from Secondary Sources
Bismuth is a critical metal broadly used in cosmetic, medicine and metallurgy. However, its scarcity in Earth’s crust may impair further applications. An alternative is to recover bismuth from secondary sources. In this work, a methodology to extract bismuth from safety valves of discharged gas cylinders is proposed. Extraction and purification of bismuth
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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4. Transmissive to Dark Electrochromic and Fluorescent Device Based on Poly(fluorene-bisthiophene) Derivative
Films of a poly(fluorene-bisthiophene) derivative, named PFBT, were electrodeposited onto indium tin oxide (ITO) electrodes and their electrochromic and fluorescence properties were investigated. Such films displayed color variation from yellow, in the neutral state, to green, in the oxidized state, as shown by tracking of the CIE (Commission Internationale
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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5. Application of Zinc Oxide in Hybrid Solar Cells Using a P3HT and P3OT Polymer Junction as Charge Carrier
Hybrid solar cells show an increasing number in researches due to its low cost and easy of production. They are composed by and organic material and a semiconductor oxide. The aim of this paper was to synthesis and characterize zinc oxide by coprecipitation and apply it in a hybrid solar cell that uses a P3HT/P3OT copolymer as charge carrier. The cell was as
Mat. Res.. Publicado em: 01/07/2019
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6. Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell
A new sulfonated poly(aromatic imide-co-aliphatic imide) (SPI) for the use as a polymer electrolyte membrane was successfully synthesized from 4,4'-diaminodiphenylmethane (DDM), 4,4'-diaminodiphenylmethane-2,2'-disulfonic acid disodium salt (S-DDM), hexamethylenediamine, and 3,3',4,4'-benzophenonetetracarboxylic dianhydride in a one-step reaction. S-DDM was
Mat. Res.. Publicado em: 18/12/2017
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7. Thermal and Conductivity Studies of VO2+ Doped Methacrylic Acid - Ethyl Acrylate (MAA:EA) Copolymer Films
New polymer electrolyte films of Methacrylic Acid - Ethyl Acrylate (MAA:EA) copolymer embedded with different concentrations of VO2+ ions were prepared by solution casting technique. Thermal properties of these films were investigated employing differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Electrical conductivity of the films
Mat. Res.. Publicado em: 23/10/2017
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8. Preparation and Characterization of an Eco-Friendly Polymer Electrolyte Membrane (PEM) Based in a Blend of Sulphonated Poly(Vinyl Alcohol)/ Chitosan Mechanically Stabilised by Nylon 6,6
Abstract Membranes for fuel cell applications were prepared using two polymer blends: poly(vinyl alcohol) (PVAL) and chitosan (CS), 80/20 (w/w) and 60/40 (w/w) with and without nylon. Sulfosuccinic acid (SSA) was used both as a crosslinking and a sulfonating agent. An increasing in the SSA content raised ionic exchange capacity and consequently proton conduc
Mat. Res.. Publicado em: 21/07/2016
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9. Spectroelectrochemistry of Intrinsically Conducting Selenophene-3-Chlorothiophene Copolymers
The electrochemical copolymerization between selenophene and 3-chlorothiophene monomers was successfully realized. The influence of the applied polymerization potential and the monomer feed ratio on the copolymer properties were investigated, and the results revealed that the obtained polymer films strongly depended on the polymerization conditions. The obta
J. Braz. Chem. Soc.. Publicado em: 2016-05
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10. CÉLULAS SOLARES SENSIBILIZADAS POR CORANTES NATURAIS: UM EXPERIMENTO INTRODUTÓRIO SOBRE ENERGIA RENOVÁVEL PARA ALUNOS DE GRADUAÇÃO
An interesting practical experiment about the preparation of dye–sensitized solar cells (DSSC) using natural dyes were carried out by the undergraduate students in the chemistry course at UNICAMP . Natural dyes were extracted from blueberries (Vaccinium myrtillus L.), jabuticabas (Myrciaria cauliflora), raw and cooked beets (Beta vulgaris L.), and annattos
Quím. Nova. Publicado em: 2015-12
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11. Synthesis and characterization of poly(S-2-mercaptoethyl 2-(thiophen-3-yl)ethanethioate) by electrochemical polymerization
Abstract A novel monomer of S-2-mercaptoethyl 2-(thiophen-3-yl)ethanethioate (MTE) were synthesized via esterification reaction between 2-(thiophen-3-yl)acetic and ethane-1,2-dithiol in the presence of dicyclohexyl-carbodiimide (DCC) and N,N’-dimethylpyridin-4-amine (4-DMAP) as catalytic system. The structure of monomer was characterized via MS, 1H-NMR and
Polímeros. Publicado em: 2015-10
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12. Synthesis of Poly(Vinylferrocene) Perchlorate/Poly(3,3’-Diaminobenzidine) Modified Electrode in Dichloromethane for Electroanalysis of Hydroquinone
Poly(vinylferrocenium) perchlorate-poly(3,3’-diaminobenzidine) (PVF+ClO4–-PDAB) composite film was synthesized electrochemically for the first time on Pt disc electrode in a dichloromethane solution containing poly(vinylferrocene) (PVF) polymer, 3,3’-diaminobenzidine (DAB) monomer and tetrabutylammonium perchlorate as supporting electrolyte. This modif
J. Braz. Chem. Soc.. Publicado em: 2015-09