Synthesis and characterization of poly(S-2-mercaptoethyl 2-(thiophen-3-yl)ethanethioate) by electrochemical polymerization

AUTOR(ES)

Nguyen, Ha Tran, Nguyen, Le-Thu Thi

FONTE

Polímeros

DATA DE PUBLICAÇÃO

2015-10

RESUMO

Abstract A novel monomer of S-2-mercaptoethyl 2-(thiophen-3-yl)ethanethioate (MTE) were synthesized via esterification reaction between 2-(thiophen-3-yl)acetic and ethane-1,2-dithiol in the presence of dicyclohexyl-carbodiimide (DCC) and N,N’-dimethylpyridin-4-amine (4-DMAP) as catalytic system. The structure of monomer was characterized via MS, 1H-NMR and 13C-NMR spectroscopies. The electrochemical polymerization of MTE monomer was performed in acetonitrile using lithium perchlorate (LiClO4) as electrolyte agent. The obtained polymer film (PMTE) was characterized via cyclic voltammetry and it exhibited the main oxidation peaks centered at +2V.

Documentos Relacionados

• Photochemistry of 3-alkoxychromones: photocyclisation of 2-aryl-6-chloro-3-{(thiophen-2-yl)methoxy}chromones
• Ultrasound-Promoted Synthesis of 3-(Thiophen-2-yl)-4,5-dihydro-1H-pyrazole-1-carboximidamides and Anticancer Activity Evaluation in Leukemia Cell Lines
• Synthesis, characterization and computational studies of (E)-2-{[(2-aminopyridin-3-yl)imino]-methyl}-4,6-di-tert-butylphenol
• Chemometric Evaluation of Poly(3-hexylthiophene) Electrochemical Aging Path as a Function of Electrochemical Synthesis Variables
• Synthesis and electrochemical characterization of bimetallic ruthenium complexes with the bridging eta2(s,s)-1,3-butadiyne-1,4-diyl ligand