Polychlorinated
Mostrando 1-12 de 210 artigos, teses e dissertações.
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1. A Selective Gas Chromatography-Selected Ion Monitoring Mass Spectrometry (GC-MS/SIM) Method to Determine Polychlorinated Biphenyls in Fuller’s Earth
Polychlorinated biphenyls (PCBs) are carcinogenic to humans and can be found in Fuller’s earth used for the regeneration of used transformer oil. This work describes a highly selective gas chromatographic-selected ion monitoring mass spectrometric method (GC-MS/SIM) for the simultaneous determination of three Aroclor PCB congener mixtures (1242, 1254, and
J. Braz. Chem. Soc.. Publicado em: 2020-03
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2. Simultaneous Determination of 2,3,7,8-TCDD and 2,3,7,8-TCDF in Water Samples by LLE-LTP and HPLC-DAD
Polychlorinated dibenzo-p-dioxins and dibenzofurans are persistent organic pollutants which can mainly be found in the environment in water. These compounds are highly toxic and therefore developing new extraction methodologies that are simpler and cost less is highly desirable. This study aimed to optimize and validate the liquid-liquid extraction with low-
J. Braz. Chem. Soc.. Publicado em: 23/05/2019
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3. AVALIAÇÃO DOS RESÍDUOS GERADOS DURANTE A DESTRUIÇÃO DE PCBS PELO PROCESSO CATALISADO POR BASE
There are many processes capable of decontamination of polychlorinated biphenyls in several matrixes. The set of inputs, materials, operation conditions and efficiencies are wide. The base catalyzed dechlorination process shows application potential in great scale, mainly due mild chemical reaction conditions and low cost raw materials. The KPEG is a familia
Quím. Nova. Publicado em: 2018-06
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4. PCDD/Fs and PCBs in Soils: a Study of Case in the City of Belo Horizonte-MG
Dioxins (polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) and polychlorinated biphenyls (PCBs)) are substances that represent a global concern due to their ubiquitous presence and toxicity. Industrial processes and other human activities as well as uncontrollable accidents are the main sources that release these pollutants into t
J. Braz. Chem. Soc.. Publicado em: 2017-05
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5. Solid-Liquid Extraction with Low Temperature Purification Coupled with Gas Chromatography and Mass Spectrometry for Determination of Polychlorinated Biphenyls in Sewage Sludge
Sewage sludge is the residue produced by the wastewater treatment plants, which can be used as soil conditioner in agriculture. However, the current legislation recommends monitoring chemical contaminants such as polychlorinated biphenyls (PCBs). In this study, solid-liquid extraction with low temperature purification (SLE-LTP) was optimized and validated fo
J. Braz. Chem. Soc.. Publicado em: 2017-01
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6. Regional analysis of potential polychlorinated biphenyl degrading bacterial strains from China
ABSTRACT Polychlorinated biphenyls (PCBs), the chlorinated derivatives of biphenyl, are one of the most prevalent, highly toxic and persistent groups of contaminants in the environment. The objective of this study was to investigate the biodegradation of PCBs in northeastern (Heilongjiang Province), northern (Shanxi Province) and eastern China (Shanghai muni
Braz. J. Microbiol.. Publicado em: 2016-09
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7. PREDICTING THE BOILING POINT OF PCDD/Fs BY THE QSPR METHOD BASED ON THE MOLECULAR DISTANCE-EDGE VECTOR INDEX
The quantitative structure property relationship (QSPR) for the boiling point (Tb) of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) was investigated. The molecular distance-edge vector (MDEV) index was used as the structural descriptor. The quantitative relationship between the MDEV index and Tb was modeled by using multivaria
Quím. Nova. Publicado em: 2015-05
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8. AVALIAÇÃO DAS NORMAS DE ENSAIO APLICADAS NA QUANTIFICAÇÃO DE PCBs EM ÓLEO ISOLANTE
Polychlorinated biphenyls (PCBs) were widely used between 1940 and 1970 as an insulating fluid for transformers and capacitors. However, they are bioaccumulative and potentially carcinogenic and, according to the 2001 Stockholm Convention, must be eliminated by 2025. In Brazil, they have been gradually eliminated but contaminated equipment remains. The Brazi
Quím. Nova. Publicado em: 2015-05
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9. POLYCHLORINATED DIBENZO-P-DIOXINS, DIBENZOFURANS, AND BIPHENYLS IN FREGATA MAGNIFICENS FROM ILHA GRANDE BAY, RIO DE JANEIRO STATE, SOUTH-EASTERN BRAZIL
O objetivo deste trabalho é realizar análises químicas em tecidos da ave marinha Fregatamagnificens que se alimenta de peixes. Esta ave é reconhecida por estar em risco de acumular contaminantes tóxicos, devido a sua alta posição na teia trófica e a sua baixa capacidade de metabolizar compostos xenobióticos. Exemplares de Fregata magnificens foram c
Braz. j. oceanogr.. Publicado em: 2015-03
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10. Química entre a microcamada superficial oceânica e os aerossóis marinhos
The sea surface microlayer (SML), although poorly understood, is important in biogeochemical cycling and sea - air exchanges; it is a source or a sink for a range of pollutants. In this paper, an overview of sampling techniques and the role of SML in biogeochemical cycles and climate is presented. The chemical and biological nature of the ocean surface film
Quím. Nova. Publicado em: 2014
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11. Integrated pressurized solvent extraction-cleanup for the rapid determination of polychlorinated biphenyls in meat samples
Um método rápido e eficiente, baseado na integração da extração com solvente sob pressão (PSE) com limpeza através do método sólido de extração (SPE) e sistema de cromatografia gasosa com detector por captura de elétrons (GC-ECD) foi desenvolvido para a determinação de bifenilos policlorados (PCBs). Seis indicadores e doze PCBs semelhantes à
J. Braz. Chem. Soc.. Publicado em: 2013-05
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12. Polychlorinated Biphenyl (PCB) congener concentrations in aquatic birds. Case study: Ilha Grande Bay, Rio de Janeiro, Brazil
Fígados de 108 pássaros encontrados prostrados ou mortos na Baía da Ilha Grande entre 2005 e 2010 foram analisados para 16 congêneres de PCB (IUPAC números 8, 18, 28, 31, 52, 77, 101, 118, 126, 128, 138, 149, 153, 169, 170 e 180). As espécies analisadas foram Egretta caerulea (Linnaeus 1758), Nycticorax nycticorax (Linnaeus 1758), Egretta thula (Molina
An. Acad. Bras. Ciênc.. Publicado em: 2013