Polybutadiene
Mostrando 1-12 de 38 artigos, teses e dissertações.
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1. SIMULAÇÃO DE COMBUSTÃO DO POLIBUTADIENO LÍQUIDO HIDROXILADO, PERCLORATO DE AMÔNIO E ALUMÍNIO EM FORMULAÇÕES DE PROPELENTE SÓLIDO COMPÓSITO
The present work presents combustion simulations of hydroxyl-terminated liquid polybutadiene loaded with ammonium perchlorate and aluminum, using Chemkin software and the “Plug Flow” type reactor. These materials are widely used in solid composite propellant formulations. Through this study, the effect of parameters of axial velocity, equivalence ratio,
Quím. Nova. Publicado em: 2019-02
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2. Estrategia para la optimización de un compuesto de caucho con aceite de soja utilizando diseños de experimentos
ABSTRACT When a rubber component is made, is necessary to start from a “rubber compound” which may be composed of one or more polymers and various additives or fillers. The development of an elastomer mixture to produce a compound with a specific end-use is complicated in the field of rubber technology. Therefore, the successful development of a compound
Matéria (Rio J.). Publicado em: 19/07/2018
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3. Research on the Specific Heat Capacity of PBX Formulations Based on RDX
ABSTRACT The experimental results of specific heat capacity of 2 plastic bonded explosives formulations based on 1,3,5-trinitroperhydro-1,3,5-triazine, using differential scanning calorimetry thermal analysis, and the theoretical ones calculated with the specific heat capacity and mass fraction of individual compounds are compared for a temperature range bet
J. Aerosp. Technol. Manag.. Publicado em: 2016-09
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4. Comparative Assessment of stabilised Polybutadiene Binder under Accelerated Ageing
ABSTRACT Polybutadiene elastomers are versatile materials, being employed at several applications from rocket propellant binder to adhesives and sealants. The elastomers derived from hydroxyl-terminated polybutadiene are usually stabilised with antioxidants to prevent degradation. In this study, a comparative assessment among 2,2’-methylene-bis (4-methyl-6
J. Aerosp. Technol. Manag.. Publicado em: 2016-06
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5. Silane Crosslinked Polyethylene from Different Commercial PE’s: Influence of Comonomer, Catalyst Type and Evaluation of HLPB as Crosslinking Coagent
In the present work, the synthetic route to obtain crosslinked polyethylene (PEX) was studied using vinyltrimethoxy silane (VTMS) as crosslink agent and commercial polyethylene (HDPE and LLDPE). Materials were processed with increasing amounts of VTMS (2.5, 5.0 and 7.5 wt.%). After insertion of silane onto polymer chain in solid state, samples were molded by
Mat. Res.. Publicado em: 2015-04
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6. Cloisite 15Aº nanoclay as an effective PTC for the epoxidation of hydroxyl terminated polybutadiene (HTPB)
A simple method is reported for the epoxidation of hydroxyl-terminated polybutadiene (HTPB) by using in-situ generated dimethyl dioxirane (DMD) as an oxidant and Cloisite 15Aº nanoclay as a phase-transfer catalyst (PTC). In order to find the optimum reaction conditions, real time analyses of the products as well as epoxidation progress, followed by ¹HNMR a
Polímeros. Publicado em: 12/09/2014
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7. Desenvolvimento de tecnologia de pré-polímeros na síntese de poliuretanos empregados em combustíveis sólidos
The aim of this work was to synthesize a polyurethane polymer matrix using polyols as a raw material to obtain a binder such as the hydroxyl terminated polybutadiene (HTPB) pre-polymer in energetic material formulation. The soybean-based polyol was the best starting raw material for producing a binder for solid fuel formulation in rocket motor applications.
Quím. Nova. Publicado em: 2014-07
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8. Copolymerization of 1-hexene and 1-dodecene with 1,3-butadiene by a versatate/diisobutylaluminum hydride/t-butyl chloride catalyst system
The aim of this study was to incorporate an alpha-olefin (1-hexene or 1-dodecene) in a high cis polybutadiene chain, using a neodymium versatate/diisobutylaluminum hydride/t-butyl chloride catalyst system. The influence of alpha-olefin on polymerization reaction and polymer characteristics, using different weight ratios of butadiene/α-olefin, was evaluated.
Polímeros. Publicado em: 2014
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9. Acúmulo de cargas elétricas em propelente sólido compósito com matriz de polibutadieno líquido hidroxilado
Composite solid propellants prepared with HTPB prepolymer - Hydroxyl Terminated Polybutadiene, AP - Ammonium Perchlorate as oxidizer and aluminum particles as an additive metal, have characteristics of high electrical resistivity. The loading process of the polymer matrix did not obtain homogeneity, resulting in clusters, mainly of metal particles. The effec
Quím. Nova. Publicado em: 2014
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10. Effect of hyperbranched polyesters on HTPB polyurethane curing kinetic
Effects of hyperbranched polyesters on kinetics of the reaction between hydroxyl-terminated polybutadiene (HTPB) and isophorone diisocyanate (IPDI) were investigated. HTPB and IPDI were in-situ cured in the presence of two different hyperbranched polyesters, stearic acid ester-terminated hyperbranched polyester (SHPE) and acetate-terminated hyperbranched pol
Mat. Res.. Publicado em: 03/12/2013
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11. An Overview of the Technological Progress in Propellants Using Hydroxyl-Terminated Polybutadiene as Binder During 2002-2012
ABSTRACT: The purpose of this article is to present a study on the technological development of propellants, which are used in solid and hybrid rocket motor, that have been employing hydroxyl-terminated polybutadiene (HTPB) as a binder, for the past ten years. The results prove that major research conducted on propulsion technologies continues using HTPB as
J. Aerosp. Technol. Manag.. Publicado em: 2013-09
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12. Influence of reaction operation conditions on the final properties of high impact polystyrene (hips)
The main objective of the present work is to analyze the influence of some important operational reaction parameters (agitation speed, polybutadiene - PB - content and initiator concentration) on the final properties of High Impact Polystyrene (HIPS) produced in bulk. Variable effects are analyzed both qualitatively and quantitatively with the help of a frac
Braz. J. Chem. Eng.. Publicado em: 2013-09