Platinum Catalysts
Mostrando 13-24 de 40 artigos, teses e dissertações.
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13. Catalytic materials based on Pt, Pb and carbon powder to the oxidation of formic acid in acid medium / Materiais catalíticos baseados em PT, PB e pó de Carbono para a oxidação de ácido fórmico em meio ácido
Proton Exchange Membrane Fuel Cell (PEMFC) that operates with formic acid as fuel (Direct Formic Acid Fuel Cell, DFAFC) constitutes a promising power source to be used in portable devices. In this context, this work aims to find efficient anodes to be used in this kind of system. All materials, based in Pt, Pb and carbon black were synthesized by the Sol-Gel
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 19/02/2009
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14. Characterization of AlMCM-41 synthesized with rice husk silica and utilization as supports for platinumiron catalysts
RH-MCM-41 was synthesized by using silica from rice husk and further modified to increase acidity by adding Al with grafting method with Si/Al ratio of 75 and 25. The resulting materials were referred to as RH-AlMCM-41(75) and RH-AlMCM-41(25). The XRD spectra of all RH-AlMCM-41 confirmed a mesoporous structure of MCM-41. Surface areas of all RH-AlMCM-41 were
Brazilian Journal of Chemical Engineering. Publicado em: 2009-06
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15. Study of oxygen reduction reaction in acidic media on platinum and palladium electrocatalysts supported on carbon / Estudo da reação de redução de oxigênio em meio ácido em eletrocatalisadores de platina e paládio dispersos em carbono
Oxygen reduction reaction (ORR) on platinum-palladium electrocatalysts supported on carbon was studied in H2SO4 electrolyte. The structure of the catalysts was characterized by XRD (X-ray diffractometry) and the composition was determined by EDX (Energy dispersive X-ray spectroscopy). The electronic properties were investigated by in situ XAS (X-ray absorpti
Publicado em: 2009
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16. A hidrogenação do adipato de dimetila utilizando catalisadores suportados em argilas pilarizadas / Hydrogenation of dimethyl adipate at presence of pillared clay based catalysts
Vários métodos de síntese das argilas pilarizadas foram testados. Obtivemos os materiais pilarizados com alumínio em condições distintas: suspensões diluídas (Al-PILC 02), suspensões concentradas (Al-PILC 03), soluções pilarizantes concentradas (Al-PILC 04) e o uso de microondas no processo de envelhecimento (Al-PILC 05). Este último demonstrou s
Publicado em: 2009
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17. Eletrocatalisadores de ligas de platina dispersos em substratos de óxidos para a reação de oxidação de hidrogênio puro e na presença de CO / Electrocatalysts of platinum alloys dispersed in oxide substrates for pure hydrogen oxidation reaction and in the presence of CO
This work shows results of studies of the hydrogen oxidation reaction (HOR) pure in rotation in ultra porous layer and in the presence of CO in the fuel cell to the electrocatalysts of Pt alloy dispersed on oxide substrates such Pt/RuO 2 -C, Pt/RhO 2 -C, Pt/WO 3 -C, Pt/WC-C and pure materials, as RhO 2 /C and WC. The study of the catalytic properties of thes
Publicado em: 2009
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18. Efeito da concentração de irídio sobre as propriedades de catalisadores do tipo Pt-Ge-Ir/Al2O3. / Effect of concentration of iridium on the properties of type catalysts Pt-Ge-Ir/Al2O3.
The effect of iridium content on the activity, selectivity and stability of platinum, germanium and iridium supported in alumina catalysts for oil naphta catalytic reforming was studied in this work. Samples were prepared by the impregnation of the metallic salts (hexachloroplatinic acid, hexachoroiridic acid and germanium chloride) over g-alumina in order t
Publicado em: 2008
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19. Desenvolvimento de catalisadores nanoparticulados do tipo Pt-M1-M2(M1 e M2 = Sn e Re) para aplicação em células a combustível direta de etanol / Development of catalysts nanoparticles of type Pt-M1-M2 (M1 and M2 and Re + Sn) for application in the direct ethanol fuel cell
Neste trabalho foi investigada a eletrooxidação de etanol sobre eletrodos nanoparticulados binários Pt-M1 (M1 = Sn ou Re) e ternários Pt-M1-M2 (M1 e M2 = Sn e Re) suportados em carbono. Estes materiais foram preparados pelo método da redução por álcool e foram caracterizados por difração de raios-X e microscopia eletrônica de varredura associada a
Publicado em: 2008
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20. Desenvolvimento de nanocamadas e nanocristais de Óxido de Zircônio aplicados a catálise / Development of nanolayers and nanocrystals of Oxide of Zirconium applied the catalysis
This work investigate the synthesis and characterization of a catalytic support of -alumina with a nanolayers and nanocrystals of ZrO2. The incorporation of the platinum began during and after the formation of the catalytic support. The technology is based on the Pechini method. The nanolayer was applied to cover the surface of the γ-alumina, av
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 14/09/2007
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21. Preparation of PtRu/carbon hybrids by hydrothermal carbonization process
PtRu/Carbon hybrids were prepared by hydrothermal carbonization process using glucose or starch as carbon sources and reducing agents and platinum and ruthenium salts as catalysts of carbonization process and metals source. The obtained PtRu/Carbon materials were characterized by SEM/EDX, TGA, XRD and cyclic voltammetry. The electro-oxidation of methanol was
Materials Research. Publicado em: 2007-06
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22. Desenvolvimento de catalisadores bifuncionais de óxido de zircônio modificado por óxidos de tungstênio e molibdênio contendo platina para a reação de isomerização de n-parafinas / Development of bifunctional catalysts on zircon oxide modify by tungsten and molybdenum oxides contain platinum for nparaffin isomerization
Bifunctional catalysts based on zircon oxide modified by tungsten (W = 10, 15 and 20 %) and by molybdenum oxide (Mo= 10, 15 e 20 %) containg platinum (Pt = 1%) were prepared by the polymeric precursor method. For comparison, catalysts the tungsten base was also prepared by the impregnation method. After calcinations at 600, 700 and 800 C, the catalysts were
Publicado em: 2007
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23. Estudo do efeito da dopagem da alumina com CÃrio em catalisadores Pt/CeZrO2/Al2O3 na reaÃÃo de oxidaÃÃo parcial do Metano
The transformation of methane into liquid fuels has drawn a lot of attention in the last years due to both economical and environmental concerns. Currently, the main route to obtain synthesis gas from methane is the steam reforming. The major problems associated with this route are the high temperatures and pressures required. Nowadays, the partial oxidation
Publicado em: 2007
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24. Influência de M/C (M = Mo, Cu, Fe e W) incorporado à camada difusora do eletrodo de difusão de gás frente à reação de oxidação de hidrogênio na presença de CO
The performance of proton exchange membrane fuel cells (PEMFC) with Pt-based anodes is drastically lowered when CO-containing hydrogen is used to feed the system, because of the strong adsorption of CO on platinum. In the present work the effects of the presence of a conversion layer of CO to CO2 composed by several M/C materials (where M = Mo, Cu, Fe and W)
Química Nova. Publicado em: 2007