Pd Catalysts
Mostrando 13-24 de 64 artigos, teses e dissertações.
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13. Study of PtPd Bimetallic Nanoparticles for Fuel Cell Applications
Bimetallic nanoparticles are of special interest for their potential applications for fuel cells, mainly for portable power applications. Among the bimetallic systems, Pt-Pd bimetallic nanoparticles have received great interest as they can be widely used as effective catalysts for various electrochemical reactions. In this work, Pt-Pd alloy bimetallic nanopa
Mat. Res.. Publicado em: 15/05/2017
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14. MODELING STYRENE HYDROGENATION KINETICS USING PALLADIUM CATALYSTS
Abstract The high octane number of pyrolysis gasoline (PYGAS) explains its insertion in the gasoline pool. However, its use is troublesome due to the presence of gum-forming chemicals which, in turn, can be removed via hydrogenation. The use of Langmuir-Hinshelwood kinetic models was evaluated for hydrogenation of styrene, a typical gum monomer, using Pd/9%N
Braz. J. Chem. Eng.. Publicado em: 2016-09
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15. Effect of Metal Dispersion on the Hydrogenation of 2-Amyl Anthraquinone over Pd/Al2O3 Catalyst
A series of highly dispersed Pd/Al2O3 catalysts were prepared via the polyol method. The catalysts were characterized by nitrogen adsorption, X-ray diffraction (XRD), UV-Vis spectrophotometry, temperature programmed reduction (TPR) and transmission electron microscopy (TEM). The influence of Pd particle size on the hydrogenation of 2-amyl anthraquinone (AAQ)
J. Braz. Chem. Soc.. Publicado em: 2016-06
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16. Zwitterionic Surfactant Stabilized Palladium Nanoparticles as Catalysts in Aromatic Nitro Compound Reductions
Palladium nanoparticles (NPs) stabilized by ImS3-14, a zwitterionic surfactant structurally related to ionic liquids, are revealed here to be good catalysts for the reduction of a large number of substituted aromatic nitro compounds. Our mass spectrometry results are consistent with the formation of amino products in a direct route, where the aromatic nitro
J. Braz. Chem. Soc.. Publicado em: 2016-02
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17. NANOPARTICLES OF TUNGSTEN AS LOW-COST MONOMETALLIC CATALYST FOR SELECTIVE HYDROGENATION OF 3-HEXYNE
Low-cost tungsten monometallic catalysts containing variable amounts of metal (4.5, 7.1 and 8.5%W) were prepared by impregnating alumina with ammonium metatungstate as an inexpensive precursor. The catalysts were characterized using ICP, XPS, XRD, TPR and hydrogen chemisorption. These techniques revealed mainly WO3-Al2O3 (W6+) species on the surface. The eff
Quím. Nova. Publicado em: 2016-01
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18. Wet oxidation of glycerol into fine organic acids: catalyst selection and kinetic evaluation
The liquid phase oxidation of glycerol was performed producing fine organic acids. Catalysts based on Pt, Pd and Bi supported on activated carbon were employed to perform the conversion of glycerol into organic acids at 313 K, 323 K and 333 K, under atmospheric pressure (1.0 bar), in a mechanically agitated slurry reactor (MASR). The experimental results ind
Braz. J. Chem. Eng.. Publicado em: 2014-12
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19. Desenvolvimento de reator tipo "dip catalyst" para filmes poliméricos contendo nanopartículas de metais de transição
This article describes the development of a new catalytic reactor designed to operate with nanoparticle-embedded polymer thin films. Stabilization of metal nanoparticles in films that serve as catalysts in organic reactions is relatively new; therefore, the development of reactors to facilitate their use is necessary. We describe in detail the preparation of
Quím. Nova. Publicado em: 2014
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20. Catalisadores de Pd metálico modificados por líquidos iônicos para a hidrogenação seletiva de compostos poli-insaturados
In this work, heterogeneous catalysts immobilized on supported ionic liquid (IL) were prepared, characterized and investigated in hydrogenation reactions of the substrates 1,5-cyclooctadiene (1,5-COD), trans-cinnamaldehyde (CALD) and nitrobenzene (NB). Two methods were used to prepare the catalysts. In the first, commercial Pd/C catalyst was coated with diff
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 06/08/2012
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21. Preparation and properties of nanophase (Ce, Zr, Pr)O2-doped alumina coating on cordierite ceramic honeycomb for three-way catalysts
Nanophase (Ce, Zr, Pr)O2-doped alumina coatings were prepared by impregnating the cordierite ceramic honeycomb in the sol or in the slurry of already calcined powder, respectively. The effects of preparation methods on the crystal phase, texture, oxygen storage capacity (OSC), reducibility, surface morphology and thermal stability of coatings were investigat
Brazilian Journal of Chemical Engineering. Publicado em: 2012-03
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22. Palladium-supported catalysts in methane combustion: comparison of alumina and zirconia supports
Palladium catalysts supported on alumina and zirconia were prepared by the impregnation method and calcined at 600 and 1000 ºC. Catalysts were characterized by BET measurements, XRD, XPS, O2-TPD and tested in methane combustion through temperature programmed surface reaction. Alumina supported catalysts were slightly more active than zirconia supported cata
Química Nova. Publicado em: 2012
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23. O efeito da desativação térmica nas propriedades oxirredutoras e na atividade catalítica de catalisadores CZ e Pd-CZ
Automotive catalyst, using in Brazil since 1992, is a essential technology for vehicular emissions control. Noble metals are the active phase of these catalysts, and cerium zirconium mixed oxides (CZ), responsibles for the oxygen storage capacity (OSC), one of the most important aspect for the operational performance of the catalyst. In this context, the oxi
Química Nova. Publicado em: 2012
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24. Catalisadores de paládio suportado em carvão ativado para produção de biocombustíveis / Palladium catalysts supported on activated carbon for the production of biofuels.
A proposta deste trabalho é estudar a preparação e caracterização do catalisador Pd/C para a descarboxilação do ácido esteárico, a fim de obter biodiesel parafínico. Os precursores utilizados na preparação dos carvões foram o endocarpo do coco da baía e a bainha da palmeira de manila. Estes carvões foram ativados quimicamente e por microondas
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 16/11/2011