Partial Oxidation Of Methane
Mostrando 13-24 de 29 artigos, teses e dissertações.
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13. Study of nickel catalysts supported on modified ZrO2 applied in reforming reactions / Estudo de catalisadores de níquel suportados em ZrO2 modificados aplicados em reações de reforma
Zirconium dioxide is a material with physics and chemical characteristics that can be applied in many fields, as academic as industrial. In the catalysis, the interest in systems based on zirconia (ZrO2) are growing- up quickly, as a catalyst as a support, considering that ZrO2 properties can be changed by the addition of different cations. The objective of
Publicado em: 2008
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14. "Aplicação de catalisadores de níquel e cobalto preparados via precursores do tipo hidrotalcita nas reações de reforma a vapor, oxidação parcial e reforma oxidativa do metano" / "Application of nickel and cobalt catalysts prepared via hydrotalcite-type precursors in the reactions of steam reforming, partial oxidation and oxidative reforming of methane"
One of the most important applications of methane is the syngas production, a mixture of H2 and CO. Three processes can lead to syngas formation from methane: steam reforming, CO2 reforming and partial oxidation. Various non-noble metal catalysts were studied in these processes, although the carbon deposition or the metal sinterization is always observed. Ca
Publicado em: 2007
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15. Influência do teor e efeito promotor de Ag, Fe, Pd e Pt ao catalisador Ni/CeZrO2 nas reações de oxidação parcial e reforma autotérmica do metano
In the present study the behavior of Ni/CeZrO2 catalysts were investigated for the autothermal reforming and partial oxidation of methane and compared with the sample 10%Ni/Al2O3. Samples with 1.5; 5 and 10% nickel were supported on CeZrO2 and catalysts 10%Ni/CeZrO2 promoted by different metals (Ag, Fe, Pd and Pt). The catalysts were characterized by BET sur
Publicado em: 2007
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16. InfluÃncia do teor e efeito promotor de Ag, Fe, Pd e Pt ao catalisador Ni/CeZrO2 nas reaÃÃes de oxidaÃÃo parcial e reforma autotÃrmica do metano
In the present study the behavior of Ni/CeZrO2 catalysts were investigated for the autothermal reforming and partial oxidation of methane and compared with the sample 10%Ni/Al2O3. Samples with 1.5; 5 and 10% nickel were supported on CeZrO2 and catalysts 10%Ni/CeZrO2 promoted by different metals (Ag, Fe, Pd and Pt). The catalysts were characterized by BET sur
Publicado em: 2007
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17. Nanopartículas de Pt suportadas em Al2O3 e CeO2-Al2O3: síntese, caracterização e propriedades catalíticas para reforma do metano.
A new method to prepare Pt nanoparticles (NPs) dispersed on Al2O3 and CeO2-Al2O3 is described in this work. The Pt-NPs were used to prepare CeO2-Al2O3-supported Pt nanocatalysts (Pt-NPs/Al2O3 and Pt-NPs/CeO2-Al2O3). The catalysts were characterized by BET surface area (SBET), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) reaction of
Publicado em: 2007
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18. ProduÃÃo de gÃs de sÃntese por tri-reforma do metano em reator de leito fixo
The ever increasing availability of natural gas (NG), and the abundant carbonic gas production, via fermentation of most prepared from sugar cane products (sugar cane juice, and molasses), thermoelectric generators, and refineries have enhanced the research interest of these commodities. The indirect NG conversion processes to synthesis gas (CO and H2), the
Publicado em: 2007
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19. Estudo do efeito da dopagem da alumina com CÃrio em catalisadores Pt/CeZrO2/Al2O3 na reaÃÃo de oxidaÃÃo parcial do Metano
The transformation of methane into liquid fuels has drawn a lot of attention in the last years due to both economical and environmental concerns. Currently, the main route to obtain synthesis gas from methane is the steam reforming. The major problems associated with this route are the high temperatures and pressures required. Nowadays, the partial oxidation
Publicado em: 2007
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20. Estudo do efeito da dopagem da alumina com Cério em catalisadores Pt/CeZrO2/Al2O3 na reação de oxidação parcial do Metano
Atualmente, a reação de oxidação parcial do metano tem sido extensivamente estudada com o objetivo de produzir gás de síntese e contribuir para a viabilização econômica da tecnologia de conversão do metano, principal constituinte do gás natural, em produtos de maior valor agregado. Essa reação frente às reformas seca e a vapor, apresenta as van
Publicado em: 2007
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21. Efeito da temperatura de calcinação em catalisadores de platina a base de óxidos de cério e zircônio mássicos e suportados em alumina nas reações de oxidação parcial e reforma autotérmica do metano
The transformation of methane into higher value products became more important in recent years due to the search for new energy sources. The use of partial oxidation and autothermal reforming of methane can give synthesis gas with a H2/CO ratio of 2, that is very adequate for the Fischer-Tropsch synthesis. In order to develop this process, the use of catalys
Publicado em: 2006
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22. Síntese e caracterização do carbeto de molibdênio nanoestruturado para fins catalíticos na reação de oxidação parcial do metano
Os materiais nanoestruturados são caracterizados por terem um tamanho de cristalito inferior a 100 nm podendo atingir 1 nm. Devido às dimensões extremamente reduzidas dos cristalitos, as propriedades destes materiais são significativamente modificadas relativamente às dos materiais convencionais. No presente trabalho foi realizado um estudo de síntese
Publicado em: 2006
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23. Comparison of two different synthesis methods of perovskites, SrCo0.5FeO3 type, aiming at evaluating their use as membranes for partial oxidation of methane
In this work two different synthesis methods of perovskites, SrCo0.5FeO3, were compared: combustion synthesis and oxides mixture aiming at evaluating their use as membranes for partial oxidation of methane. The combustion synthesis method explores an exothermic, generally very fast and self-sustaining chemical reaction between the desired metal salts and a s
Materials Research. Publicado em: 2004-06
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24. Oxidação parcial de metano a compostos oxigenados (HCHO e CH3OH) sobre catalizadores oxidos MoOx/MgO-SiO2 e VOx-SiO2
Methane is the major component of natural gas, often present as more than 90% of the gas. Current1y it is primarily used as a fuel. In the chemical industry it is used in the production of synthesis gas, hydrogen, and in the manufacture of the halogen derivatives of methane, acetylene, hydrogen cyanide, technical carbon, and many other products. The direct c
Publicado em: 2003