Parameters Kinetic
Mostrando 13-24 de 1016 artigos, teses e dissertações.
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13. MULTIVARIATE ANALYSIS OF DIGITAL IMAGES AS AN ALTERNATIVE TO MONITOR DYE DEGRADATION BY THE FENTON PROCESS
The present work proposed the application of a multivariate regression model based on image data to monitor the decolorization process. Thus, a PLS regression based on the color histogram was applied to monitor the methylene blue degradation by the Fenton reaction. The results obtained by the digital imaging and UV-Vis methods were compared and the initial (
Quím. Nova. Publicado em: 2020-05
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14. DINÂMICA MOLECULAR REATIVA DA ABERTURA DO ANEL EPÓXI EM REAÇÕES COM POLIAMINA Ellen
The molecular dynamics simulations were used to study the epoxy ring-opening in the determination of kinetic parameters, with a temperature range from 1500 to 2500 K in a 20 x 20 x 20 Å unit cell containing 15 molecules of C2H4O (ethylene oxide) and 35 molecules of CH6N2 (methanediamine). The activation energy values for epoxy and diamine was 66 and 92 kJ m
Quím. Nova. Publicado em: 2020-05
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15. Kinetic parameters study for the slow pyrolysis of coffee residues based on thermogravimetric analysis
Thermal decomposition of coffee husks was investigated by thermogravimetric analyses. The proximate, ultimate and composition analyses were performed. Thermogravimetric tests were realized, the material was heated to 1173 K using five heating rates: 5, 10, 15, 20, 25 K min-1. The kinetic parameters were estimated using the methods of Kissinger-Akahira-Sunose
Quím. Nova. Publicado em: 2020-04
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16. Characteristics of glucose oxidase immobilized on Magnetic Chitosan Nanoparticles
Abstract Immobilization process is used to facilitate the enzyme recovery and reusability. The aims of this study were to evaluate the effect of different amounts of chitosan on immobilization efficiency of Glucose Oxidase (GOX), pH effect on enzyme activity and changes of kinetic characteristics of enzyme immobilized on Magnetic Chitosan Nanoparticles (MCNP
Food Sci. Technol. Publicado em: 2020-03
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17. Kinetics of Lumefantrine Thermal Decomposition Employing Isoconversional Models and Artificial Neural Network
Thermal analysis can be used to determine shelf-life and kinetic parameters in pharmaceutical systems. This work investigates the kinetic of lumefantrine thermal decomposition, an antimalarial, using non-isothermal and isothermal experimental data. The non-isothermal conditions are analyzed applying Vyazovkin method, while isothermal conditions employ models
J. Braz. Chem. Soc.. Publicado em: 2020-03
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18. Mathematical Modeling of the Transesterification Reaction by Finite Elements: Optimization of Kinetic Parameters Using the Simplex Sequential Method
The use of biodiesel as fuel has been presented as a viable alternative in the search for renewable energies. It can be produced from the transesterification reaction of vegetable oils with methanol in the presence of sodium or potassium hydroxide as catalysts. In the present research, the transesterification reaction of soybean oil was modeled considering t
J. Braz. Chem. Soc.. Publicado em: 2020-02
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19. KINETIC MODELING AND EXPERIMENTAL VALIDATION OF A PHOTOCATALYTIC FLUIDIZED BED REACTOR FOR n-HEXANE DEGRADATION
Abstract This work presents a modeling procedure for a tall photocatalytic fluidized bed photoreactor used for the photocatalytic oxidation of n-hexane on the anatase TiO2 surface. The modeling strategy split the reactor into two parts: a lower dense phase, with high solids concentration behaving as a bubbling bed treated as a continuous stirred tank reactor
Braz. J. Chem. Eng.. Publicado em: 13/01/2020
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20. PREPARATION AND SIMULATION OF THE ON-LINE SiO2/S COATING FOR COKING INHIBITION IN THE INDUSTRIAL CRACKING FURNACE
Abstract Coke formation inside radiant coils is one of the main problems during thermal cracking of hydrocarbons. The on-line preparation of the coating for coking inhibition is a promising technology because it provides more flexibility to the operators on site. The SiO2/S coating was prepared on the inner surface of coils in an 8-year-served GK-VI industri
Braz. J. Chem. Eng.. Publicado em: 13/01/2020
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21. ANALYTICAL EXPRESSIONS FOR THE CONCENTRATION AND CURRENT IN THE REDUCTION OF HYDROGEN PEROXIDE AT A METAL-DISPERSED CONDUCTING POLYMER FILM
A mathematical model describing the reduction of Hydrogen peroxide (H2O2) to water in a metal dispersed conducting polymer film is discussed. The model is based on a system of reaction-diffusion equations containing a non-linear term related to Michaelis-Menten kinetics of the enzymatic reaction. The approximate analytical expressions corresponding to the co
Quím. Nova. Publicado em: 2020-01
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22. Performance evaluation of GSA, SOS, ABC and ANN algorithms on linear and quadratic modelling of eggplant drying kinetic
Abstract In this study, kinetics of eggplant drying was modeled in the laboratory-scaled Food Drying Oven (FDO) with resistance heater was designed and manufactured. The temperature, energy consumption and drying time of FDO were recorded by keeping the temperature of at different temperatures as 40, 50 and 60 °C. These saved values were chosen as the input
Food Sci. Technol. Publicado em: 20/12/2019
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23. RE-ESTERIFICATION OF MACAUBA ACID OIL USING GLYCEROL FOR ACIDITY REDUCTION AND BIODIESEL PRODUCTION
Abstract Biodiesel production using acid oils is an important alternative for biofuel cost reduction. However, it is a huge challenge for homogeneous transesterification, the main industrial route commonly used. This paper presents macauba oil with high acidity, 43.90 w/w%, as a potential raw material for biodiesel production. The acidity was reduced to 0.8
Braz. J. Chem. Eng.. Publicado em: 09/12/2019
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24. Pentoses Used in Cultures of Synechococcus nidulans and Spirulina paracas: Evaluation of Effects in Growth and in Content of Proteins and Carbohydrates
Abstract The biological assimilation of the sugars present in lignocellulosic residues has gained prominence since these residues are the most abundant and economic residues in nature. Thus, the objective of this work was to determine whether the use of D-xylose and L-arabinose as sources of carbon in Synechococcus nidulans and Spirulina paracas cultures af
Braz. arch. biol. technol.. Publicado em: 25/11/2019