KINETIC MODELING AND EXPERIMENTAL VALIDATION OF A PHOTOCATALYTIC FLUIDIZED BED REACTOR FOR n-HEXANE DEGRADATION

AUTOR(ES)

Matsumoto, Danielle

FONTE

Braz. J. Chem. Eng.

DATA DE PUBLICAÇÃO

13/01/2020

RESUMO

Abstract This work presents a modeling procedure for a tall photocatalytic fluidized bed photoreactor used for the photocatalytic oxidation of n-hexane on the anatase TiO2 surface. The modeling strategy split the reactor into two parts: a lower dense phase, with high solids concentration behaving as a bubbling bed treated as a continuous stirred tank reactor (CSTR); and an upper lean phase of low solids concentration behaving as a plug-flow reactor (PFR). The Langmuir-type kinetic parameters were obtained for the flow rate of 1.67 × 10-4 m3 s-1 and catalyst mass of 0.1 kg. The model revealed a good adjustment with experimental data when predicting conversion results for the same experimental conditions, but deviations grew as flow rates and catalyst loads departed from those values in which the model was obtained.

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