Langmuir And Langmuir Blodgett Lb Films
Mostrando 13-24 de 32 artigos, teses e dissertações.
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13. Chemsensor of NO2 gas based on porphyrin of 5, 10, 15, 20-tetraphenylporphyrin LB films and LS films
The sensitivity of 5, 10, 15, 20-tetraphenylporphyrin (H2TPP) to the presence of NO2 gas in diluted solutions and in Langmuir-Blodgett (LB) and Langmuir-Schaefer (LS) films was investigated by UV-visible spectroscopy. The shift of Soret and Q bands were analyzed and the energies involved were calculated. The exposure of LB porphyrin films deposited onto glas
Materials Research. Publicado em: 2008-12
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14. Estudo da interação da peroxidase de raiz forte em interfaces nanoestruturadas / Study of horseradish peroxidase interaction in nanostructured interfaces
A study has been performed on the interaction of the enzyme horseradish peroxidase (HRP) in nanostructured interfaces and their possible application in biosensors for hydrogen peroxide. The nanostructured films were obtained with the Langmuir, Langmuir-Blodgett (LB) and layer-by-layer (LbL) methods. The interaction between HRP and species at interfaces was i
Publicado em: 2008
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15. Liquid-crystalline azopolymers for the fabrication of nanostructured films / Preparação de azopolímeros líquido-cristalinos para a fabricação de filmes nanoestruturados
A birrefringência fotoinduzida e a formação de grades de relevo vêm sendo extensivamente investigadas em filmes de azopolímeros, obtidos por diversas técnicas de fabricação. Embora para azopolímeros amorfos já haja modelos bem estabelecidos tanto para explicar a dinâmica de fotoindução da birrefringência quanto para o transporte de massa que le
Publicado em: 2008
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16. Estudos sobre interações da 2,3,5,6-tetra(-piridil)pirazina (tppz) com európio e efeitos na luminescência do complexo Eu(ttfa)3 / Studies on the interactions of 2,3,5,6-tetra(-pyridyl)pyrazine (tppz) with europium and effects on the luminescence of the Eu(ttfa)3 complex.
In this work, we have conducted studies on the interactions of 2,3,5,6-tetra(-pyridyl)pyrazine (tppz) with Eu3+ in different situations. In the first of them, we have made a detailed study on the ongoing interactions in solution between tris(thenoiltrifluoroacetonate)europium(III), Eu(ttfa)3 and tppz, where it was verified that tppz act as a luminescence sup
Publicado em: 2008
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17. Influência da temperatura e de aditivos na matriz fosfolipídica usada para incorporação de fosfatases alcalinas pela técnica de Langmuir-Blodgett / Influence of the temperature and adtives in phospholipidic matrix utilized to Alkaline Phosphatases incorporation by Langmuir-Blodgett tecnique
ABSTRACT Alkaline phosphatases (AP) are unspecific enzymes that hydrolyze phosphate esthers. In this Dissertation we have studied the adsorption of two forms of AP in phospholipid Langmuir monolayers and Langmuir-Blodgett films, considered as biomembrane models, at different temperatures. Further, the effect of the presence of a disaccharide, trehalose, as w
Publicado em: 2007
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18. Polimetalates porphyrins with ruthenium phosphinics complex to application in homogeny catalyze, Non Linear Optic and Langmuir-Blodgett film preparation / Porfirinas polimetaladas com complexos periféricos de rutênio com aplicações em catálise homogênea, óptica não linear e montagem de filmes de Langmuir-Blodgett
A novel metaloporphyrin with ruthenium complexes, {H2-TPyP[RuCl(dppb)(Xbipy)] 4}(PF6)4 and {M-TPyP[RuCl(dppb)(X-bipy)]4}(PF6)4, (where M = Mn(III), Co(II) and Zn(II), X = Me- MeO- and Cl-) has been synthesized and structurally characterized by 31P{1H} magnetic resonance, UV-Vis and IR spectroscopy, cyclic voltammetry and CHN. The catalytic activity of {Mn-TP
Publicado em: 2007
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19. Estudo de monocamadas fosfolipidicas nanoestruturadas obtidas por LB para aplicações em biossensores
There has been long-standing interest in the physical chemical properties of defined mixtures of cholesterol and phospholipids in monolayer and bilayer membranes. They also provide insight into certain properties of the membranes of animal cells. Even if phospholipids and sphingolipids build up the matrix of cellular membranes, sterols are essential componen
Publicado em: 2007
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20. A novel binuclear ruthenium complex: spectroscopic and electrochemical characterization, and formation of Langmuir and Langmuir-Blodgett films
O complexo [{RuCl3(dppb)}2(µ-4,4'-bipy)] (dppb = PPh2(CH2)4PPh2; 4,4'-bipy= 4,4'-bipiridil) foi obtido por meio da reação entre 4,4'-bipiridina e mer-[RuCl3(dppb)].H2O, em bom rendimento. As características do complexo binuclear obtido, estudadas por medidas de FT-IR, UV-Vis, EPR e análise elementar foram similares às do complexo [RuCl3(dppb)L] (L= N-h
Journal of the Brazilian Chemical Society. Publicado em: 2006-12
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21. Surface morphology and optical characterization of OC1 OC6-PPV films
We report optical and morphological properties of poly(2-methoxy-5-hexyloxy-p-phenylenevinylene) (OC1OC6-PPV) films processed by casting, spin-coating (SC) and Langmuir-Blodgett (LB) techniques. The absorption spectra are practically the same, with an absorption maximum at approximately at 500 nm. For the photoluminescence (PL) spectra at low temperature (T=
Brazilian Journal of Physics. Publicado em: 2006-06
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22. Filmes de Langmuir e Langmuir-Blodgett (LB) de azopolímeros com controle do tamanho da cadeia e posição dos cromóforos / Langmuir and Langmuir-Blodgett (LB) films of azopolymers with controlled chain-length and chromophores position
Azopolímeros apresentam propriedades de fotoisomerização, úteis para confecção de memórias ópticas, que dependem da arquitetura molecular do azopolímero e do filme formado a partir dele. Neste trabalho foram sintetizados polímeros com arquitetura molecular controlada, usando os azomonômeros [4-(N-etil-N-2-(metacriloxietil)) amino-2-cloro-4-nitroaz
Publicado em: 2006
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23. Técnicas de caracterização para investigar interações no nível molecular em filmes de Langmuir e Langmuir-Blodgett (LB)
This paper discusses fundamental concepts for the characterization of Langmuir monolayers and Langmuir-Blodgett (LB) films, with emphasis on investigations of material properties at the molecular level. By way of illustration, results for phospholipid monolayers interacting with the drug dipyridamole are highlighted. These results were obtained with several
Química Nova. Publicado em: 2005-06
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24. Study of photoinduced birefrigence, in layer-by-layer films containing azopolymer and azodye / Estudo de birrefrigência fotoinduzida em filmes automontados de azopolímeros e azocorantes
This work was aimed at investigating the influence of the molecular architecture and film fabrication on the photoinduced birefi-ingence of layer-by-layer (LbL) films containing the azopolymer PS 119® or the azodye Brylliant Yellow (BY) as photoreactive materials. The LbL films were produced with six polications, viz.: poly(allylamine hydrochloride) (PAH),
Publicado em: 2005