Ethyl Ester
Mostrando 1-12 de 187 artigos, teses e dissertações.
-
1. Synthetic Studies toward (−)-Cleistenolide: Highly Stereoselective Synthesis of New γ-Lactone Subunits
This study describes the stereoselective synthesis of two new γ-lactones in 6 and 3 steps and 19 and 32% yield, respectively, directed toward the total synthesis of the natural product (−)-cleistenolide. The starting material was an enantiomerically pure diacetonide diol, derived from d-mannitol with the required stereocenters for (−)-cleistenolide synt
J. Braz. Chem. Soc.. Publicado em: 2021-04
-
2. Crystal Structure and 1H NMR Experimental and Theoretical Study of Conformers of 5-Methyl-1-(4’-methylphenylsulfonylamino)-1H-[1,2,3]-triazole-4-carboxylic Acid Ethyl Ester and 5-Methyl-1-(phenylsulfonylamino)-1H-[1,2,3]-triazole-4-carboxylic Acid Ethyl Ester
We reported experimental and theoretical investigation of conformers of 1,2,3-triazole derivatives, substances of exclusively synthetic origin, subject of extensive studies, because of several biological properties, such as antiviral, antimicrobial and antileishmaniasis. We reported molecular/supramolecular X-ray structures of antiophidian compounds I and II
J. Braz. Chem. Soc.. Publicado em: 2020-05
-
3. AVALIAÇÃO DA BIOMASSA DE FUNGOS AMAZÔNICOS COMO FONTE DE LIPASES PARA BIOCATÁLISE
We evaluated the biomass of twenty Amazonian fungal isolates as a potential source of mycelium-bound lipases with hydrolytic, synthetic or enantioselective activity for biocatalysis application. We compared the hydrolytic activity of three biomass treatments (delipidated, non-delipidated and cultivated in medium without inducer). Delipidated biomass showed b
Quím. Nova. Publicado em: 2020-02
-
4. Evaluation of Antifungal Potential of Leaf Extract of Chenopodium murale Against Fusarium oxysporum f. sp. lycopersici
RESUMO: O presente estudo foi realizado para avaliar a atividade antifúngica e a análise por CG-EM do extrato de folhas de Chenopodium murale contra Fusarium oxysporum f. sp. lycopersici (FOL), um patógeno de tomate altamente problemático no solo. Folhas secas de C. murale foram extraídas com metanol por duas semanas e, após a evaporação do solvente
Planta daninha. Publicado em: 02/12/2019
-
5. New cathepsin V inhibitor from stems of Bowdichia virgilioides
Abstract Bioassay-guided fractionation of Bowdichia virgilioides Kunth, Fabaceae, extracts has led to the isolation of cathepsin V inhibitors. The investigation of the hexane and ethyl acetate extracts allowed the characterization of eleven compounds: lupeol, lupenone, β-sitosterol and stigmasterol in mixture, trans p-coumaric acid ester derivative, syringa
Rev. bras. farmacogn.. Publicado em: 17/10/2019
-
6. Chemical characterization, antioxidant and anti-HIV activities of a Brazilian propolis from Ceará state
ABSTRACT Propolis (bee glue) a product of Apis mellifera L. is a resinous mixture containing chiefly beeswax and resin harvested by bees from plant leaves, buds and exudates. Extracts of a propolis sample from Salitre, a municipality of Ceará state (northeast Brazil) were obtained with solvents of increasing polarity (hexane, chloroform, ethyl acetate and m
Rev. bras. farmacogn.. Publicado em: 26/08/2019
-
7. ESTERIFICATION OF OLEIC ACID IN A SEMI-BATCH BUBBLE REACTOR FOR BIODIESEL PRODUCTION
ABSTRACT A semi-batch bubble reactor has been developed to produce fatty acid ethyl ester (biodiesel) by acid-catalyzed esterification of oleic acid with superheated ethanol vapor. In this paper, the effects of reaction temperature (110, 130 and 150°C), ethanol volumetric flow rate (1.35, 2.50 and 3.65 mL/min) and vapor bubble size on the reactor performanc
Braz. J. Chem. Eng.. Publicado em: 15/07/2019
-
8. Design, synthesis, biological evaluation, and nitric-oxide release studies of a novel series of celecoxib prodrugs possessing a nitric-oxide donor moiety
A new group of hybrid nitric oxide-releasing anti-inflammatory drugs (NONO-coxibs), in which an O 2-acetoxymethyl-1-(N-ethyl-N-methylamino)diazen-1-ium-1,2-diolate NO-donor moiety is attached directly to the carboxylic acid group of 1-(4-aminosulfonylphenyl)-5-aryl-1H-pyrazol-3-carboxylic acids (6a-c), were synthesized. A low amount of NO was released from t
Braz. J. Pharm. Sci.. Publicado em: 08/04/2019
-
9. Thermal Properties of the Blends of Methyl and Ethyl Esters Prepared from Babassu and Soybean Oils
Fatty acid esters (methyl and ethyl) prepared from babassu nut oil were blended with the respective esters from soybean oil. These binary blends (babassu:soybean) were made in proportions of 10:90, 20:80, 30:70, 40:60, and 50:50 (vol%). The ester content of all the blends was higher than 96.5%, which is the minimum value required by the Brazilian National Ag
J. Braz. Chem. Soc.. Publicado em: 2018-08
-
10. PHYTOCHEMISTRY INVESTIGATION OF CASEARIA ARBOREA (RICH.) URB. (SALICACEAE) AND ANTIMICROBIAL ANALYSIS OF ITS DITERPENE
A phytochemical investigation from aerial parts of Casearia arborea (Rich.) Urb. (Salicaceae) led to isolation and identification of: sitosterol, 4-en-stigmast-3-one, 13-hydroxy-trans-ent-cleroda-3,14-diene,3-hydroxy-2-oxo-trans-ent-cleroda-3,14-diene (kolavelone), a mixture of 13-hydroxy-trans-ent-cleroda-3,14-diene and an ester ethyl hexadecanoate, kaempfe
Quím. Nova. Publicado em: 2018-06
-
11. Determination of Alkyl Esters Content by Gas Chromatography: Validation of Method Based on Short Column and Response Factor
In this study an analytical method, based on gas chromatography with flame ionization detection, using a short column and response factor (GCSCRF), was validated for the quantification of fatty acid alkyl esters (methylic or ethylic). During the validation process, the proposed method was employed to analyze twenty samples of fatty acid methyl esters and fat
J. Braz. Chem. Soc.. Publicado em: 2018-06
-
12. GC-FID METHODOLOGY VALIDATION FOR THE FATTY ESTERS CONTENT DETERMINATION IN BIODIESEL WITH HEXADECYL ACETATE AS THE INTERNAL STANDARD
Biodiesel purity expressed as fatty esters content is one of its most important quality parameters. Although several instrumental methods have been employed, gas chromatography with internal standard calibration has been the most used. Biodiesel is a very complex matrix, therefore finding a suitable internal standard (IS) is not straightforward. EN14103:2003
Quím. Nova. Publicado em: 2017-09