Electrochemical Synthesis
Mostrando 13-24 de 140 artigos, teses e dissertações.
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13. Synthesis, Photophysical and Electrochemical Properties of Novel D-π-D and D-π-A Triphenylamino-Chalcones and β-Arylchalcones
A series of triphenylamino (TPA)-chalcones and triphenylamino-β-arylchalcones, displaying either D-π-D or D-π-A architecture, were synthesized through aldol condensations and Heck reactions. The chalcone derivatives display intense absorption bands ranging from 389 to 432 nm and molar extinction coefficients of ca. 105 L mol-1 cm-1 corresponding to π-π*
J. Braz. Chem. Soc.. Publicado em: 2019-01
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14. PAni-coated LiFePO4 Synthesized by a Low Temperature Solvothermal Method
The composite LiFePO4/polyaniline was prepared by chemical synthesis to promote the intensification of the electrochemical properties for use as cathodes in lithium ion batteries. The X-ray diffraction (XRD) of LiFePO4 synthesized by solvothermal method were indexed to the orthorhombic structure, according to the JCPDS 40-1499. The spectra Raman and FTIR sho
Mat. Res.. Publicado em: 03/12/2018
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15. Obtención de nanopartículas de LiCoO2 mediante síntesis por combustión de soluciones
ABSTRACT Lithium Cobalt Oxide (LiCoO2) nanoparticles were obtained by the Solutions Combustion Synthesis method, using starch as fuel. Four starch/nitrates ratios (φe) (ranging 0.5-1.25) have been studied. One route was a conventional, stoichiometric process, while the other ones were a nonstoichiometric process. The samples were calcined in air at 773K. Th
Matéria (Rio J.). Publicado em: 19/07/2018
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16. Enhancing the Supercapacitive and Superparamagnetic Performances of Iron Oxide Nanoparticles through Yttrium Cations Electro-chemical Doping
A one-pot electrosynthesis platform is reported for fabrication of Y3+ doped iron oxide nanoparticles (Y-IONPs). In this procedure, Y-IONPs are electro-deposited from an additive-free aqueous solution of iron(III) nitrate, iron(II) chloride and yttrium chloride. The analysis data provided by X-ray diffraction (XRD), field emission electron microscopy (FE-SEM
Mat. Res.. Publicado em: 10/07/2018
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17. A Potential Visible-Light NO Releaser: Synthesis, Reactivity and Vasodilator Properties
The cis-[Ru(bpy)2(4-bzpy)(NO)](PF6)3 complex was prepared (4-bzpy = 4-benzoylpyridine), and characterized by UV-visible, infrared and nuclear magnetic resonance (NMR) spectroscopies and electrochemical techniques. The reaction with cysteine was preliminarily investigated, aiming to shed light on the potential biological mechanism for NO or HNO release mediat
J. Braz. Chem. Soc.. Publicado em: 2017-11
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18. Carbon Nanotube@MnO2@Polypyrrole Composites: Chemical Synthesis, Characterization and Application in Supercapacitors
Abstract Core/shell structures of carbon-based materials/ metal oxide have been considered as potential candidates for electrochemical devices due to their improved pseudocapacitance/electrical double layer capacitance and high conductivity/ superior surface area. The development of multiple core-shell structures of MWCNT@MnO2@PPy was analyzed as a standard
Mat. Res.. Publicado em: 11/08/2016
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19. MATERIAIS DE COMPOSIÇÃO TI/PBXTI1-XO2 PARA DEGRADAÇÃO ELETROQUÍMICA FOTO-ASSISTIDA DE POLUENTES ORGÂNICOS
Electrochemical methods are an interesting and clean alternative for the abatement of toxic organic pollutants. This paper details the study of the synthesis of electrode materials of nominal composition Ti/PbXTi1-XO2 (X = 0; 0.05; 0.10; 0.20 e 0.30) and their use as electrodes for degradation of organic pollutants using both electrochemical and photo-assist
Quím. Nova. Publicado em: 2016-06
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20. Ni(II), Cu(II), AND Zn(II) COMPLEXES DERIVED FROM A NEW SCHIFF BASE 2-((Z)-(3-METHYLPYRIDIN-2- YLEIMINO)METHYL)PHENOL AND SYNTHESIS OF NANO SIZED METAL OXIDE PARTICLES FROM THESE COMPOUNDS
Synthesis, spectral identification, and magnetic properties of three complexes of Ni(II), Cu(II), and Zn(II) are described. All three compounds have the general formula [M(L)2(H2O)2], where L = deprotonated phenol in the Schiff base 2-((z)-(3-methylpyridin-2-yleimino)methyl)phenol. The three complexes were synthesized in a one-step synthesis and characterize
Quím. Nova. Publicado em: 2015-11
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21. Synthesis and characterization of poly(S-2-mercaptoethyl 2-(thiophen-3-yl)ethanethioate) by electrochemical polymerization
Abstract A novel monomer of S-2-mercaptoethyl 2-(thiophen-3-yl)ethanethioate (MTE) were synthesized via esterification reaction between 2-(thiophen-3-yl)acetic and ethane-1,2-dithiol in the presence of dicyclohexyl-carbodiimide (DCC) and N,N’-dimethylpyridin-4-amine (4-DMAP) as catalytic system. The structure of monomer was characterized via MS, 1H-NMR and
Polímeros. Publicado em: 2015-10
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22. Synthesis of Poly (2,5-dimethoxyaniline) and Electrochromic Properties
Poly(2,5-dimethoxyaniline) (PDMA) was synthesized using electrochemical polymerization of DMA in oxalic acid. The PDMA film coated onto ITO glass was studied for its chemical structure, morphology, electro-deposition, and electro-activity by FT-IR, TGA, SEM, cyclic voltammetry, and UV-Vis spectrophotometry. The PDMA film showed reversible color changes from
Mat. Res.. Publicado em: 25/08/2015
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23. Effect of Applied Voltage on Slow-Release of Cu(II) Ions on the Synthesis of Copper(II) Stearate Complex by Electrochemical Technique
An electrochemical technique based on the slow-release of Cu2+ ion from electrochemical oxidation of a Cu anode in the presence of stearic acid (HSt) and an aqueous solution of ammonium acetate (CH3COONH4) (0.1 mol L-1) as supporting electrolyte has been used to synthesize Cu(II) stearate (Cu(II)St) complex. Different values of applied voltages (1, 5 and 10
J. Braz. Chem. Soc.. Publicado em: 2015-06
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24. Proton conductive membranes based on poly (styrene-co-allyl alcohol) semi-IPN
The optimization of fuel cell materials, particularly polymer membranes, for PEMFC has driven the development of methods and alternatives to achieve systems with more adequate properties to this application. The sulfonation of poly (styrene-co-allyl alcohol) (PSAA), using sulfonating agent:styrene ratios of 2:1, 1:1, 1:2, 1:4, 1:6, 1:8 and 1:10, was previous
Polímeros. Publicado em: 10/06/2014