Electrochemical Modification
Mostrando 1-12 de 38 artigos, teses e dissertações.
-
1. Molecularly Imprinted Polypyrrole on Glassy Carbon Electrode Modified with Reduced Graphene Oxide and Gold Nanoparticles for Isoamyl Alcohol Analysis in Fusel Oil
A molecularly imprinted electrochemical sensor for determination of isoamyl alcohol was successfully constructed by modifying the glassy carbon electrode (GCE) with gold nanoparticles (AuNPs) and reduced graphene oxide (RGO). The modification of the GCE increased the electron transfer rate and the electrode surface area, which, consequently, made more room a
J. Braz. Chem. Soc.. Publicado em: 2021-02
-
2. CONVERSÃO FOTOELETROCATALÍTICA DE CO2 E BIOGÁS EM PRODUTOS DE INTERESSE ENERGÉTICO UTILIZANDO SEMICONDUTORES NANOESTRUTURADOS DE Ti/TiO2 MODIFICADOS COM ÓXIDO DE COBRE
This work describes the superficial modification of Ti/TiO2 nanotubes by copper oxide electrochemical deposition, in different temperatures (25 and 65 ºC), and its application on the photoelectrocatalytic conversion of CO2 and biogas in products of energy interest. The different temperatures deposition resulted in the formation of different geometric forms
Quím. Nova. Publicado em: 2020-02
-
3. Dendritic Gold Nanoparticles Towards Transparent and Electroactive Electrodes
Abstract: The combination of UV-visible absorption and electrochemical experiments (spectroelectrochemistry) enables to obtain highly specific spectroscopic information (in situ and operando) from modified surfaces. However, such application can be limited by the self-absorbance, for example, when metallic nanoparticles are present on modified surfaces. Indi
An. Acad. Bras. Ciênc.. Publicado em: 28/11/2019
-
4. Silica/Titania Graphite Composite Modified with Chitosan and Tyrosinase Employed as a Sensitive Biosensor for Phenolic Compounds
A mesoporous, high surface area and conductive silica/titania graphite composite modified with chitosan and functionalized with tyrosinase was prepared. The composite was obtained by the sol-gel method and the surface of the resultant material was modified with chitosan solutions containing 5, 10 and 15% by mass. The textural characterization showed that eve
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
-
5. Produção e caracterização de revestimentos de ligas metálicas Cu-Sn em banho eletrolítico contendo glicina: ensaios preliminares
RESUMO Os problemas relacionados à corrosão são frequentes, podendo ocorrer nas mais variadas áreas, tais como, nas indústrias química, petroquímica, naval, de construção civil e automobilística, dentre outros setores produtivos. Portanto, métodos para prevenir a corrosão devem ser empregados para evitar a perda de materiais e o uso de revestimen
Matéria (Rio J.). Publicado em: 16/09/2019
-
6. Influence of the Gas Pressure of Plasma Nitriding on the Structural, Mechanical and Tribological Surface Properties of AISI 316L
In this paper, the influence of gas nitriding (80% H2-20% N2) pressure (between 3 and 7 Torr) on the modification of surface properties of AISI 316L stainless steel is examined. The structural, mechanical, tribological and electrochemical properties of the layer produced in disk samples were studied. The samples’ characteristics were determined by scanning
Mat. Res.. Publicado em: 15/07/2019
-
7. Application of biosynthesized ZnO nanoparticles on an electrochemical H 2 O 2 biosensor
ABSTRACT ZnO nanoparticles (NPs) were synthesized via a green biochemical method using Corymbia citriodora leaf extract as a reducing and stabilizing agent. The biosynthesized ZnO NPs were characterized by SEM and XRD. An electrochemical H2O2 biosensor was fabricated by modification of a glassy carbon electrode using our proposed ZnO NPs. The electrochemical
Braz. J. Pharm. Sci.. Publicado em: 2016-12
-
8. Voltammetric Determination of Sulfonamides with a Modified Glassy Carbon Electrode Using Carboxyl Multiwalled Carbon Nanotubes
New glassy carbon electrode (GCE) modified with carboxyl multiwalled carbon nanotubes (MWCNTs) and treated with ultrasonic dispersing in N,N-dimethylfomamide (DMF) media, namely DMF/carboxyl/MWCNTs/GCE, was prepared for electrochemical determination of sulfonamides (SAs). Electrochemical behavior of SAs based on DMF/carboxyl/MWCNTs/GCE was investigated by cy
J. Braz. Chem. Soc.. Publicado em: 2016-12
-
9. Characterization of Polylactide-Stabilized Gold Nanoparticles and Its Application in the Fabrication of Electrochemical DNA Biosensors
In this work, two different approaches to gold nanoparticles (AuNPs) have been explored for the modification of screen-printed electrode based on AuNPs and AuNPs stabilized with polylactic acid (PLA). The modified substrate has been characterized using UV-Vis spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), field emission scanni
J. Braz. Chem. Soc.. Publicado em: 2016-09
-
10. Electrochemical Stability and Bioactivity Evaluation of Ti6Al4V Surface Coated with Thin Oxide by EIS for Biomedical Applications
To improve the implants biocompatibility many surface modifications were proposed. Investigations about the surface modification on Ti alloys by anodic oxidation are reported. This research presents a study on the stability of thin titanium dioxide grown by potentiodynamic method on Ti6Al4V surfaces up to 5.0 V. Its bioactive surface in phosphate buffer solu
Mat. Res.. Publicado em: 2015-06
-
11. INVESTIGAÇÃO DO USO DE ELETRODO DE CARBONO VÍTREO MODIFICADO COM HEXACIANOFERRATO DE RUTÊNIO PARA DETECÇÃO DE PROCAÍNA
A glassy carbon electrode modified with ruthenium hexacyanoferrate (RuOHCF) was investigated as an electrocatalyst for the detection of procaine with the aim of quantification in pharmaceutical and forensic samples. The RuOHCF films were prepared by electrochemical deposition, and the parameters used in this process (concentration of RuCl3, K3Fe(CN)6, temper
Quím. Nova. Publicado em: 2015-01
-
12. Corrosion resistance of 2024 aluminum alloy coated with plasma deposited a-C:H:Si:O films
AA 2024 aluminum alloy is widely employed in aeronautic and automobilist industries. Its hardness and low density are attractive properties for such industrial areas. However, since it contains copper, it undergoes severe corrosion in aggressive media as saline or low Earth orbit environments. In this work, it was investigated the properties of films deposit
Mat. Res.. Publicado em: 2014-12