Cyclic Voltammograms
Mostrando 1-12 de 27 artigos, teses e dissertações.
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1. Comparative Study of Degradation of Reactive Dyes and Decolorization and Detoxification in Aqueous Solution Applying DyP Peroxidases Isolated from Saccharomonospora viridis (SviDyP) and Thermobifida fusca (TfuDyp)
The wastewater that originates from the widespread usage of synthetic dyes in the industry have become a severe environmental problem. Several efforts have been made to develop new types of treatment which are capable of performing the degradation of the dyes from the environment. Within this scope, much attention has been drawn to enzymatic approaches, main
J. Braz. Chem. Soc.. Publicado em: 2021-06
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2. Experimental and Theoretical Study of LiMn2O4 Synthesized by the Solution Combustion Method Using Corn Starch as Fuel
Lithium manganese oxide, LiMn2O4, was synthesized in two temperature stages, where the first consisted by an ecofriendly solution combustion method at 300 °C. Finally, the as-burned powders were thermal treated at 500 and 700 °C. The structural and morphological changes were evaluated by the Rietveld method and density functional theory (DFT) calculations.
J. Braz. Chem. Soc.. Publicado em: 2020-02
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3. Scanning Electrochemical Microscopy (SECM) Study of the Electrochemical Behavior of Anodized AZ31B Magnesium Alloy in Simulated Body Fluid
In this work, scanning electrochemical microscopy (SECM) was employed to study the corrosion behavior of anodized AZ31B magnesium alloy exposed to simulated body fluid. SECM measurements were carried out in surface generation/tip collection mode. The hydrogen evolution flux caused during corrosion of the magnesium alloy was oxidized at the ultra-microelectro
Mat. Res.. Publicado em: 28/10/2019
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4. High Order Cyclic Voltammograms During Electrooxidation of Ethanol Catalyzed by Gold
Under fixed limits, potential sweeps in some electrochemical systems depict current profile whose shape repeats in every n cycle (with n > 1), receiving the name of high order voltammograms (HOV). HOV have been observed during electrooxidation of organic molecules catalyzed mainly by Pt. The present study shows HOV behavior during ethanol electrooxidation re
J. Braz. Chem. Soc.. Publicado em: 2017-09
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5. INVESTIGAÇÃO DO USO DE ELETRODO DE CARBONO VÍTREO MODIFICADO COM HEXACIANOFERRATO DE RUTÊNIO PARA DETECÇÃO DE PROCAÍNA
A glassy carbon electrode modified with ruthenium hexacyanoferrate (RuOHCF) was investigated as an electrocatalyst for the detection of procaine with the aim of quantification in pharmaceutical and forensic samples. The RuOHCF films were prepared by electrochemical deposition, and the parameters used in this process (concentration of RuCl3, K3Fe(CN)6, temper
Quím. Nova. Publicado em: 2015-01
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6. Construção de eletrodo de grafite retirado de pilha comum: aplicações didáticas
This paper presents a proposal for using recycled graphite electrodes obtained from exhausted commercial 1.5 V batteries and its application in electroanalysis. The electrode could be prepared by the students and applied in the simple didactic experiments suggested, such as determination of active electrode area, cyclic voltammetry and useful potential range
Quím. Nova. Publicado em: 2014-07
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7. DETERMINAÇÃO DE ÁCIDO LIPÓICO SOBRE ELETRODO DE GRAFITE PIROLÍTICO MODIFICADO COM FTALOCIANINA DE COBALTO / DETERMINATION OF LIPOIC ACID ON PYROLYTIC GRAPHITE ELECTRODE MODIFIED WITH COBALT PHTHALOCYANINE
Lipoic acid, also known as thioctic acid is a compound organosulfur derived from octanoic acid, which is a saturated fatty acid. It is an antioxidant that has the property of suppressing free radicals in both aqueous and lipid environment, which differs from other antioxidants. Nowadays, various techniques are employed for determining the lipoic acid such as
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 03/07/2012
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8. PREPARAÇÃO, CARACTERIZAÇÃO E ESTUDOS ELETROQUÍMICOS DE ELETRODOS MODIFICADOS COM DIFERENTES MONOCAMADAS AUTOORGANIZADAS
In this work were studied investigated different types of modifiers for the formation of self-assembled monolayers on the gold surface. The monolayers used were formed by different structural arrangements, alkyl chains and functional groups. The thiols groups used were: 3-mercaptopropionic acid (MPA), thiolactic acid (TLA), cystamine (CYS) and 11-mercaptound
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 03/03/2011
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9. Electrodeposition of gold from formaldehyde-sulfite baths: bath stability and deposits characterization
It was investigated Au(I)-sulfite baths containing formaldehyde. As a result, high stability was achieved for baths containing formaldehyde concentration close to 10 mL L-1 with a lifetime superior to 600 days. On the other hand, cyclic voltammograms indicated that the increase of formaldehyde concentration in the bath promotes decreasing of the maximum cath
Química Nova. Publicado em: 2011
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10. Syntheses, Characterization and Chemical Reactivity of Chloro and Nitrosyl Complexes of trans-Tetrakispyridines of Ruthenium / Síntese, caracterização e reatividade química de complexos de cloro e nitrosil de trans-Tetrakispiridina de rutênio
The complexes trans-[RuCl2(L)4] (L = py, isn, 4-acpy e 3-acpy), trans-[RuCl(NO)(L)4](PF6)2 (L = py, isn e 4-acpy), trans-[Ru(OH)(NO)(py)4](PF6)2, trans-[RuCl(NO)(py)4]Cl23H2O, trans-[Ru(OH)(NO)(py)4]Cl2, cis-[RuCl2(DMSO)4], trans-[Ru(NO2)2(py)4], trans-[RuCl(NO2)(py)4], trans-[RuCl(acn)(py)4](PF6) and the reduced complex trans-[RuCl(NO)(py)4]I were synthesiz
Publicado em: 2009
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11. Comportamento eletroquímico da N-nitrosotiazolidina ácido carboxílico sobre eletrodos de ouro e mercúrio
The electrochemical behavior of N-nitrosothiazolidine carboxylic acid (NTAC) on gold and hanging mercury electrodes, using the cyclic and square wave voltammetries, was studied. Whereas NTAC suffer reduction in a single step on the mercury electrode, two peaks appears on the cyclic voltammograms on the gold electrode, one anodic peak overlaying the gold oxid
Química Nova. Publicado em: 2008
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12. Estudo da aplicação de naftaleno-diimidas para o desenvolvimento de sensores e dispositivos: eletroquimica de eletrodos modificados de carbono vítreo e compósitos com nanotubos de carbono / Study of the application of naphthalene-diimides for the development of sensors and devices: electrochemistry of carbon glassy modified electrodes and composites with carbon nanotubes
Four naphthalene-diimides (NDIs) were synthesized functionalyzed with N- alkyl-amino and N-alkyl-hydroxi groups. These NDIs were characterized by conventional spectrometric methods. The electrochemical properties of NDIs were studied through cyclic voltametry in acetonitrile and N-metyl-pyrrolidone. Typical voltammograms present two reversible redox processe
Publicado em: 2007