Catalytic Oxidation
Mostrando 25-36 de 317 artigos, teses e dissertações.
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25. Synthetic Niobium Oxyhydroxide as a Bifunctional Catalyst for Production of Ethers and Allyl Alcohol from Waste Glycerol
A synthetic niobia was modified by treatment with hydrogen peroxide to be used as a catalyst for converting glycerol into petrochemical compounds. The catalytic properties of niobium oxyhydroxide were obtained by generating acidic and oxygenated groups (peroxo groups) on the solid surface. Compounds like ethers and allyl alcohol were obtained. A very active
J. Braz. Chem. Soc.. Publicado em: 2017-11
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26. AgAu Nanotubes: Investigating the Effect of Surface Morphologies and Optical Properties over Applications in Catalysis and Photocatalysis
We herein report the preparation of AgAu nanotubes displaying controlled surface morphologies and optical properties by varying the reaction temperature during the galvanic reaction between Ag nanowires and AuCl4-(aq). As the AgAu nanotubes presented similar sizes and compositions, they enabled us to isolate the influence of surface morphology and optical pr
J. Braz. Chem. Soc.. Publicado em: 2017-09
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27. Ethylene glycol oxidation on ternary PtRhNi/C electrocatalyst with different metal compositions
ABSTRACT Direct Alcohol Fuel Cells (DAFC’s) are an alternative to fuel cell systems and when is used alkaline medium this has an increase performance. The alkaline direct alcohol fuel cells (ADAFC's) have some advantages such as low-emission, high energy efficiency, improved oxidation kinetics, low crossover and in addition there is a broad range of materi
Matéria (Rio J.). Publicado em: 20/07/2017
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28. Ethylene Glycol Electro-Oxidation on Platinum-Free Surfaces: How the Composition of PdRuRh Surfaces Influences the Catalysis
In this work we performed electrochemical (cyclic voltammetry and chronoamperommetry) and spectroelectrochemical studies (in situ Fourier transform infrared (FTIR)) in PdRuRh electrodeposits in acidic media in presence of ethylene glycol (0.5, 1.0 and 2.0 mol L-1). The electrochemical results show that the ethylene glycol oxidation is sensitive to the compos
J. Braz. Chem. Soc.. Publicado em: 2017-06
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29. Low Potential and Non-Enzymatic Hydrogen Peroxide Sensor Based on Copper Oxide Nanoparticle on Activated Pencil Graphite Electrode
An electrochemical sensor for H2O2 determination was prepared by electrodepositing copper oxide nanoparticles on the activated pencil graphite electrodes. At first, a study has been made of the optimum conditions for chemical activation of the pencil graphite electrodes (APGE) and then the activated pencil graphite electrode was modified with copper oxide na
J. Braz. Chem. Soc.. Publicado em: 2017-05
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30. Gallium-Containing Mesoporous Silica: Supported Catalysts with High Catalytic Activity for Oxidation of Benzene, Toluene and o-Xylene
Benzene, toluene and xylene (BTX) are a particular class of volatile organic compounds, which are highly toxic pollutants. In this study, samples of gallium-containing mesoporous silica (MS-Ga7% and MS-Ga11%) were synthesized and their catalytic activity in the oxidation of BTX was investigated. The physicochemical characterization shows that the inclusion o
J. Braz. Chem. Soc.. Publicado em: 2017-01
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31. Optimization of Reaction Conditions for Cyclohexane to Cyclohexanone with t-Butylhydroperoxide Over CuCl2 Loaded with Activated Carbon
Catalytic oxidation of hydrocarbons can be performed efficiently in the presence of tert- butylhydroperoxide (TBHP) under a low-valent transition metal as the catalyst. CuCl2 loaded with activated carbon had synthesized and characterized by X-ray diffraction (XRD) and energy-dispersive X-ray spectroscopy (EDX), and then utilized as a catalyst for the oxidati
J. Braz. Chem. Soc.. Publicado em: 2016-01
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32. OXIDATION OF PHENOL IN AQUEOUS SOLUTION WITH COPPER OXIDE CATALYSTS SUPPORTED ON γ-Al2O3, PILLARED CLAY AND TiO2: COMPARISON OF THE PERFORMANCE AND COSTS ASSOCIATED WITH EACH CATALYST
Abstract The Catalytic Wet Air Oxidation (CWAO) of phenol using copper oxide catalysts supported by γ-Al2O3, TiO2, and pillared clay was evaluated to identify which of these catalysts was the most appropriate for this reaction. The CuO/PILC, CuO/γ-Al2O3 and CuO/TiO2 catalysts were the most successful at removing phenol and resulted in more than 96% convers
Braz. J. Chem. Eng.. Publicado em: 2015-12
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33. Synthesis and characterization of poly(S-2-mercaptoethyl 2-(thiophen-3-yl)ethanethioate) by electrochemical polymerization
Abstract A novel monomer of S-2-mercaptoethyl 2-(thiophen-3-yl)ethanethioate (MTE) were synthesized via esterification reaction between 2-(thiophen-3-yl)acetic and ethane-1,2-dithiol in the presence of dicyclohexyl-carbodiimide (DCC) and N,N’-dimethylpyridin-4-amine (4-DMAP) as catalytic system. The structure of monomer was characterized via MS, 1H-NMR and
Polímeros. Publicado em: 2015-10
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34. Synthesis, Characterization and Applications of Iron Oxide Nanoparticles - a Short Review
ABSTRACT: Iron oxide is a mineral compound that shows different polymorphic forms, including hematite (α-Fe2O3), magnetite (Fe3O4) and maghemite (γ-Fe2O3). Solid propulsion technology nanoparticulate materials, such as hematite and maghemite, exhibit high performance on thermal decomposition of ammonium perchlorate. The enhanced catalytic effect of metalli
J. Aerosp. Technol. Manag.. Publicado em: 2015-09
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35. KINETIC STUDY OF SELECTIVE GAS-PHASE OXIDATION OF ISOPROPANOL TO ACETONE USING MONOCLINIC ZRO2 AS A CATALYST
Zirconia was prepared by a precipitation method and calcined at 723 K, 1023 K, and 1253 K in order to obtain monoclinic zirconia. The prepared zirconia was characterized by XRD, SEM, EDX, surface area and pore size analyzer, and particle size analyzer. Monoclinic ZrO2 as a catalyst was used for the gas-phase oxidation of isopropanol to acetone in a Pyrex-gla
Quím. Nova. Publicado em: 2015-08
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36. Kinetic Parameters of Soot Oxidation Catalyzed by Nanosized ZnO-CeO2 Solids
Catalytic combustion of soot was performed over ZnO:CeO2 catalysts obtained via a non‑alkoxide sol-gel route. Different kinetics parameters were calculated through thermal analyses, thus, enabling the correlation between the experimental data and the decomposition mechanisms probably associated with the soot decomposition in each case.
J. Braz. Chem. Soc.. Publicado em: 2015-07