Carbon Paste Electrode
Mostrando 1-12 de 64 artigos, teses e dissertações.
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1. Magnetic and Mesoporous Silica-Niobia Material as Modifier of Carbon Paste Electrode for p-Nitrophenol Electrochemical Determination
In the present work, the sol-gel synthesis method was employed as strategy to obtain a magnetic and mesoporous silica-niobia material. The planned synthesis was based on the hetero-condensation of niobium and silicon alkoxide precursors, in the presence of spherical magnetite particles. The resulting material presented interesting characteristics such as mag
J. Braz. Chem. Soc.. Publicado em: 2021-03
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2. Drawing Electrochemical Sensors Using a 3D Printing Pen
This communication demonstrates that a 3D printing pen, commercially-available as a toy for kids, can be used to draw thermoplastic electrochemical sensors using conductive filaments over any desirable format and substrate. A polylactic acid filament containing graphene or carbon black was passed through the 3D pen that works as a handheld 3D printer (fused
J. Braz. Chem. Soc.. Publicado em: 2020-09
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3. Chemically-Activated Biochar from Ricinus communis L. Cake and Their Potential Applications for the Voltammetric Assessment of Some Relevant Environmental Pollutants
Biochar is a rich-carbon material highly functionalized, which allows the use as electrodes modifier for preconcentration and voltammetric determination of several species. This work describes a castor cake biochar production and chemical activation with different reaction conditions using HNO3 and/or H2O2. Biochar samples were characterized using scanning e
J. Braz. Chem. Soc.. Publicado em: 2020-05
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4. Electrode Modified with the Ionic Liquid [P6,6,6,14+]2[MnCl42-] for the Determination of Bisphenol A in Plastic Samples
This paper describes a new and simple electrode for the determination of bisphenol A (BPA) in different plastic samples using carbon paste electrode (CPE) modified with a trihexyltetradecylphosphonium tetrachloromanganate(II) ([P6,6,6,14+]2[MnCl42-]) magnetic ionic liquid (MIL/CPE). Electrochemical characterization of MIL/CPE by cyclic voltammetry and electr
J. Braz. Chem. Soc.. Publicado em: 21/10/2019
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5. Construction and Evaluation of a Graphene Oxide Functionalized Aminopropyltriethoxy Silane Surface Molecularly Imprinted Polymer Potentiometric Sensor for Dipyridamole Detection in Urine and Pharmaceutical Samples
A dipyridamole (DIP) based surface molecularly imprinted polymer (MIP) was synthesized and applied as a sensing agent in a sensing layer of a new modified potentiometric carbon paste electrode (CPE). The potentiometric modified CPEs (GO@SiO2-NH2-MIP/MWCNTs/CPE, where GO is graphene oxide and MWCNTs is multi-walled carbon nanotubes) showed an improved perform
J. Braz. Chem. Soc.. Publicado em: 16/09/2019
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6. Semiconductor Nanocrystals-Reduced Graphene Composites for the Electrochemical Detection of Carbendazim
A new nanocomposite based on ZnCdTe semiconductor nanocrystals (NCs) synthesized in situ on reduced graphene oxide (rGO) was obtained. The heterostructure was characterized using UV-Vis emission and absorption spectroscopies, which provided evidences of the growth of the nanocrystals onto the rGO matrix. To evaluate the electrochemical performance, carbon pa
J. Braz. Chem. Soc.. Publicado em: 23/05/2019
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7. Adsorptive Stripping Voltammetric Determination of Oxolinic Acid in Water Sample
One new methodology for analysis of the antimicrobial oxolinic acid (OXA) based on adsorptive stripping voltammetry (AdSV) in carbon paste electrode (CPE) was developed and applied in untreated pond water sample. Cyclic voltammetry (CV) indicated that an irreversible anodic process occurs in KOH solution as supporting electrolyte. Quantification of the antim
J. Braz. Chem. Soc.. Publicado em: 2018-07
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8. Development of a Novel and Simple Electroanalytical Procedure for the Determination of Copper in Biofuel Employing a Sensor Based on Vulcan Functionalized with Carbazone
A novel and simple electroanalytical method for the determination of Cu2+ in biodiesel samples by stripping voltammetric analysis was developed. The method employs a carbon paste electrode (CPE) modified with Vulcan carbon, previouly functionalized with carbazone (CBZ). The CPE/Vulcan-CBZ sensor promoted a significant increase in the analytical signal obtain
J. Braz. Chem. Soc.. Publicado em: 2018-04
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9. Determination of Chlorophenol in Environmental Samples Using a Voltammetric Biosensor Based on Hybrid Nanocomposite
In this work, a simple electrochemical biosensor for 4-chlorophenol was developed based on laccase immobilized on a hybrid nanocomposite (ZnO nanoparticles/chitosan), and incorporated in a carbon paste electrode. There are few biosensors in the literature for this specific pollutant because it tends to form polymeric films on the electrode, causing surface p
J. Braz. Chem. Soc.. Publicado em: 2017-07
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10. A Sensitive Voltammetric Determination of Anti-Parkinson Drug Pramipexole Using Titanium Dioxide Nanoparticles Modified Carbon Paste Electrode
In this study, a facile sensor based on TiO2 nanoparticles modified carbon paste electrode was developed for voltammetric determination of pramipexole in pharmaceutical formulations and biological samples. Surface of the fabricated electrode have been characterized using field emission scanning electron microscopy. Under the optimized experimental conditions
J. Braz. Chem. Soc.. Publicado em: 2017-04
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11. Electrodeposition of Gold Films from a Glycerol Solution on Carbon Paste Electrode and the Effect of Chemical and Electrochemical Parameters of Electrodeposition on the Electrode Performance in Potassium Ferrocyanide Solution
The gold electrodeposition process from a glycerol solution on a carbon paste electrode (CPE) was investigated by voltammetry and the morphologies of the electrodeposits were analyzed by scanning electron microscopy (SEM). Voltammetric study indicated that AuCl4− was reduced to Au0 and the process was mixed controlled (mass transport and electron transfer)
J. Braz. Chem. Soc.. Publicado em: 2017-01
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12. A Kinetic, Equilibrium, and Thermodynamic Study on the Biosorption of Tl+ and Cd2+ by Eichhornia crassipes Roots Using Carbon Paste Electrode
In this work, Eichhornia crassipes roots were used as a modifier for carbon paste electrode in a biosorption study of thallium (Tl+) and cadmium (Cd2+) ions. The ions were accumulated on modified electrode surfaces at open circuit potential and analyzed by square wave anodic stripping voltammetry. Before the biosorption study, the effect of ratio of biomass
J. Braz. Chem. Soc.. Publicado em: 2016-09