Capillary Electrophoresis Separation
Mostrando 13-24 de 74 artigos, teses e dissertações.
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13. Princípios da determinação de íons em amostras por eletroforese capilar.
ABSTRACT: This work presents theory and applications in capillary electrophoresis. This technique is a powerful tool representing a large saving in chemicals (0.5 to 4 nL s-1 flux), samples (1 to 100 nL), and method development time. In addition, this work pictures applications such as separation and determination of analytical compounds. Recent reviews were
Planaltina. Publicado em: 2011
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14. Desenvolvimento e validação de método analítico para determinação de benzoato, sorbato, metil e propilparabenos em produtos alimentícios utilizando a eletroforese capilar
In this work, a rapid and simple method using capillary electrophoresis (CE) was developed for the determination of the benzoate, sorbate, methyl and propylparaben in foodstuffs. A running buffer consisting of 20 mmol L-1 (pH = 9.3) tetraborate enabled separation of the analytes in less than 5 min. The detector wavelength was set at 220 nm. The method was su
Química Nova. Publicado em: 2011
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15. Determination of cetirizine in tablets and compounded capsules: comparative study between CE and HPLC
A capillary electrophoresis (CE) method was developed and validated for determination of cetirizine dihydrochloride in tablets and compounded capsules. The electrophoretic separation was performed in an uncoated fused-silica capillary (40 cm x 50 μm i.d.) using 20 mmol L-1 sodium tetraborate buffer (pH 9.3) as background electrolyte, a hydrodinamic sample i
Química Nova. Publicado em: 2010
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16. Eletrophoretic and spectrometric characterization of Cinchona extracts of use phytoterapic and cosmetic / Caracterização eletroforética e espectrométrica de extratos de Cinchona de uso fitoterápico e cosmético
Every year, malaria kills about one million people. According to OMS, 3.3 billion people, half of the world population, are exposed to the disease, mostly in underdeveloped countries. The pharmaceuticals used in the treatment of malaria include: chloroquine, primaquine, quinine, mefloquine, doxyclyne, clindamicina and artemisin. The increased resistance of t
Publicado em: 2010
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17. Otimização da separação de compostos fenolicos por eletroforese capilar e analise da composição em acidos graxos de azeite de oliva extravirgem / Optimization of phenolic compound separation by capillary electrophoresis and analysis of extra-virgin olive oil fatty acid profiles
Nos últimos anos, o interesse em relação ao consumo do azeite de oliva aumentou significativamente, em função da divulgação dos benefícios à saúde provenientes da sua ingestão. O azeite de oliva extravirgem é obtido das azeitonas somente por meios mecânicos, e a ausência de etapas posteriores de refino permite a retenção de diversos compostos
Publicado em: 2010
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18. Desenvolvimento e otimização de metodologia para análise de edulcorantes por Eletroforese Capilar
An innovative methodology was developed to simultaneously separate and quantify aspartame, cyclamate, saccharin and acesulfame-K through capillary electrophoresis with direct and indirect detection of UV, analysis time of roughly 6 minutes and with no sample derivatization. As the cyclamate has low absorptivity we used a system of electrolyte added to a chro
Publicado em: 2010
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19. Eletrocromatografia capilar: contextualização, estado da arte e perspectivas
Capillary electrochromatography (CEC) is a separation technique in which the mobile phase flow is based on the application of a voltage across a packed capillary, which generates an electroosmotic flow that transports the analytes along the capillary toward the detector. As it combines the separation mechanisms of high-performance liquid chromatography (HPLC
Química Nova. Publicado em: 2009
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20. Estratégias de pré-concentração em eletroforese capilar (CE): parte 1. Manipulação da velocidade eletroforética do analito
Capillary electrophoresis has become a well-established and routine-based separation technique. It is based on the differences between charged analyte mobility in aqueous or organic electrolytes. Its major limitation is the sensitivity due to small sample injection volumes and the narrow diameter of the capillaries, especially when UV detection is used. Ther
Química Nova. Publicado em: 2009
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21. DEVELOPMENT OF A CAPILLARY ELECTROPHORESIS SYSTEM WITH CONTACTLESS CONDUCTIVITY DETECTION (C4D) FOR THE SEPARATION OF INORGANIC IONS / DESENVOLVIMENTO DE EQUIPAMENTO DE ELETROFORESE CAPILAR COM DETECÇÃO POR CONDUTIVIDADE SEM CONTATO PARA A SEPARAÇÃO DE ÍONS INORGÂNICOS
This work describes the development and evaluation of a home-made capillary electrophoresis (CE) system based on the capacitively coupled contactless conductivity detection (C4D) for the application in capillary zone electrophoresis (CZE). The C4D detection is based on prototypes previously described in the literature. The equipment constructed has a hydrody
Publicado em: 2009
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22. Determinação simultânea de cátions empregando eletroforese capilar com detecção condutométrica sem contato em equipamento construído em laboratório
This work describes the development of a home-made capillary electrophoresis (CE) system based on the capacitively coupled contactless conductivity detection (C4D) for the separation of the metallic species Zn2+, Cr3+, Pb2+, Cd2+, Co2+, Cu2+, Ni2+ e Tl+. A background electrolyte composed of MES/Histidine 0,02 mol L-1 (pH 5.0) was optimized for the separation
Química Nova. Publicado em: 2009
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23. DEVELOPMENT AND VALIDATION OF METHODOLOGY FOR THE EVALUATION OF RUPATADINE BY LIQUID CHROMATOGRAPHY AND CAPILLARY ELECTROPHORESIS / DESENVOLVIMENTO E VALIDAÇÃO DE METODOLOGIA PARA AVALIAÇÃO DE RUPATADINA POR CROMATOGRAFIA LÍQUIDA E ELETROFORESE CAPILAR
Rupatadine is a second generation antihistamine H1, from the pyperidinic group, which inhibits both the histamine and platelet activating factor effects, and is clinically used for the treatment of allergic rhinitis and chronic urticaria. The methods for the evaluation of rupatadine in pharmaceutical products were developed and validated in the present work.
Publicado em: 2009
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24. DEVELOPMENT AND VALIDATION OF METHODOLOGY FOR THE EVALUATION OF FLUTICASONE BY LIQUID CHROMATOGRAPHY AND CAPILLARY ELECTROPHORESIS / DESENVOLVIMENTO E VALIDAÇÃO DE METODOLOGIA PARA AVALIAÇÃO DE FLUTICASONA POR CROMATOGRAFIA LÍQUIDA E ELETROFORESE CAPILAR
Fluticasone propionate (FP) is a synthetic glucocorticoid with potent anti-inflammatory activity that has been effectively used for the treatment of seasonal and allergic perennial rhinitis, minimizing systemic activity. In the present study, the methods were developed and validaded for assessment of FP in pharmaceutical products. The analysis by reversed-ph
Publicado em: 2009