The reaction of 1-tetralones with thallium trinitrate supported on clay: ring contraction vs alpha-oxidation

AUTOR(ES)

Ferraz, Helena M. C., Silva Jr., Luiz F., Aguilar, Andrea M., Vieira, Tiago O.

FONTE

Journal of the Brazilian Chemical Society

DATA DE PUBLICAÇÃO

2001-10

RESUMO

A reação de uma série de 1-tetralonas com trinitrato de tálio adsorvido em Montmorilonita K-10 forneceu produtos de contração de anel (1-indanocarboxilatos de metila) e/ou alfa-oxidação (2-metóxi-1-tetralonas), em rendimentos bastante variáveis.

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