"Síntese e caracterização espectroscópica de materiais orgânicos para eletrônica molecular" / "Synthesis and spectroscopic characterization of the organic materials for molecular electronic"

AUTOR(ES)
DATA DE PUBLICAÇÃO

2002

RESUMO

This work was separated in two parts, in the first, called PART A, the synthesis of the polymers PPV, Cl-PPV, Br-PPV and of the co-polymers (Cl-PPV)m / (PPV)n and (Br-PPV)m / (PPV)n in the following relationships m:n of 30:70; 50:50 and 70:30 are presented. These polymers were characterized by infrared spectroscopy, UVvisible and fluorescence emission. The modifications caused in the polymers due to the doping with iodine vapor and 0,12M ferric chloride in nitrometano solution were studied also by these same techniques. The doping of PPV with iodine vapor have been monitored by optical spectroscopy allowing us to do the attribution of the polaronic and bipolaronic bands. Measurements of cyclic voltametry revealed important electric properties of these polymers, such as the Electronic Affinity (HOMO), Ionization Potential (LUMO) and " GAP " that is the difference between those two energy levels. The co-polymers presented smaller values of GAP than PPV and HOMO and of LUMO energy levels that can be appropriate to the use these materials in Light-Emitting Devices (LED). In PARTE B, the synthesis of an unpublished compound is presented, the 4-(2-fenoxi-p-xileno)-N-methyl-1,8-naftalimida, here called as NPOX. The characterization of NPOX was made by of nuclear magnetic resonance of proton vii spectroscopy (1H NMR), Gas Cromatography/ Mass Spectrometry (GC/MS), UVVisible and Fluorescence Emission spectroscopy. NPOX is soluble in chloroform that when evaporated it promotes in a transparent film formation. This film has fluorescence emission in 456 nm when excited in 363 nm. The film also showed a similar behavior as diodes that was demonstrated by the electric measurement of current versus potential (I x V curve). These properties open the possibility of the use of NPOX as activate layer, with emission in the blue region, in OLED (Organic Light- Emitting Devices).

ASSUNTO(S)

oled - organic light-emiting devices ppv co-polímeros ppv co-polymers oled - dispositivos orgânicos de emissão de luz

ACESSO AO ARTIGO

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