Experimental and theoretical research on catalytic synthesis of thiophene from furan and H2S
AUTOR(ES)
Song-Qing, Hu, Jian-Ye, Yuan, Xin, Shi, Ai-Ling, Guo, Jian-Chun, Hu
FONTE
Brazilian Journal of Chemical Engineering
DATA DE PUBLICAÇÃO
2011-03
RESUMO
The yield of thiophene from furan and H2S was investigated using selected catalyst carriers (alumina, active carbon and silica gel) and active ingredients (silicotungstic, phosphomolybdic and phosphotungstic acids) to obtain the optimized synthesis parameters. The experimental results indicated that the yield of thiophene reached a maximum when the supported catalyst was alumina and the active ingredient was phosphotungstic acid. Furthermore, the reaction mechanism of the optimized reactive system was studied by the density functional theory (DFT) method. The calculated energy profile indicated that there were four transition states in the reaction process.
Documentos Relacionados
- Stimulation of H2S Emission from Pumpkin Leaves by Inhibition of Glutathione Synthesis 1
- Fotoionização do H2S
- Synthesis and Insecticidal Activity of Lactones Derived from Furan-2(5H)-one
- Observations on brilliant green agar with H2S indicator.
- Experimental and Computational Studies of the Adsorption of Furan, Pyrrole, and Thiophene on Hydroxyapatites in a Single and Ternary Component