Electronic and steric tuning of ancilary ligands in the reactivity of catalysts for metathesis polymerization / Sintonia eletrônica e estéreo de ligantes ancilares na reatividade de catalisadores para polimerização via metátese

AUTOR(ES)
DATA DE PUBLICAÇÃO

2008

RESUMO

The complex [RuCl2(PPh2Bz)3] (1) is active in ROMP of norbornene. At 50 °C in presence of EDA, it is observed promptly precipitation of polymer. It is obtained c.a. 50% yield at 50 ºC for either 5 min or 30 min. The PDI value is larger when increasing the reaction time. This complex presents high yields when increasing the [NBE]/[Ru] ratio, with a quantitative reaction when [NBE]/[Ru] = 15,000. When the [NBE]/[Ru] ratio is 1,000, it is obtained polymodal polymer chains. Changing one PPh2Bz molecule in 1 for piperidine, the new complex [RuCl2(PPh2Bz)2pip] (2) is active at 25 ºC for 30 min with 92% yield (PDI = 2.22). Quantitative yield is obtained at 50 ºC for 30 min. The increase of [NBE]/[Ru] ratio affords the decrease in the yield when using this complex. The complexes [RuCl2(PPh2Bz)2(nic)2] (3) and [RuCl2(PPh2Bz)2(isn)2] (4) do not show good activity at 25 ºC up to 30 min. It is obtained 7.2% yield at 50 ºC for 5 min and 12.0% for 30 min with 5µL of EDA.

ASSUNTO(S)

metathesis metátese rutênio romp ruthenium romp

ACESSO AO ARTIGO

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