Alternativas analíticas para determinação de ferro e titânio em cimento Portland
AUTOR(ES)
Franco Jr., Jorge de O., Korn, Maria das Graças A., Costa, Antonio Celso S., Santos Jr., Anibal de Freitas, Teixeira, Leonardo S. G.
FONTE
Química Nova
DATA DE PUBLICAÇÃO
2001-04
RESUMO
In the present work four different analytical methodologies were studied for the determination of iron and titanium in Portland cement. The cement samples were dissolved with hot HCl and HF, being compared Fe and Ti concentrations through four analytical methods: molecular absorption spectrophotometry using the reagents 1,2-hydroxybenzene-3,5-disulfonic acid (Tiron) and the 5-chloro-salicylic acid (CSA), inductively coupled plasma atomic emission spectrometry (ICP-AES) and flame atomic absorption spectrophotometry (FAAS). In the spectrophotometric determinations were studied pH conditions, reagents addition order, interferences, amount of reagents, linear range and stability of the system. In the techniques of ICP-AES and FAAS were studied the best lines, interferences, sensibility and linear range. The obtained results were compared and the agreement was evaluated among the methods for the determination of the metals of interest.
Documentos Relacionados
- Estudo comparativo de métodos analíticos para a determinação de Fe e Ti em cimento Portland.
- Aplicação de lama de minério de ferro em forma de póna presença de cimento portland
- OBTENÇÃO DE COMPÓSITOS HÍBRIDOS BASEADOS EM HIDROGÉIS E CIMENTO PORTLAND
- Areia descartada de fundição para uso em concreto de cimento Portland: análise do agregado
- Metodologias analíticas para determinação das fumonisinas em milho e alimentos à base de milho