Anodic Voltammetry In Square Wave
Mostrando 1-12 de 14 artigos, teses e dissertações.
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1. Electroanalytical Method for Determination of Trace Metals in Struvite Using Electrochemically Treated Screen-Printed Gold Electrodes
We present an electroanalytical method using square-wave anodic stripping voltammetry on electrochemically-treated screen-printed gold electrodes to the simultaneous determination of lead(II), copper(II) and mercury(II) in struvite (natural fertilizer produced from urine). Electrochemical treatment via cyclic voltammetry of the working electrodes increased s
J. Braz. Chem. Soc.. Publicado em: 2020-09
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2. Development of a Novel and Simple Electroanalytical Procedure for the Determination of Copper in Biofuel Employing a Sensor Based on Vulcan Functionalized with Carbazone
A novel and simple electroanalytical method for the determination of Cu2+ in biodiesel samples by stripping voltammetric analysis was developed. The method employs a carbon paste electrode (CPE) modified with Vulcan carbon, previouly functionalized with carbazone (CBZ). The CPE/Vulcan-CBZ sensor promoted a significant increase in the analytical signal obtain
J. Braz. Chem. Soc.. Publicado em: 2018-04
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3. ANÁLISE POR INJEÇÃO SEQUENCIAL COM DETECÇÃO POR VOLTAMETRIA DE ONDA QUADRADA PARA DETERMINAÇÃO DE As(III) EM AMOSTRAS DE ÁGUAS USANDO ELETRODO DE OURO
A sequential injection method with square wave anodic stripping voltammetry (SI-SWASV) using screen printed and crystalline gold electrode was developed for determination of As(III). The carrier solution used for electrode conditioning and stripping medium was composed of 0.050 mol L-1 HCl, whereas the supporting electrode for samples (deposition medium) was
Quím. Nova. Publicado em: 2018-01
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4. A Kinetic, Equilibrium, and Thermodynamic Study on the Biosorption of Tl+ and Cd2+ by Eichhornia crassipes Roots Using Carbon Paste Electrode
In this work, Eichhornia crassipes roots were used as a modifier for carbon paste electrode in a biosorption study of thallium (Tl+) and cadmium (Cd2+) ions. The ions were accumulated on modified electrode surfaces at open circuit potential and analyzed by square wave anodic stripping voltammetry. Before the biosorption study, the effect of ratio of biomass
J. Braz. Chem. Soc.. Publicado em: 2016-09
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5. Simultaneous Voltammetric Determination of Antihypertensive Drugs Amlodipine and Atenolol in Pharmaceuticals Using a Cathodically Pretreated Boron-Doped Diamond Electrode
The simultaneous voltammetric determination of antihypertensive drugs amlodipine besylate (AML) and atenolol (ATN) using a cathodically pretreated boron-doped diamond electrode (CP-BDDE) is reported for the first time. The anodic peak potentials of AML and ATN at a CP-BDDE were found to be 0.727 and 1.32 V (vs. Ag/AgCl (3.0 mol L-1 KCl)) in phosphate buffer
J. Braz. Chem. Soc.. Publicado em: 2016-06
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6. Especiação de cobre e zinco em urina: importância dos metais em doenças neurodegenerativas
Metals such as copper and zinc are essential for the development and maintenance of numerous enzymatic activities, mitochondrial functions, neurotransmission, and also for memorization and learning. However, disruption in their homeostasis can cause neurodegenerative disorders such as the Alzheimer and Parkinson diseases. In this work, the speciation of copp
Quím. Nova. Publicado em: 2012
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7. Desenvolvimento de método eletroanalítico para determinação direta de cobre em biodiesel e monitoramento do metal em biodiesel exposto a condições simuladas de armazenamento
A simple, effective and low cost for copper determination in biodiesel, without decomposition of the sample is presented. The samples of biodiesel were diluted in a hydro-ethanolic solution (containing HCl as supporting electrolyte) generating a homogeneous ternary system (water-ethanol-biodiesel) in which copper was detected directly using potentiometric st
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 19/09/2011
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8. DETERMINAÇÃO DE Pb (II) EM MICROEMULSÕES DE BIODIESEL USANDO ELETRODO DE FILME DE BISMUTO PELA VOLTAMETRIA DE REDISSOLUÇÃO ANÓDICA NO MODO ONDA QUADRADA / DETERMINATION OF PB (II) MICROEMULSIONS IN BIODIESEL USING BISMUTH ELECTRODE FILM BY ANODIC STRIPPING VOLTAMMETRY SQUARE WAVE MODE
O biodiesel tem sido estudado como uma das alternativas energéticas na redução de emissões de gases, no entanto, precisa-se avaliar a qualidade desse biocombustível devido à presença de possíveis contaminantes, tais como os metais, que degradam o biodiesel durante o processo de estocagem, além de possíveis emissões de resíduos oriundos da sua pro
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 12/08/2011
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9. SIMULTÂNEA DE METAIS EM BIODIESEL, POR VOLTAMETRIA DE REDISSOLUÇÃO ANÓDICA USANDO ELETRODO DE FILME DE MERCÚRIO EM MEIO ALCÓOLICO / SIMULTANEOUS METAL IN BIODIESEL BY VOLTAMMETRY ANODIC STRIPPING USING MERCURY FILM ELECTRODE IN ALCOHOLIC MEDIUM
Diferential pulse and square wave anodic stripping voltammetry at the mercury film electrode, prepared in the ex-situ and in-situ modes, showed an adequate analytical performance and were employed for the development of a procedure for analysis of Biodiesel. Samples were simply diluted into a methanol solution to a final concentration of 0.33 mol L-1 (v/v) a
Publicado em: 2010
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10. Novos materiais para aplicações analíticas nas determinações de compostos orgânicos de interesse farmacêutico e ambiental / New materials for analytical application in organic compound determination for pharmaceutical and environmental interests
Carbon film sensors, built from resistors of 2 Ω nominal resistance, were employed for application in the environment and pharmaceutical fields without previous modification of the electrode surface. When these sensors are electrochemically treated they obtain a wider potential window (both anodic and cathodic regions) than many other forms of carbon. D
Publicado em: 2009
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11. Funcionalization of mesoporous silica with 2-bezothiazolethiol and 3-mercaptopropyltrimetoxysilane for electronalytical application / Funcionalização de sílicas mesoporosas com benzotiazol-2-tiol e 3-mercaptopropiltrimetoxisilano para aplicações em eletroanalítica
Mesoporous silicas were functionalised by immobilisation of organic substances covalently bonded to the silanol groups on the silica surface. SBA-15 nanostructured silica was functionalised by post-synthesis with 2-benzothiazolethiol and silica films modified with 3-mercaptopropyltrimethoxysilane were obtained by direct functionalisation. The characterizatio
Publicado em: 2009
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12. DETERMINATION OF LEAD IN KEROSEN AND IN LUBRICATING OIL BY ANODIC STRIPPING VOLTAMMETRY USING BISMUTH-FILM ELECTRODE AND SAMPLE PREPARATION AS MICROEMULSION / DETERMINAÇÃO DE CHUMBO EM QUEROSENE E EM ÓLEO LUBRIFICANTE POR VOLTAMETRIA DE REDISSOLUÇÃO ANÓDICA USANDO ELETRODO DE FILME DE BISMUTO E MEIO MICROEMULSIONADO
In the presente work, was developed an analytical method aiming the determination of lead in kerosen and in lubricating oil. Anodic redissolution voltammetry with a bismuth-film electrode was employed by measuring the analyte in the sample microemulsions. Square-wave scanning mode (SWV) was employed and the BiFE performance was compared to the one achieved u
Publicado em: 2008