Anodic Stripping Voltammetry
Mostrando 1-12 de 46 artigos, teses e dissertações.
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1. Graphite-Polyurethane Composite Electrode Modified with Molecularly Imprinted Polymer for Determination of Diclofenac
A molecularly imprinted polymer (MIP) was prepared using the anti-inflammatory diclofenac (DCF) as a template. A non-imprinted polymer (NIP) was also prepared as a control. These MIP and NIP were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET), revealing a higher porosity in the fir
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Thallium Associated with Manganese Ore Tailings in a Deactivated Mine in the Western Region of Bahia, Brazil
Thallium (Tl) is a rare metal with toxic effects notably harmful to human health and the environment. In this article, the natural occurrence of Tl was evaluated in a deactivated manganese mine located in the western region of Bahia, Brazil. The extraction procedure with aqua regia was used to dissolve the soil, sediment, and tailings samples. The Tl content
J. Braz. Chem. Soc.. Publicado em: 2021-05
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3. Electroanalytical Method for Determination of Trace Metals in Struvite Using Electrochemically Treated Screen-Printed Gold Electrodes
We present an electroanalytical method using square-wave anodic stripping voltammetry on electrochemically-treated screen-printed gold electrodes to the simultaneous determination of lead(II), copper(II) and mercury(II) in struvite (natural fertilizer produced from urine). Electrochemical treatment via cyclic voltammetry of the working electrodes increased s
J. Braz. Chem. Soc.. Publicado em: 2020-09
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4. Solid Phase Extraction Using SiO2/Al2O3/TiO2 Ternary Oxide for Cu2+ Preconcentration
The present work aims at studying the preconcentration of Cu2+ ions by solid phase extraction using SiO2/Al2O3/TiO2 ternary oxide as adsorbent material. This methodology consists of the affinity of the analyte for the adsorbent material and its subsequent elution with the least amount of solvent. Subsequently, the aqueous phase containing the extracted analy
J. Braz. Chem. Soc.. Publicado em: 04/07/2019
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5. Adsorptive Stripping Voltammetric Determination of Oxolinic Acid in Water Sample
One new methodology for analysis of the antimicrobial oxolinic acid (OXA) based on adsorptive stripping voltammetry (AdSV) in carbon paste electrode (CPE) was developed and applied in untreated pond water sample. Cyclic voltammetry (CV) indicated that an irreversible anodic process occurs in KOH solution as supporting electrolyte. Quantification of the antim
J. Braz. Chem. Soc.. Publicado em: 2018-07
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6. Development of a Novel and Simple Electroanalytical Procedure for the Determination of Copper in Biofuel Employing a Sensor Based on Vulcan Functionalized with Carbazone
A novel and simple electroanalytical method for the determination of Cu2+ in biodiesel samples by stripping voltammetric analysis was developed. The method employs a carbon paste electrode (CPE) modified with Vulcan carbon, previouly functionalized with carbazone (CBZ). The CPE/Vulcan-CBZ sensor promoted a significant increase in the analytical signal obtain
J. Braz. Chem. Soc.. Publicado em: 2018-04
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7. ANÁLISE POR INJEÇÃO SEQUENCIAL COM DETECÇÃO POR VOLTAMETRIA DE ONDA QUADRADA PARA DETERMINAÇÃO DE As(III) EM AMOSTRAS DE ÁGUAS USANDO ELETRODO DE OURO
A sequential injection method with square wave anodic stripping voltammetry (SI-SWASV) using screen printed and crystalline gold electrode was developed for determination of As(III). The carrier solution used for electrode conditioning and stripping medium was composed of 0.050 mol L-1 HCl, whereas the supporting electrode for samples (deposition medium) was
Quím. Nova. Publicado em: 2018-01
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8. DESEMPENHO DO ELETRODO DE FILME DE PALÁDIO NA DETERMINAÇÃO DE TÁLIO E CHUMBO EM AMOSTRAS DE ÁGUAS NATURAIS POR VOLTAMETRIA DE REDISSOLUÇÃO ANÓDICA COM PULSO DIFERENCIAL
The use of a palladium film electrode (PdFE) as an alternative electrode for the determination of thallium (Tl+) and lead (Pb2+) in water samples by anodic stripping voltammetry is proposed. Preliminary studies of the influence of the substrate were performed on the electrochemical behavior of PdFE prepared ex situ. Using a silver solid amalgam electrode as
Quím. Nova. Publicado em: 2017-09
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9. UV-Assisted Digestion of Petrochemical Industry Effluents Prior to the Determination of Zn, Cd, Pb and Cu by Differential Pulse Anodic Stripping Voltammetry
A petrochemical effluent is usually a matrix of very high complexity and composition variability, requiring robust and suitable methods for routine analysis. In this paper, the feasibility of applying a voltammetric technique for the determination of metals species in the petrochemical industry effluent was demonstrated after UV-assisted digestion procedure.
J. Braz. Chem. Soc.. Publicado em: 2016-09
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10. A Kinetic, Equilibrium, and Thermodynamic Study on the Biosorption of Tl+ and Cd2+ by Eichhornia crassipes Roots Using Carbon Paste Electrode
In this work, Eichhornia crassipes roots were used as a modifier for carbon paste electrode in a biosorption study of thallium (Tl+) and cadmium (Cd2+) ions. The ions were accumulated on modified electrode surfaces at open circuit potential and analyzed by square wave anodic stripping voltammetry. Before the biosorption study, the effect of ratio of biomass
J. Braz. Chem. Soc.. Publicado em: 2016-09
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11. Polytetrafluorethylene Membrane-Based Liquid Three-Phase Micro Extraction Combined with
in situ Differential Pulse Anodic Stripping Voltammetry for the Determination of Cadmium Ions Using Au-Nanoparticles Sol-Gel Modified Pt-WireIn this study, one particular application of in situ pulse anodic stripping voltammetry and polytetrafluoroethylene membrane-based liquid three-phase micro extraction is presented for the micro extraction and quantification of cadmium(II) ions in trace levels. The main factors influencing on preconcentration and micro extraction of cadmium ions
J. Braz. Chem. Soc.. Publicado em: 2015-07
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12. Determination of anti-cancer drug emodin using a silica-gel-modified carbon paste electrode
In this paper, a silica-gel-modified carbon paste electrode (Si-gel/CPE) was used to determine the anti-cancer drug emodin by anodic stripping differential pulse voltammetry (ASDPV). The effects of the silica-gel content, the pH of the supporting electrolyte, and the scan rate on the oxidation current of emodin were investigated. The oxidation currents of em
Quím. Nova. Publicado em: 2014