Aliphatic Compounds
Mostrando 1-12 de 156 artigos, teses e dissertações.
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1. Spectroscopic techniques combined with chemometrics to study organic matter in tropical soils with different degrees of pedogenetic evolution
Understanding of the organomineral interactions in soil can elucidate the humic substances (HS) formation and the humification process. This study aimed to structurally characterize the humic acids (HA) formed in tropical soils with different pedogenesis degrees. The HA fraction was extracted from soil samples in the superficial horizons of an Inceptisol and
Química Nova. Publicado em: 2022
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2. Ketones as Electrophile in Nitroaldol Reaction: Synthesis of β,β-Disubstituted- 1,3-dinitroalkanes and Allylic Nitro Compounds
Abstract β,β-Disubstituted-1,3-dinitro compounds were obtained exclusively with an overall yield of 83% through a domino nitroaldol/elimination/1,4-addition process, when excess nitromethane was added to cyclohexanone or butanone using DBU (1,8-diazabicyclo[5.4.0]undec-7-ene), as a basic catalyst. On the other hand, β-nitroalcohols could be obtained in 30
J. Braz. Chem. Soc.. Publicado em: 2021-08
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3. The influence of cultivar and enzyme treatment on the aroma complex of apple juice
Abstract This paper aims to determine the influence of a cultivar (Golden delicious and Granny Smith) and enzyme treatments (hot and cold) on the aroma complex of clear apple juice. While the composition of aromatic components of the juice was determined by Gas Chromatography Mass Spectrometry (GC/MS) technique, a panel of 24 semi trained evaluators carried
Food Sci. Technol. Publicado em: 2021-06
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4. The effects of adding garlic (Allium sativum L.) on the volatile composition and quality properties of yogurt
Abstract In this study, the effects of adding garlic (Allium sativum L.) of different origins on the volatile composition and quality properties of yogurt were investigated on day 1, 7 and 14 of storage. The addition of garlic did not cause a decrease in the total specific microorganism count (>107) in yogurt samples, and it led to a significant decrease in
Food Sci. Technol. Publicado em: 2020-12
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5. Structural Assessment of Chemical Constituent of Sidaguri (Sida rhombifolia Linn) and Its Ability to Inhibit Cyclooxygenase
Abstract Objective: To elicit the structure of isolated compounds from roots of sidaguri (Sida rhombifolia Linn). Material and Methods: Several organic standard protocols were involved, including extraction, fractionation, and phytochemical testing. Further spectroscopy methods, FTIR and 1HNMR, were used to determine the predicted structure of molecules, w
Pesqui. Bras. Odontopediatria Clín. Integr.. Publicado em: 31/10/2019
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6. Synthesis and Cytotoxicity Evaluation of a Series of 3-Alkenyl-2-Hydroxy-1,4-Naphthoquinones Obtained by an Efficient Knoevenagel Condensation
A modified and efficient Knoevenagel condensation procedure was developed to synthesize the title compounds using β-alanine and acetic acid as catalysts, showing good to excellent yields. We used lawsone with suitable aliphatic aldehydes including isobutyraldehyde, 3-methyl-butyraldehyde, 2-ethylbutyraldehyde, phenylacetaldehyde, 2-phenyl-propionaldehyde, a
J. Braz. Chem. Soc.. Publicado em: 2019-01
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7. ESTUDO MECANÍSTICO DAS REAÇÕES FENTON E CUPRO-FENTON POR ANÁLISE VOLTAMÉTRICA IN SITU
Although the classical Fenton process exhibits a high initial rate of the organic compounds degradation, this process is not complete due to the formation of refractory compounds which resist the attack of the hydroxyl radicals. In the presence of Cu(II), the degradation is slower, but results in a greater reduction of TOC (total organic carbon) measurements
Quím. Nova. Publicado em: 2017-08
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8. In vitro antifungal activity of organic compounds derived from amino alcohols against onychomycosis
Abstract Onychomycosis is a fungal infection of the nail caused by high densities of filamentous fungi and yeasts. Treatment for this illness is long-term, and recurrences are frequently detected. This study evaluated in vitro antifungal activities of 12 organic compounds derived from amino alcohols against standard fungal strains, such as Trichophyton rubru
Braz. J. Microbiol.. Publicado em: 2017-07
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9. Aggregate Stability in Soil with Humic and Histic Horizons in a Toposequence under Araucaria Forest
ABSTRACT Aggregate stability is one of the most important factors in soil conservation and maintenance of soil environmental functions. The objective of this study was to investigate the aggregate stability mechanisms related to chemical composition of organic matter in soil profiles with humic and histic horizons in a toposequence under Araucaria moist fore
Rev. Bras. Ciênc. Solo. Publicado em: 2017
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10. Quantification of Synthetic Amino-Nitroquinoxaline Dyes: An Approach Using Image Analysis
This paper describes the use of digital imaging acquired from a conventional desktop scanner for characterization of newly synthesized amino-nitroquinoxaline dyes. The synthetic protocol was based on reactions of building block 2,3-dichloro-6,7-dinitroquinoxaline with aliphatic amines and experiments based on image analysis were carried out with compounds in
J. Braz. Chem. Soc.. Publicado em: 2016-06
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11. PHASE EQUILIBRIA FOR BINARY SYSTEMS CONTAINING IONIC LIQUID WITH WATER OR HYDROCARBONS
Abstract In this work, the mutual solubilities of sets of ionic liquids ([CnMIM] [TF2N] (n = 4, 8, 12), [C4PY] [TF2N], [C8MIM] [OTF]) and organic compounds (heptane, o-xylene, toluene, or water) are investigated. The experimental data measured for these systems were used to adjust the binary interaction parameters between their components for the Non-Random
Braz. J. Chem. Eng.. Publicado em: 2015-12
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12. Interlaboratory Comparison of Quantifying Hydrocarbons and Trace Elements in Sediment Samples from a Tropical Estuary
The Marine and Environmental Studies Laboratory at PUC-Rio, in partnership with the PETROBRAS R&D Center (Brazil), conducted an interlaboratory comparison of aliphatic and aromatic hydrocarbons and trace element determinations. The goal of this study was to produce a homogeneous and stable material and obtain consensus concentration values for its use as a r
J. Braz. Chem. Soc.. Publicado em: 2015-02