Vapor Liquid Equilibrium
Mostrando 25-36 de 82 artigos, teses e dissertações.
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25. Equilibrio liquido-liquido em sistemas contendo hidrocarbonetos aromaticos + hidrocarbonetos alifaticos + liquidos ionicos / Liquid-liquid equilibrium of systems aromatic + aliphatic + ionic liquids
A nafta reformada é um produto do refino do petróleo que contém compostos aromáticos e alifáticos de grande interesse industrial. Para separar estes componentes utiliza-se, em sua grande maioria, o processo de extração líquido-líquido. Os solventes mais utilizados, até o momento, são extratantes com alta pressão de vapor, que apresentam emissões
Publicado em: 2009
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26. Modelagem termodinamica de equilibrio liquido-liquido em sistemas envolvendo liquidos ionicos com modelos de composição local/contribuição de grupo e estruturas moleculares determinadas via quimica quantica / Thermodynamic modeling of liquid-liquid equilibrium in systems involving ionic liquids with models of local composition/group contribution and molecular structures determined by quantum chemistry
Líquidos iônicos são sais orgânicos de alto peso molecular que são líquidos a temperatura ambiente. Estas substâncias têm recebido considerável atenção como solventes ecologicamente corretos, já que não possuem pressão de vapor mensurável e, portanto, não apresentam emissões tóxicas ou poluentes como os solventes orgânicos tradicionais. Ne
Publicado em: 2009
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27. Otimização das colunas de absorção da recuperação de acetona na produção de Filter Tow por meio de estudos fenomenológicos e análise estatística. / Optimization of the absorption columns in the acetone recovery at the Filter Tow production by phenomenological studies and statistical analysis.
Absorption is the key step of the acetone recovery at Filter Tow production, for reducing the acetone emission and improving economics. For this reason it is the subject of this study, including the revision of phenomenological concepts, considering the choice of the best vapor liquid equilibrium model, passing by the improvement of coherent mass balances an
Publicado em: 2009
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28. Study of physical deacidification of the vegetable oils using model systems / Estudo da desacidificação por via fisica de oleos vegetais utilizando sistemas-modelos
The steam deacidification step must be designed in order to take into account the high difference in the volatility of undesirable compounds and the neutral oil under high temperatures and vacuum, without causing damage to nutraceutical compounds, excessive production of trans fatty acids and neutral oil loss. To improve the process conditions of this import
Publicado em: 2009
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29. Filtro a base de nanofibras de carbono para sequestro de enxofre em efluentes gasosos ricos em H2S / Carbon nanofibers based filter to sulfur removal from efluents rich in H2S.
Over the last few decades, sulfur recovery from the H2S-containing acid gases have become more and more important due to the ever increasing standards of efficiency required by environmental protection measures. The general trend is to selectively transform H_2S into elemental sulfur which is a valuable product, by the modified Claus process. However, due to
Publicado em: 2009
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30. High-pressure cloud point data for the system glycerol + olive oil + n-butane + AOT
This work reports high-pressure cloud point data for the quaternary system glycerol + olive oil + n-butane + AOT surfactant. The static synthetic method, using a variable-volume view cell, was employed for obtaining the experimental data at pressures up to 27 MPa. The effects of glycerol/olive oil concentration and surfactant addition on the pressure transit
Brazilian Journal of Chemical Engineering. Publicado em: 2008-09
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31. Parameter estimation for VLE calculation by global minimization: the genetic algorithm
Vapor-liquid equilibrium calculations require global minimization of deviations in pressure and gas phase compositions. In this work, two versions of a stochastic global optimization technique, the genetic algorithm, the freeware MyGA program, and the modified mMyGA program, are evaluated and compared for vapor-liquid equilibrium problems. Reliable experimen
Brazilian Journal of Chemical Engineering. Publicado em: 2008-06
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32. Simulation of styrene polymerization reactors: kinetic and thermodynamic modeling
A mathematical model for the free radical polymerization of styrene is developed to predict the steady-state and dynamic behavior of a continuous process. Special emphasis is given for the kinetic and thermodynamic models, where the most sensitive parameters were estimated using data from an industrial plant. The thermodynamic model is based on a cubic equat
Brazilian Journal of Chemical Engineering. Publicado em: 2008-06
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33. Prediciton of high-pressure vapor liquid equilibrium of six binary systems, carbon dioxide with six esters, using an artificial neural network model
Artificial neural networks are applied to high-pressure vapor liquid equilibrium (VLE) related literature data to develop and validate a model capable of predicting VLE of six CO2-ester binaries (CO2-ethyl caprate, CO2-ethyl caproate, CO2-ethyl caprylate, CO2-diethyl carbonate, CO2-ethyl butyrate and CO2-isopropyl acetate). A feed forward, back propagation n
Brazilian Journal of Chemical Engineering. Publicado em: 2008-03
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34. Separation of ethanol and water by extractive distillation with salt and solvent as entrainer: process simulation
The aim of this work is to simulate and analyze an extractive distillation process for azeotropic ethanol dehydration with ethylene glycol and calcium chloride mixture as entrainer. The work was developed with Aspen Plus® simulator version 11.1. Calculation of the activity coefficients employed to describe vapor liquid equilibrium of ethanol - water - ethyl
Brazilian Journal of Chemical Engineering. Publicado em: 2008-03
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35. Predição do equilibrio liquido-vapor atraves de redes neurais artificiais / Prediction of vapor-liquid equilibrium using artificial neural networks
: Esse trabalho tem como objetivo o estudo da viabilidade de se utilizar se redes neurais artificiais (RNAs) para a predição de equilíbrio líquido-vapor (EL V), utilizando a abordagem do método de contribuição de grupos, método UNIF AC. Foram feitas duas propostas de trabalho, uma substituindo o método UNIF AC para o cálculo do coeficiente de ativi
Publicado em: 2008
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36. A subdivision algorithm for phase equilibrium calculations at high pressures
Phase equilibrium calculations at high pressures have been a continuous challenge for scientists and engineers. Traditionally, this task has been performed by solving a system of nonlinear algebraic equations originating from isofugacity equations. The reliability and accuracy of the solutions are strongly dependent on the initial guess, especially due to th
Brazilian Journal of Chemical Engineering. Publicado em: 2007-12