Preparation and Characterization of Mullite-Alumina Structures Formed "In Situ" from Calcined Alumina and Different Grades of Synthetic Amorphous Silica

The in situ reaction between alumina and silica to obtain mullite (Al6Si4O13) can be significantly affected by using synthetic amorphous silica (SAS) sources instead of crystalline ones (quartz and cristobalite). For instance, SASs promote early mullite formation (below 1300°C) and greater densification during sintering. This paper reports the "in situ" formation of mullite-alumina structures from fine calcined alumina (α-Al2O3) and four grades of SAS of different particles' morphology, specific surface area and internal porosity. After sintering assisted by dilatometry (up to 1500°C), the ...