Local piezo-response for lead-free Ba0.9Ca0.1Ti0.9Zr0.1O3 electro-ceramic by switching spectroscopy

The purpose of this work is to determine the effective piezoelectric coefficient (d33) and the macro ferroelectric hysteresis behavior for the Ba0.9Ca0.1Ti0.9Zr0.1O3 (BCZT). The sample was prepared by the modified Pechini method and it was sintered at 1250 ºC for 5 h. The refinements of X-ray diffraction (XRD) patterns obtained by the Rietveld method suggest a slight degree of tetragonality (c/a = 1.0025) in the perovskite structure. High counting statistics was performed in the two-dimensional grazing incidence 2D-GIXRD characterization by using synchrotron radiation. These results and the R...