2020-07

COVID-19: Um Novo Desafio para a Cardiopatia na Gravidez

This work presents the results obtained for the gas chromatography-mass spectrometry (GC-MS) monitoring of the liquid-phase hydrodeoxygenation (HDO) reaction of furfural (FFR) to 2-methylfuran (MF) over a bifunctional Ru/RuOx/C catalyst in the presence of a direct source of H2. Hydrogenation and hydrogenolysis reactions of FFR and of the intermediate furfuryl alcohol (FA), respectively, were independently studied to provide insights on the HDO mechanism. The mass spectra monitoring of the kinetic isotope effect indicated the HDO reaction occurs through a two-step mechanism comprising of an ini...

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