2003-09

Catalysis with competitive reactions: static and dynamical critical behavior

We studied in this work a competitive reaction model between monomers on a catalyst. The catalyst is represented by hypercubic lattices in d = 1, 2 and 3 dimensions. The model is described by the following reactions: A + A -> A2 and A + B -> AB, where A and B are two monomers that arrive at the surface with probabilities yA and yB, respectively. The model is studied in the adsorption controlled limit where the reaction rate is infinitely larger than the adsorption rate. We employ site and pair mean-field approximations as well as static and dynamical Monte Carlo simulations. We show that, for ...

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