12/08/2019

Addition of CeO2 Nanorods in PtSn-Based Electrocatalysts for Ethanol Electrochemical Oxidation in Acid Medium

This work describes the preparation of Pt/C, PtxSny/C and PtxSny(CeO2 nanorods/C) nanoparticle catalysts synthesized by the chemical reduction method via sodium borohydride for the ethanol oxidation reaction. Using X-ray diffractogram analysis, it was verified that no alloy formation occurred between platinum (Pt) and tin (Sn). The distribution of the nanoparticles in the support occurs in a more agglomerated form for the materials containing Sn and CeO2 nanorods (NR). The electrocatalyst Pt3Sn1_20%NRCeO2/C was highlighted in CO-stripping experiments because it showed the lowest onset potentia...

Texto completo