Stripping
Mostrando 25-36 de 273 artigos, teses e dissertações.
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25. Adsorptive Stripping Voltammetric Determination of Oxolinic Acid in Water Sample
One new methodology for analysis of the antimicrobial oxolinic acid (OXA) based on adsorptive stripping voltammetry (AdSV) in carbon paste electrode (CPE) was developed and applied in untreated pond water sample. Cyclic voltammetry (CV) indicated that an irreversible anodic process occurs in KOH solution as supporting electrolyte. Quantification of the antim
J. Braz. Chem. Soc.. Publicado em: 2018-07
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26. ESPECIAÇÃO DINÂMICA DE METAIS TRAÇO EM AMBIENTE AQUÁTICO USANDO CRONOPOTENCIOMETRIA DE REDISSOLUÇÃO ANÓDICA
The contamination of natural environments by trace metals has several adverse effects on human health, which is mainly due to the high toxicity, persistence and reactivity of these species in the environment. To understand the bioavailability of trace metals, it is necessary to know the speciation in equilibrium and the dynamic behavior of the system. In thi
Quím. Nova. Publicado em: 2018-07
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27. Development of a Novel and Simple Electroanalytical Procedure for the Determination of Copper in Biofuel Employing a Sensor Based on Vulcan Functionalized with Carbazone
A novel and simple electroanalytical method for the determination of Cu2+ in biodiesel samples by stripping voltammetric analysis was developed. The method employs a carbon paste electrode (CPE) modified with Vulcan carbon, previouly functionalized with carbazone (CBZ). The CPE/Vulcan-CBZ sensor promoted a significant increase in the analytical signal obtain
J. Braz. Chem. Soc.. Publicado em: 2018-04
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28. ANÁLISE POR INJEÇÃO SEQUENCIAL COM DETECÇÃO POR VOLTAMETRIA DE ONDA QUADRADA PARA DETERMINAÇÃO DE As(III) EM AMOSTRAS DE ÁGUAS USANDO ELETRODO DE OURO
A sequential injection method with square wave anodic stripping voltammetry (SI-SWASV) using screen printed and crystalline gold electrode was developed for determination of As(III). The carrier solution used for electrode conditioning and stripping medium was composed of 0.050 mol L-1 HCl, whereas the supporting electrode for samples (deposition medium) was
Quím. Nova. Publicado em: 2018-01
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29. DESEMPENHO DO ELETRODO DE FILME DE PALÁDIO NA DETERMINAÇÃO DE TÁLIO E CHUMBO EM AMOSTRAS DE ÁGUAS NATURAIS POR VOLTAMETRIA DE REDISSOLUÇÃO ANÓDICA COM PULSO DIFERENCIAL
The use of a palladium film electrode (PdFE) as an alternative electrode for the determination of thallium (Tl+) and lead (Pb2+) in water samples by anodic stripping voltammetry is proposed. Preliminary studies of the influence of the substrate were performed on the electrochemical behavior of PdFE prepared ex situ. Using a silver solid amalgam electrode as
Quím. Nova. Publicado em: 2017-09
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30. SUBSTITUIÇÃO DO NITROBENZENO PELO ÓLEO DE SOJA COMO UMA PROPOSTA PARA O ENSINO DO MÉTODO DE VOLHARD EM ANÁLISE QUANTITATIVA
Volhard method is extensively employed in the teaching laboratories of classical quantitative analysis to chloride determination and is based on the reaction of Ag+ with Cl- and Ag+ residual titration with SCN-. Its drawback is that SCN- reacts with the AgCl(s) initially formed. Nitrobenzene is used to avoid this stripping, but it is toxic to the environment
Quím. Nova. Publicado em: 2017-09
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31. Ethylene glycol oxidation on ternary PtRhNi/C electrocatalyst with different metal compositions
ABSTRACT Direct Alcohol Fuel Cells (DAFC’s) are an alternative to fuel cell systems and when is used alkaline medium this has an increase performance. The alkaline direct alcohol fuel cells (ADAFC's) have some advantages such as low-emission, high energy efficiency, improved oxidation kinetics, low crossover and in addition there is a broad range of materi
Matéria (Rio J.). Publicado em: 20/07/2017
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32. STRIPPING AND DISSIPATION TECHNIQUES FOR THE REMOVAL OF DISSOLVED GASES FROM ANAEROBIC EFFLUENTS
Abstract UASB reactors are a common technology for wastewater treatment. However, certain disadvantages must be considered. One of the disadvantages relates to the presence of dissolved gases, hydrogen sulfide and methane, in the effluent, which can potentially be released into the atmosphere. This can cause malodours and contribute to the greenhouse effect.
Braz. J. Chem. Eng.. Publicado em: 2016-12
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33. CONCEPTUAL DESIGN OF NON-IDEAL MIXTURE SEPARATION WITH LIGHT ENTRAINERS
Abstract A method is proposed to study the separation of minimum-, maximum-boiling azeotropic, and low volatility mixtures with a light entrainer, to investigate feasible regions of the key operating parameters reboil ratio (S) and entrainer - feed flowrate ratio (FE/F) for continuous processes. The thermodynamic topological predictions are carried out for 1
Braz. J. Chem. Eng.. Publicado em: 2016-12
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34. UV-Assisted Digestion of Petrochemical Industry Effluents Prior to the Determination of Zn, Cd, Pb and Cu by Differential Pulse Anodic Stripping Voltammetry
A petrochemical effluent is usually a matrix of very high complexity and composition variability, requiring robust and suitable methods for routine analysis. In this paper, the feasibility of applying a voltammetric technique for the determination of metals species in the petrochemical industry effluent was demonstrated after UV-assisted digestion procedure.
J. Braz. Chem. Soc.. Publicado em: 2016-09
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35. A Kinetic, Equilibrium, and Thermodynamic Study on the Biosorption of Tl+ and Cd2+ by Eichhornia crassipes Roots Using Carbon Paste Electrode
In this work, Eichhornia crassipes roots were used as a modifier for carbon paste electrode in a biosorption study of thallium (Tl+) and cadmium (Cd2+) ions. The ions were accumulated on modified electrode surfaces at open circuit potential and analyzed by square wave anodic stripping voltammetry. Before the biosorption study, the effect of ratio of biomass
J. Braz. Chem. Soc.. Publicado em: 2016-09
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36. Evaluation of skin absorption of drugs from topical and transdermal formulations
ABSTRACT The skin barrier function has been attributed to the stratum corneum and represents a major challenge in clinical practice pertaining to cutaneous administration of drugs. Despite this, a large number of bioactive compounds have been successfully administered via cutaneous administration because of advances in the design of topical and transdermal f
Braz. J. Pharm. Sci.. Publicado em: 2016-09