Solid Electrolytes
Mostrando 1-12 de 34 artigos, teses e dissertações.
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1. Influence of Yttria-Stabilized Zirconia on Microstructure and Electrical Properties of Doped Lanthanum Gallate
Lanthanum gallate with partial substitutions for strontium and magnesium shows higher ionic conductivity than traditional ionic conductors such as yttria-stabilized zirconia (8YSZ), and has been considered for application as solid electrolyte and electrode in Solid Oxide Fuel Cells operating at intermediate temperatures (500-700ºC). Parallel to the developm
Mat. Res.. Publicado em: 01/08/2019
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2. Eco-Friendly Luminescent Hybrid Materials Based on EuIII and LiI Co-Doped Chitosan
Biopolymer-based materials have been of particular interest as alternatives to synthetic polymers due to their low toxicity, biodegradability and biocompatibility. Among them, chitosan is one of the most studied ones and has recently been investigated for the application as solid state polymer electrolytes. Furthermore, it can serve as a host for luminescent
J. Braz. Chem. Soc.. Publicado em: 2015-12
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3. Compatibility analyses of BICUVOX.10 as a cathode in yttria-stabilized zirconia electrolytes for usage in solid oxide fuel cells
Copper-substituted bismuth vanadate has been considered a promising material for composite cathodes in SOFC. However, high reactivity of BICUVOX.10 towards the electrolytes still has been its greatest shortcoming. This paper describes reactions between BICUVOX.10 and yttria-stabilized zirconia (YSZ) electrolytes. Secondary phases formed were evaluated by X-r
Mat. Res.. Publicado em: 30/09/2014
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4. Aplicação do método da minimização da energia de Gibbs no cálculo de equilíbrio químico e de fases em sistemas eletrolíticos / Application method of the Gibbs energy minimization to calculation of phase and chemical equilibrium in electrolyte systems
In several industrial applications are used mixtures containing different solutes, often these solutes are non-volatile, such as electrolytes. The phase and chemical equilibrium in these processes occur in the various unit operations. The stages of production, as well as the separation and purification steps are critical to product quality. Thus, the calcula
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 14/12/2011
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5. Desenvolvimento de camadas finas de eletrólitos de zircênia depositados por spin coating para células a combustível de óxido sólido / Development of thin layers of zirconia electrolytes deposited by spin coating for solid oxide fuel cells
Este trabalho de mestrado teve como objetivo principal a fabricação de células a combustível de óxido sólido (SOFC) suportadas no anodo com camada de eletrólito depositada por spin coating. As principais etapas envolveram: i) a fabricação e caracterização dos substratos do anodo, o compósito níquel / zircônia estabilizada com ítria (Ni / YSZ);
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 18/08/2010
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6. Obtenção de cerâmicas de céria-samária-gadolínia para aplicação como eletrólito em células a combustível de óxido sólido (SOFC) / Obtaining of ceria - samaria - gadolinia ceramics for application as solid oxide fuel cell (SOFC) electrolyte
O óxido de cério (CeO2), quando dopado com óxidos de terras raras, tem sua condutividade iônica aumentada, possibilitando seu uso como eletrólito de Células a Combustível de Óxido Sólido de Temperatura Intermediária (IT-SOFC), que são operadas entre 500 e 700°C. Os aditivos ou dopantes mais eficientes para o aumento da condutividade iônica são
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 23/02/2010
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7. Properties and applications of perovskite proton conductors
A brief overview is given of the main types and principles of solid-state proton conductors with perovskite structure. Their properties are summarized in terms of the defect chemistry, proton transport and chemical stability. A good understanding of these subjects allows the manufacturing of compounds with the desired electrical properties, for application i
Materials Research. Publicado em: 2010-09
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8. Solid polymer electrolytes based in sodium alginate. / Eletrólitos sólidos poliméricos a base de alginato de sódio
The aim of this study was the preparation and characterization of sodium alginate membranes plasticized with glycerol. The samples were obtained with different concentration of acetic acid or lithium perchlorate in order to use them as solid polymer electrolytes (SPE) in electrochemical devices, such as sensors and batteries. The films were characterized by
Publicado em: 2010
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9. Preparation and characterization solid polymer electrolytes based of commercial gelatin for application in solar cells. / Preparação e caracterização de eletrólitos sólidos poliméricos à base de gelatina comercial para aplicação em células solares.
O presente trabalho visou estudar e caracterizar eletrólitos sólidos poliméricos (ESP) à base de gelatina plastificada com glicerol, entrecruzada com formaldeído e contendo LiI/I2 para a aplicação em células solares. O objetivo foi obter os eletrólitos à base de gelatina comercial (Dr. Oetker) de origem animal, uma vez que a mistura de aminoácidos
Publicado em: 2010
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10. Preparação de vidros boratos dos sistemas 50B2O315PbO(35-x)Li2OxNa2O e 50B2O315PbO(35-x)LiFxNaF e determinação do efeito dos alcalinos mistos / Preparation of borate glasses from 50B2O315PbO(35-x)Li2OxNa2O and 50B2O315PbO(35-x)LiFxNaF systems and the evaluation of the mixed alkali effect
Different alkali glasses have been developed because exhibit a high ionic conductivity and can be used as solid electrolytes in the fabrication of devices such as batteries and chemical sensors. However, a deleterious effect emerges when two alkali ions are present in the same glassy matrix. The phenomenon, named of the mixed alkali effect (MAE), causes a no
Publicado em: 2010
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11. BIOCHEMICAL AND PHYSIOLOGICAL RESPONSES OF Cucumis sativus AND Avena sativa TO EXCESS ALUMINUM STRESS. / RESPOSTAS BIOQUÍMICAS E FISIOLÓGICAS DE Cucumis sativus E Avena sativa AO ESTRESSE CAUSADO POR ALUMÍNIO
Aluminum (Al) is the most abundant metal in the Earth s crust, affecting growth and development of plants. The aim of this study was to investigate the effects of Al on seedlings of cucumber (Cucumis sativus L.) and oat (Avena sativa L) through the analysis of biochemical and physiological parameters. Three different genotypes of oat seedlings were studied,
Publicado em: 2010
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12. Condutividade elétrica da solução sólida céria-zircônia dopada com ítrio e gadolínio / Electrical conductivity of solid solution ceria-zirconia doped yttria and gadolinium
Rare earth doped ceria has a great potential to be used as electrolyte in temperatures around 800 C in fuel cells due to its higher electrical conductivity than YSZ. However, the reduction of Ce+4 to Ce+3 in low oxygen partial pressure has introduced limitations for using doped ceria electrolyte due to electronic conduction. Among the several ceria solid sol
Publicado em: 2009