Ru
Mostrando 13-24 de 1229 artigos, teses e dissertações.
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13. Candida tropicalis sp. Nov., a novel, zinc-enriched yeast species found in China
Abstract Zinc is one of the most important trace elements and deficiency can lead to significant clinical complications. Microbial transformation is one of the most important methods used to supplement organic zinc and there may be some naturally occurring microorganisms that have both higher zinc tolerances and transformation capabilities. In this study, mi
Food Sci. Technol. Publicado em: 2021-03
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14. An Electrochemiluminescence Biosensor for the Determination of Mercury Ion via Dual-Amplification Strategy
A novel dual-signal amplificatory electrochemiluminescence (ECL) deoxyribonucleic acid (DNA) biosensor was designed for the determination of Hg2+. One amplification unit was gold nanoparticles (AuNPs) modified on a glassy carbon electrode, and the other was single-stranded DNA (ssDNA) (with amino at the 3’ terminal and thiol at the 5’ terminal) labeled w
J. Braz. Chem. Soc.. Publicado em: 2020-12
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15. Sunlight-Driven Dehydrogenative Oxidation Photocatalysis by a Mononuclear Complex Acting as both Chromophore and Catalyst
Under simulated solar irradiation in the visible spectral region, the catalytically active RuIV-oxo species [Ru(O)(bpy)(tppz)]2+ (tppz = tetrapyridylpyrazine, a strongly π-accepting tridentate N, N, N-ligand) is produced directly from a single metal-to-ligand charge-transfer (MLCT) photoexcitation of the resting RuII-aquo complex [Ru(H2O)(bpy)(tppz)]2+ in a
J. Braz. Chem. Soc.. Publicado em: 2020-11
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16. Self-Assembled Nanoparticles of Diruthenium(II,III)-Ibuprofen Anticancer Metallodrug
The diruthenium(II,III)-ibuprofen (RuIbp) metallodrug shows anticancer activity in vitro and in vivo. The encapsulation into lipid nanoparticles enhanced the efficacy in glioblastoma, breast and prostate cancer cells. Here we report data for RuIbp hydrophobicity, solubility in alcohol/water, and behavior in 1-5% ethanol/water and ethanol/cell culture medium.
J. Braz. Chem. Soc.. Publicado em: 2020-11
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17. NO Photorelease from a Ruthenium Complex Assisted by Formation of a Supramolecular Dimer
This work presents the NO release from compound [Ru(biq)2(H2O)(NO)](PF6)3 (biq = 2,2’-biquinoline) with visible light irradiation (λirrad = 660 nm), assisted by the low-absorbing photosensitizer [Ru(biq)2Cl2]. The structure of both compounds were characterized by means of ESI-MS (electrospray ionization mass spectrometry). The NO+ stretching, ν(NO) = 199
J. Braz. Chem. Soc.. Publicado em: 2020-11
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18. Heterostructured Langmuir-Blodgett Films of Ruthenium Bipyridine with 1,3,4-Naphthooxadiazole-Derived Amphiphile Complex as a Charge Storage Electrode
The molecular control in Langmuir-Blodgett (LB) films may be exploited in charge storage electrodes provided a suitable choice of molecular architecture and components is made. In this paper, we employed a naphtyl-1,3,4-oxadiazole amphiphile (NFT1) and its complex [Ru(bpy)2NFT1]PF6 (RuNFT1) (bpy = 2,2’-bipyridine) in heterostructured LB films in a proof-of
J. Braz. Chem. Soc.. Publicado em: 2020-11
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19. “Half-Sandwich”/RuII Anticancer Complexes Containing Triphenylphosphine and p-Substituted Benzoic Acids
Mononuclear and binuclear RuII/arene/triphenylphosphine complexes with p-substituted benzoic acid derivatives were prepared and characterized. These monocationic complexes of type [Ru(η6-p-cymene)(PPh3)L] (L = benzoic acid (1), p-hydroxybenzoic acid (2), p-nitrobenzoic acid (3) and terephthalic acid (4)) were characterized using various techniques, such as
J. Braz. Chem. Soc.. Publicado em: 2020-11
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20. Supramolecular Approach in Energy Conversion Devices
This review summarizes investigations carried out at the Laboratory of Photochemistry and Energy Conversion (LFCE) in the University of São Paulo dealing with design and characterization of ruthenium(II), rhenium(I) and iridium(III) polypyridine complexes with desired photochemical and photophysical properties in light of the development of optoelectronics
J. Braz. Chem. Soc.. Publicado em: 2020-11
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21. Effect of Push-Pull Ruthenium Complex Adsorption Conformation on the Performance of Dye Sensitized Solar Cells
A new series of tris-(bipyridyl)ruthenium-like complexes based on the 4-tripheylamine-2,2’:6’,2’’-terpyridine (TPA) push-pull ligand was prepared by incorporation of 4-carboxypyridine (cpy), 4,4’-dicarboxi-2,2’-bipyridine (dcbpy) and 4-carboxyterpyridine ligands (ctpy) ligands, in order to adsorb them on TiO2 in different anchoring conformations.
J. Braz. Chem. Soc.. Publicado em: 2020-11
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22. Synthesis, Characterization, Spectroelectrochemical, Photophysical and HSA-Binding Properties of Novel and Versatile meso-Tetra(4-pyridylvinylphenyl)porphyrins Coordinated to Ruthenium(II)-Polypyridyl Derivatives
The free-base meso-tetra(4-pyridylvinylphenyl)porphyrin (1a) and its zinc(II) complex were synthesized and then functionalized with [Ru(bpy)2Cl]+ units (2a and 2b) via conventional methods and evaluated in terms of photophysical, electrochemical and biological aspects. All porphyrins present moderate singlet oxygen production and fluorescence quantum yield,
J. Braz. Chem. Soc.. Publicado em: 2020-11
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23. New Heteroleptic RuII/Diphosphine Complexes with Cytotoxicity against Human Breast and Murine Ascitic Sarcoma 180 Tumor Cells
The preparation, characterization, theoretical calculations and biological application of four RuII complexes with 2-picolinate (pic), 2,2’-bipyridine (bipy) and P-P as ligands [P-P = 1,1-bis(diphenylphosphino)methane (dppm-1), 1,2-bis(diphenylphosphino)ethane (dppe-2), 1,3-bis(diphenylphosphino)propane (dppp-3) or 1,1’-bis(diphenylphosphino)ferrocene (d
J. Braz. Chem. Soc.. Publicado em: 2020-07
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24. COVID-19: Um Novo Desafio para a Cardiopatia na Gravidez
This work presents the results obtained for the gas chromatography-mass spectrometry (GC-MS) monitoring of the liquid-phase hydrodeoxygenation (HDO) reaction of furfural (FFR) to 2-methylfuran (MF) over a bifunctional Ru/RuOx/C catalyst in the presence of a direct source of H2. Hydrogenation and hydrogenolysis reactions of FFR and of the intermediate furfury
Arq. Bras. Cardiol.. Publicado em: 2020-07