Reaction Kinetics
Mostrando 1-12 de 1045 artigos, teses e dissertações.
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1. Utilization of the Corncob Agro-Industrial Residue as a Potential Adsorbent in the Biosorption of Bisphenol-A
The presence of plastic waste in water bodies has led to a growing concern due to the impact on human health. Among the most important plastic additive molecules is bisphenol-A (BPA). On the other hand, micro-pollutant removal processes that make use of agro-industrial waste have aroused the interest of researchers. This is because the accumulation of lignoc
J. Braz. Chem. Soc.. Publicado em: 2021-07
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2. Unified comprehension of the kinetics of isothermal ceramic processes under field-free and resonant wave-field conditions
Abstract This paper proposes a unified comprehension of the isothermal ceramic process kinetics stemming from mesoscopic irreversible thermodynamics. Accordingly, a unified process kinetic equation (UPKE) is derived, which predicts that the global isothermal process rate of any ceramic process is, in general, nonlinearly related both to its activation energy
Cerâmica. Publicado em: 2021-03
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3. Ternary system Portland cement-calcium aluminate cement-calcium sulfate applied to self-leveling mortar: a literature review
Abstract The modernization of building systems is increasingly demanding products that improve efficiency during their processing. The development of self-leveling mortars for the regularization of flooring is a consequence of this evolution. The high contents of binder and water to obtain self-flowing property, plus the application of thin layers over large
Cerâmica. Publicado em: 2021-03
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4. IMIDAZOL E CATÁLISE: UM PAR PERFEITO
The imidazole (IMZ) ring presents several chemical properties that turns it into a versatile acid-basic/nucleophilic catalyst. The discovery of the biological properties of histidine (amino acid with IMZ ring) instigates the study of this class of compounds. It is found in nature in several enzymes such as chymotrypsin and RNAses due to these properties. Thi
Quím. Nova. Publicado em: 2021-03
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5. Camu-camu (Myrciaria dubia) and jambolan (Syzygium cumini) juice blend: sensory analysis and bioactive compounds stability
Abstract In this study, the stability of the bioactive compounds from camu-camu and jambolan mixture was evaluated, and a juice blend formulation based on its sensorial properties was established. The stability of three juice formulations with camu-camu/jambolan/water (w:w:w), 37.5:12.5:50 (JB); 37.5:0:62.5 (CJ) and 0:12.5:87.5 (JJ) was evaluated. Additional
Food Sci. Technol. Publicado em: 2021-03
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6. MULTIVARIATE ANALYSIS OF DIGITAL IMAGES AS AN ALTERNATIVE TO MONITOR DYE DEGRADATION BY THE FENTON PROCESS
The present work proposed the application of a multivariate regression model based on image data to monitor the decolorization process. Thus, a PLS regression based on the color histogram was applied to monitor the methylene blue degradation by the Fenton reaction. The results obtained by the digital imaging and UV-Vis methods were compared and the initial (
Quím. Nova. Publicado em: 2020-05
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7. Residue-Based CaO Heterogeneous Catalysts from Crab and Mollusk Shells for FAME Production Via Transesterification
The production of fatty acid methyl esther (FAME) via transesterification was studied, assessing the influence of CaO heterogeneous catalysts obtained from four different fishery residues: sururu, crab, clam and mussel. Characterization and properties of the residues were obtained via thermogravimetric analysis, X-ray diffraction, X-ray fluorescence, Fourier
J. Braz. Chem. Soc.. Publicado em: 2020-04
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8. Effect of drying temperature on color and desorption characteristics of oyster mushroom
Abstract Oyster mushroom (Pleurotus ostreatus) slices were dried in a hot air dryer at three temperatures (45, 55 and 65 °C). The sorption isotherm of dried samples in the water activity (aw) range of 0.556-0.970 was also determined at three temperature levels. Moisture desorption isotherms were obtained from changes in water activities of oyster mushroom s
Food Sci. Technol. Publicado em: 2020-03
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9. Mathematical Modeling of the Transesterification Reaction by Finite Elements: Optimization of Kinetic Parameters Using the Simplex Sequential Method
The use of biodiesel as fuel has been presented as a viable alternative in the search for renewable energies. It can be produced from the transesterification reaction of vegetable oils with methanol in the presence of sodium or potassium hydroxide as catalysts. In the present research, the transesterification reaction of soybean oil was modeled considering t
J. Braz. Chem. Soc.. Publicado em: 2020-02
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10. ANALYTICAL EXPRESSIONS FOR THE CONCENTRATION AND CURRENT IN THE REDUCTION OF HYDROGEN PEROXIDE AT A METAL-DISPERSED CONDUCTING POLYMER FILM
A mathematical model describing the reduction of Hydrogen peroxide (H2O2) to water in a metal dispersed conducting polymer film is discussed. The model is based on a system of reaction-diffusion equations containing a non-linear term related to Michaelis-Menten kinetics of the enzymatic reaction. The approximate analytical expressions corresponding to the co
Quím. Nova. Publicado em: 2020-01
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11. DETERMINATION OF REACTIVITY AND THERMODYNAMIC ANALYSIS OF NICKEL-BASED OXYGEN CARRIERS FOR CHEMICAL-LOOPING COMBUSTION
Abstract This work aimed to study nickel-based oxygen carriers (OC) for Chemical Looping Combustion (CLC) using H2 and CH4 as fuel. The reactivity and reaction kinetics of the OC were investigated, applying the shrinking core, nucleation and diffusion models in three dimensions, as well as whether the OC is thermodynamically favorable for the reaction. The r
Braz. J. Chem. Eng.. Publicado em: 09/12/2019
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12. Preparation and application of Zero Valent Iron immobilized in Activated Carbon for removal of hexavalent Chromium from synthetic effluent
RESUMO Diferentemente dos contaminantes orgânicos, os metais pesados não são biodegradáveis e tendem a se acumular nos organismos vivos e também são reconhecidos por serem tóxicos ou carcinogênicos. A utilização de nanopartículas de ferro zero valente (nFVZ) é relatada como uma técnica alternativa e de elevado potencial para remediação in situ
Rev. Ambient. Água. Publicado em: 03/10/2019