Pyrolytic
Mostrando 13-24 de 46 artigos, teses e dissertações.
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13. Electrochemical feasibility study of methyl parathion determination on graphite-modified basal plane pyrolytic graphite electrode
Um método eletroquímico de baixo custo foi desenvolvido para a determinação de traços de metil paration (MP) baseado nas propriedades do eletrodo de grafite pirolítico de plano basal modificado com grafite (grafite-bppg). A combinação do grafite-bppg com voltametria de onda quadrada (VOQ) resultou em um método eletroquímico seletivo, sensível e or
Journal of the Brazilian Chemical Society. Publicado em: 2011
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14. Cobalt electrodeposition onto highly oriented pyrolytic graphite (HOPG) electrode from ammonium sulfate solutions
It was carried out an electrochemical study of the cobalt electrodeposition onto HOPG electrode from an aqueous solution containing 10-2 M of CoSO4 + 1M (NH4)2SO4. Nucleation parameters such as nucleation rate, density of active nucleation sites, saturation nucleus and the rate constant of the proton reduction reaction (kPR) were determined from potentiostat
Química Nova. Publicado em: 2010
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15. AVALIAÇÃO VOLTAMÉTRICA DOS ÍONS METÁLICOS (COBRE, CÁDMIO E CHUMBO) EM AMOSTRAS DE COMBUSTÍVEIS PREVIAMENTE DIGERIDAS EM MICROONDAS USANDO ELETRODO QUIMICAMENTE MODIFICADO POR SAIS TETRAZÓLIOS / EVALUATION OF METAL IONS VOLTAMMETRY(COPPER, CADMIUM AND LEAD) IN SAMPLES OF FUELS PREVIOUSLY DIGESTED IN USING MICROWAVE ELECTRODE CHEMICALLY MODIFIED BY SALTS TETRAZOLIUM.
This paper describes an analytical procedure for determination of trace metals copper, cadmium and lead in fuel samples, using Basal Plane Pyrolytic Graphite Modified Electrode (BPPGME) by tetrazolium salts: ([3,3 - (3-3 -dimethoxy-4, bifenililen 4 -bis [2 - (4-nitrophenyl)-5-phenyl-2H-tetrazolium (NBT) Cl 3 - (4,5 - dimetitiazol-2il) -2,5-diphenyl-2H-Tetraz
Publicado em: 2010
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16. Giant superconducting proximity effect in graphite / Efeito de proximidade gigante entre supercondutor e grafite
In order to verify the existence of superconducting correlations in graphite, in this work we studied the possibility of the so-called giant proximity effect in highly oriented pyrolytic graphite (HOPG) samples. Magnetoresistance measurements performed on various thoroughly characterized HOPG samples with attached superconducting In or Pb-In electrodes revea
Publicado em: 2009
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17. Employment of cathodes of diffusion of oxygen in eletrotrolise of brine to produce chlorine / Emprego de catodos de difusão de oxigenio na eletrolise da salmoura para a produção de cloro
This work is investigating the performance of electrodes modified with gaseous diffusion of particles of Cu, for reduction of oxygen in the production of chlorine during the electrolysis of brine. Initially, the reaction was studied on the anodic oxidation of chloride ion. Using a single cell compartment, with the type DSA anode with an area of 1.5 cm2 as wo
Publicado em: 2009
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18. Técnicas de extrações e procedimentos de clean-up para a determinação de hidrocarbonetos policílicos aromáticos (HPA) em sedimentos da costa do Ceará
Extraction and clean-up are essential points in polycyclic aromatic hydrocarbon (PAHs) analysis in a solid matrix. This work compares extraction techniques and clean-up procedures for PAH analysis. PAH levels, their toxicological significance and source were also evaluated in the waters of the Cocó and Ceará rivers. The efficiency of PAH recovery was highe
Química Nova. Publicado em: 2008
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19. Co-pirólise de polipropileno pós-consumo com gasóleo / Co-pyrolysis of polypropylene residues with gas-oil
In this study, the process of co-pyrolysis of polypropylene (PP) residues with gas-oil was evaluated, varying the temperature and the amount of polypropylene fed to the reactor. The co-pyrolysis is a promising route to minimize the environmental impact caused by the inadequate disposal of plastics, preventing its accumulation in landfields and giving a bette
Publicado em: 2008
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20. Policyclyc aromatic hidrocarbons study at São Vicente and Santos Estuaries SP using diatomite as adsorbent material / Estudo de hidrocarbonetos policíclicos aromáticos nos estuários de Santos e São Vicente/SP utilizando diatomito como material adsorvente
Diatomite spheres were used as an adsorbent material for policyclyc aromatic hidrocarbons (PAH) adsorption at water column for the identification of the main contamination sources at two estuaries of Baixada Santista. The samples were held at Santos Estuary (site 1) and São Vicente Estuary (site 2) during the year 2006, at two sites, and in 2007, only at si
Publicado em: 2008
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21. Construção e estudo das condições de operação de uma unidade de pirólise para pneumáticos inservíveis
Today the used tire is considered a residue with quite inadequate final disposition as in embankments. It can cause many environmental and human health problems because it can absorb gases and to burst. When it is burned into nature it forms toxicant substances as sulfur dioxide and powder material. An alternative use of the used is as energy source in indus
Publicado em: 2007
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22. Hidrocarbonetos policíclicos aromáticos no meio ambiente: diferenciação de fontes em sedimentos e metabólitos em bile de peixes
Many studies on environmental ecosystems quality related to polycyclic aromatic hydrocarbons (PAH) have been carried out routinely due to their ubiquotus presence worldwide and to their potential toxicity after its biotransformation. PAH may be introduced into the environmet by natural and anthropogenic processes from direct runoff and discharges and indirec
Publicado em: 2007
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23. DETERMINAÇÃO DE HIDRAZINA POR VOLTAMETRIA DE ONDA QUADRADA SOBRE ELETRODO DE GRAFITE MODIFICADO COM FeTPyPz / HYDRAZINE DETERMINATION FOR VOLTAMMETRIC OF SQUARE SHAPED WAVE ON GRAPHITE ELECTRODE MODIFIED WITH FeTPyPz
In this work, the determination of hydrazine (N2H4) in aqueous solutions was investigated by voltammetric techniques on pyrolytic graphite electrodes (GP) before and after modification with iron tetra-pyridinoporphyrazine (FeTPyPz). The modified electrode GP/FeTPyPz presented higher oxidation currents and better voltammetric profiles in comparison with the u
Publicado em: 2007
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24. DETERMINAÇÃO DO HERBICIDA PARAQUAT SOBRE ELETRODOS DE GRAFITE PIROLÍTICO MODIFICADOS COM FTALOCIANINA DE COBALTO UTILIZANDO VOLTAMETRIA DE ONDA QUADRADA / DETERMINATION OF HERBICIDE PARAQUAT ON ELECTRODES OF PYROLYTIC GRAPHITE MODIFIED WITH COBALT PHTALOCYANINE USING WAVE SQUARE VOLTAMMETRY
Determination of paraquat (PQ) in watery solutions was investigated with the technique of wave square voltammetry on pyrolytic graphite electrodes (PG) before and after modifications with metal phtalocyanines. The electrode modified with cobalt phthalocyanine (CoPc) presented PQ reduction currents more accented and voltammetrics profiles better with respect
Publicado em: 2006