Pyrolysis
Mostrando 1-12 de 288 artigos, teses e dissertações.
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1. Study of Catalytic Pyrolysis of Biomass Sorghum (Sorghum bicolor L. Moench) Using Design of Experiments and Surface Response Methodology
This study proposes a screen of variables that have an influence on the modification of the bio-oil chemical composition as a unique critical quality attribute (CQA) throughout the pyrolytic process (zeolite, ZSM-5) by using a 24 full factorial design, followed by optimization through a response surface methodology (RSM) based on central composite design (CC
Journal of the Brazilian Chemical Society. Publicado em: 2023
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2. Fast Catalytic Pyrolysis of Tetradecanoic Acid: Formation of Ketones as Intermediate Compounds in the Production of Hydrocarbons
This work aimed to compare two different catalysts in the production of a long chain ketone, intermediate in the production of hydrocarbons, during pyrolysis of tetradecanoic acid as a model fatty acid. The studied variables were the temperature, 450 and 600 ºC, and catalysts, γ-Al2O3 and Nb2O5, the latter has never been studied under such conditions. Pyro
Journal of the Brazilian Chemical Society. Publicado em: 2022
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3. Structural Characteristics of Lignite Char from Different Pyrolysis Reactors and the Influence on Their Gasification Reactivity
The gasification reactivity of coal char is affected by numerous experimental variables, and char structure is one of the dominant factors. In this work, Raman spectroscopy, powder X-ray diffraction (XRD), and N2 adsorption were used to investigate the physical and chemical structure of char prepared under different pyrolysis conditions. Three kinds of pyrol
Journal of the Brazilian Chemical Society. Publicado em: 2022
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4. ADSORPTION OF ATRAZINE IN RICE HUSK BIOCHARS: A PHENOMENOLOGICAL MODEL APPLIED TO EQUILIBRIUM AND KINETIC STUDIES
ABSTRACT Atrazine is an herbicide used to remove weeds in agricultural crops; however, because it is considered toxic, options for removing it from the environment are needed. Adsorption on biochar is an efficient technique for removing organic contaminants. In this study, the atrazine adsorption capacities of two biochars (BCA400 and BCA700) produced from r
Engenharia Agrícola. Publicado em: 2022
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5. Interaction of Lead and Calcium with Biochar Produced from Cassava Waste: Perspectives for Agricultural and Environmental Application
Biochar from slow pyrolysis under controlled conditions is favorable in the transformation of waste into materials that serve as soil conditioners, and/or environmental remediation. Thus, this work aimed to produce and characterize biochar from cassava waste under different temperature conditions and evaluate interactions with Ca2+ and Pb2+ for agricultural
Journal of the Brazilian Chemical Society. Publicado em: 2022
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6. Preparation of Silicon Oxycarbide (SiCO) Ceramics from Different Polymer Architectures and Assessment on the Performance as Electrodic Materials for Voltammetric Sensing of Antioxidant Phenolic Compounds
Silicon oxycarbide (SiCO) ceramics obtained from polymer pyrolysis and with varied carbon contents were prepared and evaluated as new electrodic materials for sensing of tert butylhydroquinone (TBHQ) and butylated hydroxyanisole (BHA) antioxidants. Three polymers were synthesized varying molecular architecture and aromatic carbon groups, followed by pyrolysi
Journal of the Brazilian Chemical Society. Publicado em: 2022
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7. An alternative energy generation from charcoal produced from Brazilian pine (Araucaria angustifolia (Bert.) O. Ktze) seed residues
The perspective is that the energy demand will grow in the coming decades worldwide. The search for renewable energy sources is urgent and necessary. Residual biomass may be a promising source of raw material for obtaining bioenergy. Thus, this research sought to evaluate the energetic and physicochemical properties of residues from the seeds of Brazilian pi
Química Nova. Publicado em: 2022
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8. Biomarkers in Source Rocks from Barreirinha Formation (Devonian): Distribution and Paleoenvironment Significance
The Barreirinha Formation-Upper Devonian, is the main petroleum source rock of the Amazon Basin, deposited during the great Devonian Transgression, contributing to significant accumulations of organic matter (OM) in anoxic conditions, which allowed its preservation. The present work had the objective of characterizing the molecular composition of biomarkers
Journal of the Brazilian Chemical Society. Publicado em: 2022
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9. Magnetized Biochar as a Gold Nanocatalyst Support for p-Nitrophenol Reduction
The biomass use is of considerable ecological and economical interest and here, biochar, a by-product of biomass carbonization, is magnetized with Fe3O4 for its use as gold nanoparticle (NP) support towards catalysis of p-nitrophenol (4-NP) reduction. Biochar was synthesized from coffee straw biomass via pyrolysis, while magnetite functionalization was obtai
J. Braz. Chem. Soc.. Publicado em: 2021-08
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10. A Gas Chromatography Method for Simultaneous Quantification of Inorganic Gases and Light Hydrocarbons Generated in Thermochemical Processes
This paper reports a method for simultaneous determination of H2, O2, N2, CO, CO2, CH4, C2H2, C2H4, C2H6, C3H4 (propadiene and propyne), C3H6, C3H8 and C4H10 (n-butane and isobutane) by gas chromatography using thermal conductivity and flame ionization detectors. A single porous layer open tubular column (0.53 mm internal diameter ? 30 m length ? 30 µm thic
J. Braz. Chem. Soc.. Publicado em: 2021-06
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11. Study of Crystallization and Composition on Silicon Oxycarbide (SiOC) and Silicon Boron Oxycarbide (SiBOC) Ceramics Obtained from Alkoxysilanes Precursors
This work deals on the preparation of silicon oxycarbide (SiOC) and silicon boron oxycarbide (SiBOC) ceramics from pyrolysis involving alkoxysilanes with different organic groups. Boron content, organic substituent and annealing time were evaluated on crystallization and composition of resulting ceramics. B-free precursors composed of methyltriethoxysilane (
J. Braz. Chem. Soc.. Publicado em: 2021-06
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12. Thermal and Catalytic Fast Pyrolysis of Oily Extracts of Microalgae: Production of Biokerosene
Three different microalgae species, Desmodesmus sp., Nannochloropsis oculata and Halamphora coffeaeformis were grown under controlled conditions. The resulting dry biomass was characterized by TG-DTA (thermogravimetry-differential thermal analysis) and extracted with three solvents having different polarities. The extracts gross mass yields varied from 2% us
J. Braz. Chem. Soc.. Publicado em: 2021-04