Proton Conductivity
Mostrando 1-12 de 29 artigos, teses e dissertações.
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1. Nafion/sulfonated poly(indene) polyelectrolyte membranes for fuel cell application
Abstract Sulfonated poly(indene) (SPInd), with 35% and 45% degree of sulfonation, was blended with Nafion to prepare blended membranes with 10, 15 and 20 wt.% of SPInd. Membranes were evaluated by infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry, scanning electron microscopy and X-ray diffraction. Water uptake (WU), ion ex
Polímeros. Publicado em: 10/07/2018
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2. Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell
A new sulfonated poly(aromatic imide-co-aliphatic imide) (SPI) for the use as a polymer electrolyte membrane was successfully synthesized from 4,4'-diaminodiphenylmethane (DDM), 4,4'-diaminodiphenylmethane-2,2'-disulfonic acid disodium salt (S-DDM), hexamethylenediamine, and 3,3',4,4'-benzophenonetetracarboxylic dianhydride in a one-step reaction. S-DDM was
Mat. Res.. Publicado em: 18/12/2017
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3. Sulfonation degree effect on ion-conducting SPEEK-titanium oxide membranes properties
Abstract Polymeric membranes were developed using a SPEEK (sulfonated poly(ether ether ketone)) polymer matrix, containing titanium oxide (TiO2) (incorporated by sol-gel method). SPEEK with different sulfonation degrees (SD): 63% and 50% were used. The influence of sulfonation degree on membrane properties was investigated. The thermal analysis (TGA and DTGA
Polímeros. Publicado em: 21/09/2017
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4. Electrical Conductivity in the KDP, ADP, and K1-x(NH4)xH2PO4 Crystals
Impedance Spectroscopy was performed to examine the electrical conductivity on KH2PO4 KDP, (NH4)H2PO4 ADP and K1-x(NH4)xH2PO4 (x = 0.076, 0.118, 0.357, 0.857, 0.942) crystals with increasing temperature. They were grown by solvent evaporation method. Zview simulation software was used to theoretically fit electrical conductivity results as a function of freq
Mat. Res.. Publicado em: 23/02/2017
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5. Preparation of Two Maleic Acid Sulfonamide Salts and Their Copper(II) Complexes and Antiglaucoma Activity Studies
Two novel proton transfer compounds (HAP)+(SAMAL)- and (HBI)+(SAMAL)-.H2O were obtained from (E)-4-oxo-4-(4-sulfamoylphenylamino)but-2-enoic acid (HSAMAL) and 2-aminopyridine (AP) or 1H-benzimidazole (BI), respectively. Copper(II) complexes of salts and of HSAMAL have also been prepared. They have been characterized by elemental, spectral, thermal analyses,
J. Braz. Chem. Soc.. Publicado em: 2016-10
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6. Preparation and Characterization of an Eco-Friendly Polymer Electrolyte Membrane (PEM) Based in a Blend of Sulphonated Poly(Vinyl Alcohol)/ Chitosan Mechanically Stabilised by Nylon 6,6
Abstract Membranes for fuel cell applications were prepared using two polymer blends: poly(vinyl alcohol) (PVAL) and chitosan (CS), 80/20 (w/w) and 60/40 (w/w) with and without nylon. Sulfosuccinic acid (SSA) was used both as a crosslinking and a sulfonating agent. An increasing in the SSA content raised ionic exchange capacity and consequently proton conduc
Mat. Res.. Publicado em: 21/07/2016
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7. IN SITU PREPARED TiO2 NANOPARTICLES CROSS-LINKED SULFONATED PVA MEMBRANES WITH HIGH PROTON CONDUCTIVITY FOR DMFC
Organic/inorganic membranes based on sulfonated poly(vinyl alcohol) (SPVA) and in situ prepared TiO2 nanoparticles nanocomposite membranes with various compositions were prepared to use as proton exchange membranes in direct membrane fuel cells. Poly(vinyl alcohol) (PVA) was sulfonated and cross-linked separately by 4-formylbenzene-1,3-disulfonic acid disodi
Quím. Nova. Publicado em: 2016-07
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8. Nanostructured Polyelectrolytes Based on SPEEK/TiO2 for Direct Ethanol Fuel Cells (DEFCs)
Proton-conducting hybrid membranes consisting of poly(ether ether ketone) sulfonated (SPEEK) and titanium oxide (TiO2) were prepared using the sol-gel technique for application in direct ethanol fuel cells. The effect from TiO2 incorporation on membrane properties such as ethanol uptake, pervaporation and proton conductivity was investigated. The uptake and
Polímeros. Publicado em: 10/06/2014
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9. Proton conductive membranes based on poly (styrene-co-allyl alcohol) semi-IPN
The optimization of fuel cell materials, particularly polymer membranes, for PEMFC has driven the development of methods and alternatives to achieve systems with more adequate properties to this application. The sulfonation of poly (styrene-co-allyl alcohol) (PSAA), using sulfonating agent:styrene ratios of 2:1, 1:1, 1:2, 1:4, 1:6, 1:8 and 1:10, was previous
Polímeros. Publicado em: 10/06/2014
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10. Influence of the NiO nanoparticles on the ionic conductivity of the agar-based electrolyte
NiO nanoparticles with an average size of 15 nm were prepared by a simple, reproducible and low-cost controlled method, using nickel nitrate hexahydrate (Ni(NO3)2·6H2O). These nanoparticles were added to an agar-based polymer electrolyte formula, resulting, after reflux and solution casting, in a proton conducting membrane. The highest ionic conductivity va
Polímeros. Publicado em: 18/04/2014
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11. Sulfonation and characterization of styrene-indene copolymers for the development of proton conducting polymer membranes
The aim of this work is to obtain polymer precursors based on styrene copolymers with distinct degrees of sulfonation, as an alternative material for fuel cell membranes. Acetyl sulfate was used to carry out the sulfonation and the performance of the polyelectrolyte was evaluated based on the content of acid polar groups incorporated into the macromolecular
Polímeros. Publicado em: 30/10/2012
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12. Preparação e caracterização de compósitos SiO2/Nafion® e TiO2/Nafion® / Preparation and characterization of SiO2/Nafion® and TiO2/Nafion® Composites.
O presente trabalho tem como objetivo principal a preparação e a caracterização de compósitos sílica/Nafion® e titânia/Nafion®, sendo o óxido a fase maioritária. A incorporação do Nafion® se deu durante o processo sol-gel. Foram testadas duas rotas sintéticas para a sílica, sendo uma delas catalisada por HNO3 e a outra por NH4OH, e uma rota,
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 10/06/2011