Polymerization Kinetics And Dsc
Mostrando 1-10 de 10 artigos, teses e dissertações.
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1. Thermal radical polymerization of Bis(methacrylamide)s
Abstract Methacrylamides monomers for dental applications were synthesized using a one-step procedure starting from methacrylic anhydride and the respective diamine: N,N’-(propane-1,3-diyl)-bis(N-ethyl-2-methylacrylamide) (1), N,N’-(butane-1,4-diyl)-bis(2-methacrylamide) (2), N,N’-(octane-1,8-diyl-)bis(2-methylacrylamide) (3) and N,N’-(1,4-phenylene)
Polímeros. Publicado em: 27/06/2019
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2. ETHYLENE POLYMERIZATION WITH NICKEL DIIMINE COMPLEXES CONTAINING PSEUDOHALIDES
Nickel-diimine complexes DADNiX2 (DAD= 2,6-iPr2-C6H3-N=C(Me)-C(Me)=N-2,6-iPr2-C6H3) containing the non-chelating pseudo-halide ligands isothyocyanate and isoseleniumcyanate (X= NCS 1 and NCSe 2) were synthesized and used in ethylene polymerization activated by methyaluminoxane (MAO) at temperatures from 0 to 50°C. Polymerizations with these complexes were c
Quím. Nova. Publicado em: 2018-07
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3. Isothermal Crystallization Kinetics of Poly(lactic acid) Stereocomplex/Graphene Nanocomposites
The isothermal crystallization kinetics of PLA stereocomplex (scPLA) and scPLA/graphene oxide nanocomposites was investigated. scPLA was prepared by symmetric blending the two isomers, PLLA and PDLA and the scPLA nanocomposite by polymerization of the respective lactides in presence of commercial graphene oxide nanoplatelets (GNPO+) followed of blending the
Mat. Res.. Publicado em: 18/12/2017
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4. Differential Scanning Calorimetry study on curing kinetics of diglycidyl ether of bisphenol A with amine curing agents for self-healing systems
ABSTRACT Epoxy resin is one of the most important polymeric matrixes for diverse uses, such as aeronautical, mobile, electronics and others. Providing a material capable of self-healing microcracks will allow it to have a more reliable and longer use. In order to study this new property of self-healing to an epoxy resin, a Differential Scanning Calorimetry (
Matéria (Rio J.). Publicado em: 20/07/2017
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5. Synthesis and thermal degradation Kinetics of D - (+) - galactose containing polymers
In this study, it is investigated the synthesis and characterizations of polymerizable vinyl sugars. Carbohydrate containing polymers were synthesized via free radical polymerization. Thermal behavior of polymer derivatives was analyzed by using DSC and TG. Molecular weight dispersion of polymer derivatives was also analyzed with GPC. Molecular structures we
Polímeros. Publicado em: 2013
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6. Estudo do processo e dos produtos da polimerização de biodiesel de óleo de soja com anidrido ftálico e 2-metil-imidazol utilizando biodiesel como solvente
This work present the polymerization study of the epoxidized methyl esters (MEE) obtained from soybean oil, with phthalic anhydride (AF) and 2-methyl-imidazole (2MI) using soybean oil biodiesel (BD) as solvent, as well as the products characterization. The gelation region for the system MEE/AF/2MI without BD was determined using the Flory¿s theory and it oc
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 2011
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7. Methodology to detect the presence of recyled PET in PET food package / Metodologia para detectar a presença do PET reciclado em embalagens PET para alimentos
Recently, Brazil recorded mechanical recycling of the poly (ethylene terepththalate), PET, the highest in the world, corresponding to about 53 wt %. This success in the recycling industry is due to the wide range of its applications, from textiles to packaging for the food industry. The recycled food-grade packaging could be mixed with virgin resin and repro
Publicado em: 2009
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8. PARAMETERS RELATED TO REACTION KINETICS AND POLYMERIZATION STRESS OF RESTORATIVE COMPOSITES / Parâmetros relacionados à cinética de reação e tensão de polimerização de compósitos restauradores
Proposição: O objetivo deste estudo foi avaliar como a contração volumétrica (CV), o grau de conversão (GC), a taxa máxima de polimerização (RPmax) e a tensão de polimerização (TPmax) de dois compósitos experimentais são influenciados pela concentração de fotoiniciadores na matriz e pela irradiância aplicada na fotopolimerização. Material
Publicado em: 2007
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9. Preparação de poliuretana à base de óleo de mamona
Polyurethanes are very versatile macromolecular materials that can be used in the form of powders, adhesives and elastomers. As a consequence, they constitute important subject for research as well as outstanding materials used in several manufacturing processes. In addition to the search for new polyurethanes, the kinetics control during its preparation is
Publicado em: 2005
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10. Modificação do poli (metacrilato de metila) com poli (epicloridrina-co-oxido de etileno)
The modification of poly(methyl methacrylate) (PMMA) with poly(epichlorohydrin-co-ethylene oxide) [(P(EPI-co-EO)] is conducted with the polymerization of the methyl methacrylate in the presence of the elastomer. With this purpose, mixtures containing 0, 10, 20, 30 and 40 wt% of the elastomer, benzoyl peroxide as the initiator, and ethylene glycol dimethacryl
Publicado em: 2000