Polychlorinated Biphenyls
Mostrando 1-12 de 122 artigos, teses e dissertações.
-
1. A Selective Gas Chromatography-Selected Ion Monitoring Mass Spectrometry (GC-MS/SIM) Method to Determine Polychlorinated Biphenyls in Fuller’s Earth
Polychlorinated biphenyls (PCBs) are carcinogenic to humans and can be found in Fuller’s earth used for the regeneration of used transformer oil. This work describes a highly selective gas chromatographic-selected ion monitoring mass spectrometric method (GC-MS/SIM) for the simultaneous determination of three Aroclor PCB congener mixtures (1242, 1254, and
J. Braz. Chem. Soc.. Publicado em: 2020-03
-
2. AVALIAÇÃO DOS RESÍDUOS GERADOS DURANTE A DESTRUIÇÃO DE PCBS PELO PROCESSO CATALISADO POR BASE
There are many processes capable of decontamination of polychlorinated biphenyls in several matrixes. The set of inputs, materials, operation conditions and efficiencies are wide. The base catalyzed dechlorination process shows application potential in great scale, mainly due mild chemical reaction conditions and low cost raw materials. The KPEG is a familia
Quím. Nova. Publicado em: 2018-06
-
3. PCDD/Fs and PCBs in Soils: a Study of Case in the City of Belo Horizonte-MG
Dioxins (polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) and polychlorinated biphenyls (PCBs)) are substances that represent a global concern due to their ubiquitous presence and toxicity. Industrial processes and other human activities as well as uncontrollable accidents are the main sources that release these pollutants into t
J. Braz. Chem. Soc.. Publicado em: 2017-05
-
4. Solid-Liquid Extraction with Low Temperature Purification Coupled with Gas Chromatography and Mass Spectrometry for Determination of Polychlorinated Biphenyls in Sewage Sludge
Sewage sludge is the residue produced by the wastewater treatment plants, which can be used as soil conditioner in agriculture. However, the current legislation recommends monitoring chemical contaminants such as polychlorinated biphenyls (PCBs). In this study, solid-liquid extraction with low temperature purification (SLE-LTP) was optimized and validated fo
J. Braz. Chem. Soc.. Publicado em: 2017-01
-
5. Regional analysis of potential polychlorinated biphenyl degrading bacterial strains from China
ABSTRACT Polychlorinated biphenyls (PCBs), the chlorinated derivatives of biphenyl, are one of the most prevalent, highly toxic and persistent groups of contaminants in the environment. The objective of this study was to investigate the biodegradation of PCBs in northeastern (Heilongjiang Province), northern (Shanxi Province) and eastern China (Shanghai muni
Braz. J. Microbiol.. Publicado em: 2016-09
-
6. AVALIAÇÃO DAS NORMAS DE ENSAIO APLICADAS NA QUANTIFICAÇÃO DE PCBs EM ÓLEO ISOLANTE
Polychlorinated biphenyls (PCBs) were widely used between 1940 and 1970 as an insulating fluid for transformers and capacitors. However, they are bioaccumulative and potentially carcinogenic and, according to the 2001 Stockholm Convention, must be eliminated by 2025. In Brazil, they have been gradually eliminated but contaminated equipment remains. The Brazi
Quím. Nova. Publicado em: 2015-05
-
7. POLYCHLORINATED DIBENZO-P-DIOXINS, DIBENZOFURANS, AND BIPHENYLS IN FREGATA MAGNIFICENS FROM ILHA GRANDE BAY, RIO DE JANEIRO STATE, SOUTH-EASTERN BRAZIL
O objetivo deste trabalho é realizar análises químicas em tecidos da ave marinha Fregatamagnificens que se alimenta de peixes. Esta ave é reconhecida por estar em risco de acumular contaminantes tóxicos, devido a sua alta posição na teia trófica e a sua baixa capacidade de metabolizar compostos xenobióticos. Exemplares de Fregata magnificens foram c
Braz. j. oceanogr.. Publicado em: 2015-03
-
8. Química entre a microcamada superficial oceânica e os aerossóis marinhos
The sea surface microlayer (SML), although poorly understood, is important in biogeochemical cycling and sea - air exchanges; it is a source or a sink for a range of pollutants. In this paper, an overview of sampling techniques and the role of SML in biogeochemical cycles and climate is presented. The chemical and biological nature of the ocean surface film
Quím. Nova. Publicado em: 2014
-
9. Integrated pressurized solvent extraction-cleanup for the rapid determination of polychlorinated biphenyls in meat samples
Um método rápido e eficiente, baseado na integração da extração com solvente sob pressão (PSE) com limpeza através do método sólido de extração (SPE) e sistema de cromatografia gasosa com detector por captura de elétrons (GC-ECD) foi desenvolvido para a determinação de bifenilos policlorados (PCBs). Seis indicadores e doze PCBs semelhantes à
J. Braz. Chem. Soc.. Publicado em: 2013-05
-
10. Determination of polychlorinated biphenyls in seawater using headspace solid-phase microextraction coupled with gas chromatography-mass spectrometry with the aid of experimental design
Uma abordagem de pré-tratamento simples e confiável em cromatografia gasosa acoplada à espectrometria de massa (GC-MS) foi desenvolvida para a limpeza simultânea da água do mar e concentração de bifenilas policloradas (PCBs), com 1 a 8 átomos de cloro, baseada na combinação da oxidação de KMnO4 com amostragem de headspace e microextração em fas
Journal of the Brazilian Chemical Society. Publicado em: 2012-01
-
11. Determinação de bifenilos policlorados em milho através de extração em fase sólida seguida de cromatografia a gás acoplada à espectrometria de massas
This paper describes an analytical method for analyzing polychlorinated biphenyls in corn samples using solid phase extraction (SPE) followed by determination by GC-MS. All calibration curves proved linear (r> 0.99). Recoveries ranged between 74.1 and 110.6% with relative standard deviation lower than 20% for all compounds. The limits of quantitation for the
Química Nova. Publicado em: 2012
-
12. RESÍDUOS DE BIFENILOS POLICLORADOS EM ARROZ E FEIJÃO DO ESTADO DO RIO GRANDE DO SUL / RESIDUES OF POLYCHLORINATED BIPHENYL IN RICE AND BEANS IN THE STATE OF RIO GRANDE DO SUL
Polychlorinated biphenyls (PCBs) were commercially produced between 1929 and the mid 1980s with industrial purposes. The same properties that interested industrially, as chemical inertness, high dielectric constant, resistance to burning; were also responsible for the spreading of the PCBs in all of the environmental compartments, mainly due to the inadequat
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 12/09/2011