Photooxidation
Mostrando 1-12 de 137 artigos, teses e dissertações.
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1. Synthesis, Characterization, Spectroelectrochemical, Photophysical and HSA-Binding Properties of Novel and Versatile meso-Tetra(4-pyridylvinylphenyl)porphyrins Coordinated to Ruthenium(II)-Polypyridyl Derivatives
The free-base meso-tetra(4-pyridylvinylphenyl)porphyrin (1a) and its zinc(II) complex were synthesized and then functionalized with [Ru(bpy)2Cl]+ units (2a and 2b) via conventional methods and evaluated in terms of photophysical, electrochemical and biological aspects. All porphyrins present moderate singlet oxygen production and fluorescence quantum yield,
J. Braz. Chem. Soc.. Publicado em: 2020-11
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2. Geochemical Investigation of Tar Balls Collected in a Brazilian Beach Using Biomarkers, Ni/V, δ13C Ratios and Ultra-High Resolution FT-ICR Mass Spectrometry
Representative tar balls collected in two distinct years (2012 and 2014) in a beach along the State of Bahia, northeastern Brazil, were geochemically characterized in order to identify correlations between them and investigate potential sources. Terpanes and steranes biomarkers (detected by gas chromatography coupled to mass spectrometry, GC-MS), carbon stab
J. Braz. Chem. Soc.. Publicado em: 2020-04
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3. Semicondutores heteroestruturados: uma abordagem sobre os principais desafios para a obtenção e aplicação em processos fotoquímicos ambientais e energéticos
Heterostructured semiconductors are materials with unique features formed by combination of two or more semiconductors with suitable interface between them. The study of the heterostructures aim the development of physico-chemical and photocatalytic properties higher than their isolated phases, which makes it possible to obtain higher efficiency and lower co
Quím. Nova. Publicado em: 15/08/2019
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4. Tratamento de efluentes de lavanderia hospitalar por processo oxidativo avançado: UV/H2O2
RESUMO O objetivo deste trabalho foi avaliar o tratamento de efluentes de lavanderia hospitalar por processo oxidativo avançado UV/H2O2. O planejamento fatorial 32 foi empregado de modo a avaliar a influência do pH e da dosagem de peróxido na eficiência do tratamento. Os experimentos de foto-oxidação foram realizados com efluentes coletados na lavander
Eng. Sanit. Ambient.. Publicado em: 01/07/2019
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5. Photodynamic action of the red laser on Propionibacterium acnes
Abstract: Background: Photodynamic therapy is a therapeutic modality that has consolidated its activity in the photooxidation of organic matter, which arises from the activity of reactive oxygen species. Objective: To evaluate the effect of red laser 660nm with the photosensitizer methylene blue on Propionibacterium acnes in vitro. Method: The experimenta
An. Bras. Dermatol.. Publicado em: 2017-10
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6. Structural Analysis of High-Spin States of S0-S4 at OEC Complex: A Theoretical Approach of Small Models
S-states at oxygen evolving complex (OEC) are widely studied due to its large importance in photo-oxidation water process. The structural aspects involving S0, S1, S2, S3 and S4 states are still not solved theoretically. Particularly, spin states have been analyzed as an important aspect in S-state models. Seeking to obtain a relevant and simple model to cov
J. Braz. Chem. Soc.. Publicado em: 2017-02
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7. Fontes, formação, reatividade e determinação de quinonas na atmosfera
Quinones are a group of semi-volatile organic substances, ubiquitous in nature, belonging to the class of oxygenated polycyclic aromatic hydrocarbons (Oxygenated PAH). These compounds are formed in biogenic processes, through the oxidative metabolism of endogenous compounds, such as catecholamines, estrogen hormones and xenobiotics, as well as directly emitt
Quím. Nova. Publicado em: 2016-05
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8. Oxidative Modifications in Crystallin Proteins and Lens Epithelial Cells Associated with Photosensitized Reactions Mediated by the Major Chromophore Arising from Glucose Degradation
Deleterious effect mediated by glucose degradation, as a parallel pathway to Maillard reaction, was analyzed in terms of the feasibility of inducing photo-crosslinking in isolated bovine crystalline proteins when exposed to ultraviolet A (UVA)-visible light. These experiments showed evidence supporting the generation of a glucose-derived chromophore (GDC). T
J. Braz. Chem. Soc.. Publicado em: 2016-02
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9. Use of Doehlert and constrained mixture designs in the development of a photo-oxidation procedure using UV radiation/H2O2 for decomposition of landfill leachate samples and determination of metals by flame atomic absorption spectrometry
Este trabalho propõe o uso de degradação por foto-oxidação com radiação ultravioleta e H2O2 como técnica de tratamento de amostras para a determinação de Fe, Zn, Mn, Ni e Co a partir de chorume de aterro sanitário municipal usando espectrometria de absorção atômica com chama (FAAS). Três variáveis (pH, tempo de irradiação e concentração d
An. Acad. Bras. Ciênc.. Publicado em: 2015-03
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10. Torularhodin and Torulene: Bioproduction, Properties and Prospective Applications in Food and Cosmetics - a Review
Torularhodin and torulene are two widespread microbial carotenoids with relatively few studies, as compared to other nutraceutical carotenoids such as β-carotene, lycopene and astaxanthin. Several genera of microorganisms produce it in high concentration (up to 0.1% of the cell dry weight), probably as a protection against photooxidation and free radicals.
Braz. arch. biol. technol.. Publicado em: 14/10/2014
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11. Estudo fotoeletroquímico de filmes finos nanoestruturados de óxidos metálicos: Aplicação na fotooxidação da água / Photoelectrochemical study of nanostructured thin films of metal oxides: Application in the photooxidation of water
Muitas pesquisas buscam o desenvolvimento de células fotoeletroquímicas (PECs) capazes de converter eficientemente energia solar em hidrogênio por meio da fotoeletrólise da água. Recentemente, diversas estratégias têm sido desenvolvidas para fabricação materiais semicondutores destinados a aplicação como fotoanodos em PECs. Neste contexto, esta di
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 13/02/2012
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12. Enhanced photocatalytic activity of TiO2 films by modification with polyethylene glycol
Titanium dioxide porous thin films on the Anatase phase were deposited onto glass slides by the sol-gel method assisted with polyethylene glycol (PEG). The dip-coated films were characterized using scanning electron microscopy (SEM), thermogravimetric analysis (TGA and DTG), UV-visible spectroscopy and X-ray diffraction (XRD). The photocatalytic activity of
Quím. Nova. Publicado em: 2012