Pechini Method
Mostrando 1-12 de 54 artigos, teses e dissertações.
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1. Perovskite-Type Oxides La0.6M0.4Ni0.6Cu0.4O3 (M = Ag, Ba, Ce) towards the Oxygen Reduction Reaction (ORR) in Alkaline Medium: Structural Aspects and Electrocatalytic Activity
In this work, La0.6M0.4Ni0.6Cu0.4O3 (M = Ag, Ba, and Ce, denoted as LANC, LBNC, and LCNC, respectively) electrocatalysts were synthesized by the Pechini method at 1023 K for two hours in air. Rietveld refinement allowed the identification of the crystallographic phases present in all oxides. The electrocatalytic performance of these oxides towards the oxygen
J. Braz. Chem. Soc.. Publicado em: 2021-03
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2. Physical and mechanical properties of low, ultralow and no cement refractory castables containing MgO nanoparticles developed in situ by means of polymeric resins
Resumo A introdução de nanopartículas de MgO desenvolvidas in situ na matriz de concretos refratários de baixo teor de cimento, ultrabaixo e sem cimento foi feita por meio de uma resina polimérica aquosa de baixa viscosidade, produzida pelo método Pechini. A adição da resina líquida aos concretos desempenhou dois papéis: primeiro serviu como fornec
Cerâmica. Publicado em: 14/11/2019
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3. Nanoparticles of Fe2O3 and Co3O4 as Efficient Electrocatalysts for Oxygen Reduction Reaction in Acid Medium
This paper presents a comparative study about the oxygen reduction reaction (ORR) catalyzed by nanoparticles of Fe2O3 and Co3O4 applied on the surface of glassy carbon electrodes (GCE). The nanoparticles were synthesized using the modified polymeric precursor method (Pechini). These two nanomaterials were characterized by Fourier transform infrared spectrosc
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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4. Influência do tipo de solvente na síntese de mulita pelo método Pechini
Resumo Mulita é um aluminossilicato com grande importância na tecnologia cerâmica. Sua síntese através de métodos químicos tem sido extensivamente estudada, no entanto, não se observam estudos da sua obtenção pelo método Pechini. Assim, este estudo teve por objetivo a síntese de mulita por meio deste método. Foi avaliada a influência de diverso
Cerâmica. Publicado em: 15/08/2019
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5. Study of ZnAl2O4 spinel nanoparticles synthesized using gelatin as organic precursor
Resumo Neste trabalho, pós do espinélio aluminato de zinco foram preparados por um método Pechini modificado, rápido, simples, ambientamento seguro e de baixo custo, utilizando gelatina comercial como precursor orgânico. Os materiais foram calcinados a 600, 700 e 800 °C e caracterizados por análise termogravimétrica, difratometria de raios X (DRX) in
Cerâmica. Publicado em: 06/06/2019
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6. Local piezo-response for lead-free Ba0.9Ca0.1Ti0.9Zr0.1O3 electro-ceramic by switching spectroscopy
The purpose of this work is to determine the effective piezoelectric coefficient (d33) and the macro ferroelectric hysteresis behavior for the Ba0.9Ca0.1Ti0.9Zr0.1O3 (BCZT). The sample was prepared by the modified Pechini method and it was sintered at 1250 ºC for 5 h. The refinements of X-ray diffraction (XRD) patterns obtained by the Rietveld method sugges
Mat. Res.. Publicado em: 11/01/2018
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7. TRATAMENTO ELETROQUÍMICO DE EFLUENTE DA PRODUÇÃO DE BIODIESEL USANDO UM ELETRODO DO TIPO ADE: Ti/IrO2-Nb2O5
This work presents the electrochemical treatment of wastewater of biodiesel production, using DSA based on IrO2 and Nb2O5. The anode was prepared by modified Pechini method and characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), in order to evaluate structural and morphological properties and by electrochemical impedance spectros
Quím. Nova. Publicado em: 2018-01
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8. Morphological Characterization of Tungsten Trioxide Nanopowders Synthesized by Sol-Gel Modified Pechini's Method
Sol-gel modified Pechini's method was used to prepare WO3 nanopowders using dicarboxylic acid and polyethylene glycol as the chelating agent and polymeric source, respectively. WO3 powders were first prepared by calcination of resin precursor at 550ºC under various initial concentrations of metal ion (12.5-50 mmol), acid (125-500 mmol), a complexing agent (
Mat. Res.. Publicado em: 28/09/2017
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9. Effect of Fe3+ Doping in the Photocatalytic Properties of BaSnO3 Perovskite
In the last ten years, stannates with perovskite structure have been tested as photocatalysts. In spite of the ability of perovskite materials to accommodate different cations in its structure, evaluation of doped stannates is not a common task in the photocatalysis area. In this work, Fe3+ doped BaSnO3 was synthesized by the modified Pechini method, with ca
Mat. Res.. Publicado em: 10/08/2017
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10. Effect of La Doping on the Crystal Structure, Electric, Magnetic and Morphologic Properties of the BSCCO System
Studies of the doping process can provide a better understanding of the superconducting mechanisms in cuprous oxide materials. In this work, we studied the doping effects on the crystal structure, electric, morphologic and magnetic properties of the BSCCO system with the nominal composition Bi1.6Pb0.4Sr(2-x)RExCa2Cu3O(10-δ). Here, the rare earth element (RE
Mat. Res.. Publicado em: 03/08/2017
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11. Structure and Physical Properties of the LaBiFe2O6 Perovskite Produced by the Modified Pechini Method
In this paper the synthesis of the LaBiFe2O6 material by the modified Pechini method is reported. Structural, morphologic, magnetic and optic experimental studies were performed. Rietveld refinement of x-ray diffraction patterns revealed that LaBiFe2O6 crystallizes in an orthorhombic perovskite structure (space group Pnma, # 62). Scanning electron microscopy
Mat. Res.. Publicado em: 24/07/2017
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12. Nanoparticles of ZnO Doped With Mn: Structural and Morphological Characteristics
In this study, the effects of dopant concentrations on the structural and morphological characteristics of Zn1-xMnxO powders (x= 0.025, 0.05, 0.075, and 0.1 mole) synthesized by the Pechini method has been investigated. The powder was characterized by X-ray diffraction (XRD), Brunauer-Emmet-Teller (BET) specific surface, energy dispersive X-ray (EDX), scanni
Mat. Res.. Publicado em: 08/06/2017